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简介：ThedynamiccompetititveadsorptionbehaviorsofdifferentbinaryorganicvapormixturesonACF-Psunderdifferentoperationconditonswereinvestigatedbygaschromatographyinthispaper,Thestudiedmixtruesincludedbenzene/toluene,toluene/xylene,benzene/isopropylbenzeneethlyacetate/tolueneandbenzene/ethylacetate.ExperimentalresultsshowthatvariousACF-Ps,aswithACF-W,canremovebothvaporsinbinaryvapormixtureswithover99%ofremovalefficiencybeforethebreakthroughpointofthemoreweaklyadsorbedvapor,Indynamiccompetitiveadsorption,themoreweaklyweakleadsorbedvapornoeonlypenetratesearly,butalsowillbedisplacedanddesorbedconsequentlybystrongeradsorbateandthereforeproducesarollingupinthebreakthroughcurve,TheACF-Pspreparedatdifferenttemperatuershavesomewhatdifferentadsorptionselectivity,Thefeedconcentrationratioofvapros,thelength/diameterratioandthethickofbedhaveeffectoncompetitiveadsorption.Thecompetitiveadsorptionabilityofavaporismainlyrelatedtoitsboilingpoint.Usually,thehighertheboilingpoint,thestrongerthevaporadsorbedonACF-P.

简介：在南部的中国的大米小麦旋转被经常的排干洪水的水政体和重氮(N)授精描绘。有进溶解的器官的氮的行为的研究的实质的缺乏(穿上)在强烈地管理的agroecosystem。在situ地实验3年的A被进行决定穿上沥滤并且它在6个连续大米/小麦季节由授精，灌溉和降水影响了的季节、每年的变化。在常规N实践下面(300kgN哈为米饭和200kgN的−1哈为小麦的−1)，季节的一般水准在leachate(100厘米土壤深度)穿上集中因为三个米饭和小麦季节是0.6–1.1和0.1–2.3mgNL−1,分别地。累积穿上沥滤被估计是1.1–2.3kgN哈为米饭季节和0.01–1.3kgN的−1哈为小麦季节的−1，与1.1–3.6kg的一个年度总数N哈−1。在大米季节，N化肥有小效果(P>0.05)在上穿上沥滤；降水和灌溉进口了3.6–9.1kgN哈−1穿上，它可以因此隐藏授精效果在上穿上。在小麦季节，N授精有积极效果(P<0.01)在上穿上。不过，这提升效果被可变降水强烈影响，它也带了1.8–2.9kgN哈−1穿上进地。尽管有到使用的化学N和大变化的一个很小的比例，走水路驾驶政体，穿上沥滤必然与另外的自然生态系统相比由于它的相对更大的数量在大米小麦旋转涉及综合的地N预算。

简介：Afieldexperimentwasconductedfortwoconsecutiveyearsinafarmer'sfieldatHajiMoraVillage,DeraIsmailKhan(D.I.Khan)intheNorthwestFrontierProvince(NWFP)ofPakistantocomparevariousmanagementpractices,suchastheeffectofvariousorganicmanuresandgypsuminarice-wheatcroppingsystemonasaline-sodicEntisol(Zindanisoilseries).Thetreatmentsconsistedof1)acontrol(rice-wheat),2)gypsum,3)farmyardmanure(FYM),4)berseem(TrifoliumalexandrinumL.)asgreenmanure(GM),and5)dhancha(Sesbaniasp.)asGM.Alltreatmentsincreasedyieldsofbothriceandwheatsignificantly(P＜0.01)overthecontrol,withthegreenmanuretreatmentsprovingmoreeconomicalthantheothers;whiletheydecreasedpH,electricalconductivity(EC),andsodiumadsorptionratio(SAR)ofthesoil.Saturationpercentageandavailablewaterofthesoilwereraisedforalltreatmentsduetoanincreaseinorganicmattercontentofthesoil.

简介：Organicmatterwasexperimentallyextractedbysupercriticalfluids(CO2+1%isopropanol)frompetroleumsourcerocksofdifferentthermo-maturitiesatdifferentburieddepthsinthesamestratigraphicunitintheDongyingBasin.Theresultsshowthatsupercriticalfluidextraction(SFE)ismoreeffectivethanSoxhletextraction(SE),withhigheramountsandgreatervarietiesofhydrocarbonsandsolubleorganicmatterbecomingextractive.ThesupercriticalCO2extractionisthereforeconsideredmorevaluableinevaluationofpetroleumsourcerocksandoilresources,particularlythoseofimmaturetypes.

简介：Anewinorganic-organichybridtetravanadate[Co(2,2′-bpy)3]2V4O12·11H2O(1)hasbeenpreparedandcharacterized.X-Raydiffractionstudyrevealsthatcompound1containsclassicalclusteranions[V4O12]4–,coordinatedcations[Co(2,2′-bpy)3]2+andelevenwatermolecules,inwhichaninterestingdecamerwaterclusterisformed.Thehybridnanoparticleswerefirstlyusedasabulk-modifiertofabricateachemicallymodifiedpasteelectrode(1-CPE).Theelectrochemicalbehaviorandelectrocatalysisof1-CPEhavebeenstudiedindetail.Theresultsindicatethat1-CPEhasagoodelectrocatalyticactivitytowardthereductionofbromateina0.5mol/LH2SO4aqueoussolution.1-CPEshowsremarkablestabilitythatbeascribedtothehydrogenbondinginteractionsbetweenV4O12clusterandwatercluster,whichareveryimportantforpracticalapplicationinelectrodemodification.

简介：Changesofsoilorganicnitrogenformsandsoilnitrogensupplyundercontinuousricecroppingsystemwereinvestigatedinalong-termfertilizationexperimentinJinhua,ZhejiangProvince,China.ThefertilizertreatmentsincludedcombinationofP-K,N-K,N-P,andN-P-Kaswellasthecontrol.Aftersixyearsofcontinuousdouble-ricecropping,totalsoilNandhydrolysableNcontentsremainedstableinplotswithNtreatments,whilethehydrolysableNcontentsweresubstantiallyreducedinthoseplotswithoutNapplication.Comparedtotheunbalancedfertilizationtreatments,PandKincreasedthepercentageofhydrolysableammoniumNinthetotalsoilNwiththebalancedapplicationofN,andalsomaintainedhigherricegrainyieldsandnitrogenuptake.GrainyieldwaspositivelycorrelatedwithtotalNuptake(r=0.875**),hydrolysableN(r=0.608**),hydrolysableammoniumN(r=0.560**)andthehydrolysableunknownN(r=0.417**).TotalNuptakewaspositivelycorrelatedwithhydrolysableN(r=0.608**),hydrolysableammoniumN(r=0.440**)andhydrolysableunknownN(r=0.431**).Soilnutrientdepletionand/orunbalancedfertilizationtoricecropreducedNcontentinsoilmicrobialbiomass,andthereforeincreasedC/Nratio,suggestinganegativeeffectonthetotalmicrobialbiomassinthesoil.

简介：经由到河口的河的器官的碳的运输是在全球碳周期的一个重要geochemical过程。这份报纸论述体积总数从Dongjiang集水的器官的碳(TOC)到邻近的Humen插头，并且在表面沉积为有机物的来源作为指示物讨论13C的适用性和碳的比率到氮(C/N)。调查结果证明在夏天的器官的碳集中比在冬季高。TOC的一个提高的趋势在调查，和最高吝啬的价值沿着河发生了到Humen插头溶解，特别的器官的碳(DOC279摩尔L1和POC163摩尔L1)在夏天洪水流动在城市的三角形的区域被观察。冬季样品有大量13C和C/N(13C24.6～30.0，C/N413)，并且夏天一稍微变化了(13C24.2～27.6，C/N618)。当结果建议在upstream-delta-outlet的三个地区的那个停靠港主导地来自河岸土壤，浮游植物和农业C3在冬季种，而主要来源在夏天从河岸和红树属植物土壤。而且，人为的污水输入有11%和7%贡献到停靠港在三角形并且插头。伴有季节的淡水变化，浮游植物生产和降级的运输，和移动行为引起了器官的碳集中的变化。结果也发现在Dongjiang的那TOC出口体积是在干燥流动的Humen流动的约一个季度，并且人为的活动显著地影响了河出口贡献。

简介：Acyano-substituteddiarylethlenederivativeaggregation-inducedemission(AIE)dyewithtwoaminoend-groupsand4,4'-(hexafluoroisopropylidene)diphthalicanhydridewerefacilelyincorporatedintoredfluorescentorganicnanoparticles(FONs)viaroomtemperatureanhydridering-openingpolymerizationunderanairatmosphere.TheseobtainedRO-HFDAFONswerecharacterizedbyaseriesoftechniquesincludinggelpermeationchromatography,Fouriertransforminfraredspectroscopy,sizedistributionandzetapotentialmeasurements,UV-Visabsorptionspectrum,fluorescentspectroscopyandtransmissionelectronmicroscopy.BiocompatibilityevaluationandcelluptakebehaviorofRO-HFDAFONswerefurtherinvestigatedtoexploretheirpotentialbiomedicalapplication.WedemonstratedthatsuchFONsshowedhighwaterdispersibility,stableuniformsphericalmorphology(150-200nm),broadexcitationband(350-605nm),intenseredfluorescence(627nm)andexcellentbiocompatibility,makingthempromisingforcellimagingapplications.

简介：在这研究，有机物(OM)和在来自北华南海(SCS)的表面沉积的类脂化合物biomarkers的内容和分发被识别揭示有细密纹理的沉积的来源和运输。有机物和类脂化合物biomarkers在北SCS展出了不同空间变化。来自在西南的台湾的珍珠河和一些多山的河的陆上的分泌物可以在相应的海区域贡献相对高的有机物。不饱和的丰满的酸相当或相同事物的察觉建议了海藻或细菌的OM贡献到表面沉积。类脂化合物biomarkers的composites和分发从陆上的植物显示他们的混合来源，海洋的水藻并且细菌。和在沉积的泥土矿物质composites的证明，结果建议包括广东沿海的水流和自台湾东面的菲律宾海流向日本的暖流电流，水流在北SCS控制陆上的沉积和沉积环境的运输和分发。

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简介：Metal-organicframeworks(MOFs)haveattractedmuchattentionasadsorbentsfortheseparationofCO2fromfluegasornaturalgas.Here,atypicalmetal-organicframeworkHKUST-1(alsonamedCu-BTCorMOF-199)waschemicallyreducedbydopingitwithalkalimetals(Li,NaandK)andtheywerefurtherusedtoinvestigatetheirCO2adsorptioncapacities.Thestructuralinformation,surfacechemistryandthermalbehaviorofthepreparedadsorbentsampleswerecharacterizedbyX-raypowderdiffraction(XRD),thermo-gravimetricanalysis(TGA)andnitrogenadsorption-desorptionisothermanalysis.TheresultsshowedthattheCO2storagecapacityofHKUST-1dopedwithmoderatequantitiesofLi+,Na+andK+,individually,wasgreaterthanthatofunmodifiedHKUST-1.ThehighestCO2adsorptionuptakeof8.64mmol/gwasobtainedwith1K-HKUST-1,anditwasca.11%increaseinadsorptioncapacityat298Kand18barascomparedwithHKUST-1.Moreover,adsorptiontestsshowedthatHKUST-1and1K-HKUST-1displayedmuchhigheradsorptioncapacitiesofCO2thanthoseofN2.Finally,theadsorption/desorptioncycleexperimentrevealedthattheadsorptionperformanceof1K-HKUST-1wasfairlystable,withoutobviousdeteriorationintheadsorptioncapacityofCO2after10cycles.

简介：Laserinsituscatteringandtransmissometry(LISST)significantlyimprovesourabilitytoassessparticlesizedistribution(PSD)inseawater,whilewide-rangingmeasurementsoftheorganic-inorganiccompositionsofsuspendedparticulatematters(SPM)arestilldifficultbyusingtraditionalmethodssuchasmicroscopy.Inthisstudy,PSDpropertiesandSPMcompositionsaroundtheBohaiStrait(China)wereinvestigatedbasedonthemeasurementsbyLISSTincombinationwithhydro-biologicalparameterscollectedfromafieldsurveyinsummer2014.FourtypicalPSDshapeswerefoundintheregion,namelyright-peak,left-peak,double-peakandnegative-skewshapes.Thedouble-peakandnegative-skewshapesmayinterconvertintoeachotheralongwithstronghydrodynamicvariation.IntheupperlayeroftheBohaiSea,organicparticleswereinthemajority,withinorganicparticlesrarelyobserved.Inthebottomlayer,SPMwerethemixtureoforganicandinorganicmatters.LISSTprovidedvaluablebaselineinformationonsize-resolvedorganic-inorganiccompositionsofSPM:thesizeoforganicparticlesmainlyrangedfrom4to20μmand40to100μm,whilemostSPMrangingfrom20to40μmwerecomposedofinorganicsediment.

简介：Theworldwideinterestinthegutmicrobiomeanditsimpactontheupstreamliverhighlightacriticalupsidetobreathresearch:itcanuniquelymeasureotherwiseunmeasurablebiology.Bacteriamakegases[volatileorganiccompounds(VOCs)]thataredirectlyrelevanttopathophysiologyofthefattyliverandassociatedconditions,includingobesity.MeasurementoftheseVOCsandtheirmetabolitesintheexhaledbreath,therefore,presentanopportunitytosafelyandeasilyevaluate,onbothapersonalandapopulationlevel,someofourmostpressingpublichealththreats.Thisisanopportunitythatmustbepursued.Todate,however,breathanalysisremainsaslowlyevolvingfieldwhichonlyoccasionallyimpactsclinicalresearchorpatientcare.Onemajorobstacletoprogressisthatbreathanalysisisinherentlyandemphaticallymutli-disciplinary:itconnectsengineering,chemistry,breathmechanics,biologyandmedicine.Unbalancedorincompleteteamsmayproduceinconsistentandoftenunsatisfactoryresults.Asecondimpedimentisthelackofawell-knownstepwisestructureforthedevelopmentofnon-invasivediagnostics.Asaresult,thebreathresearchlandscapeisrepletewithorphanedsingle-centerpilotstudies.Often,importanthypothesesandkeyobservationshavenotbeenpursuedtomaturation.ThispaperreviewstherationaleandrequirementsforbreathVOCresearchappliedtothegut-fattyliveraxisandofferssomesuggestionsforfuturedevelopment.

简介：在土壤的变化在牧场的器官的碳(SOC)广泛地被调查了。在无关的牧场区域放牧在生态系统功能上引起了严重影响。揭示在SOC上放牧的效果，我们在XilinGol联盟评估了草地，内部蒙古，中国。放牧紧张被在擦伤时期与规范的差别使用植被索引的二个图象集合决定(7月12日并且第28)。在植被索引的变化的范围然后被用来测量放牧紧张。SOC存储和密度被在地土壤样品上进行实验获得。结果显示出那1)在XilinGol联盟的放牧紧张从西方逐渐地衰退了到东方；由对比，SOC密度的空间分发逐渐地增加了。2)当放牧紧张增加了，牧场的碳存储显然减少了。最小的碳存储在在极端过度放牧下面分类的草地被观察；由比较，最大的价值在在过度放牧到中等放牧的光下面分类的区域被发现。3)估计的土壤碳存储是8.48猯灵?￡?補?補？？

简介：Theeffectsofpeptides,aminoacidsandorganicbasesasanaxialligandonreactionac-tivitiesintheelectrocarboxylationofbenzylchloridewithCO2catalyzedbyCoTPParereported.Theimidazoleorganicbase,peptidecontaining—SHandaminoacidcontainingimidazolylen-hancethecatalyticactivity.TheeffectofimidazoleamountsonthecatalyticactivityofCoTPPisstudied.

简介：三新混合器官/无机的聚合ligand交换chiral静止阶段被激进的链转移反应和表面grafting在硅石胶化上开发，并且成功地为dl氨基的酸和dl氢氧根酸的enantioseparations使用了。决定被使用包含2.0×的水完成10?是的CuAc2的4mol/L一个活动阶段，40°C的列温度，1.0mL/min和察觉在的流动率紫外254nm。在l异构体前的d异构体的elution顺序为除了dl职业人员，解决的所有dl氨基的酸被观察。

简介：在Alq(3)层的洞传导性上做的2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane(F4TCNQ)的效果被测量。在Alq(3)的洞唯一的设备，当前的密度在与F4TCNQ做之上在1-3数量级增加，建议做的罐头有效地提高Alq(3)的洞注射和洞运输能力。用F4TCNQ的一台器官的轻射出的设备做了Alq(3)洞注射和洞运输层，和太古的Alq(3)作为电子运输和射出的层被制作并且描绘的层。明亮的排放作为电子运输和射出的层作为洞运输层和内在的Alq(3)与做p的Alq(3)在简单OLED被完成。设备的射出的效率和亮度被插入薄电子块层在器官的层的中间限制搬运人再结合地区进一步改进。

简介：因为它的高收益潜力，到边缘的地点的改编，和忍耐，Switchgrass(PanicumvirgatumL.)作为持续bioenergy庄稼被建议了到水和滋养的限制。生物资源精力庄稼生产的潜在的效果的更好的理解在土壤上练习生物性质，有机物动力学对它的生产批评。我们的目的在学院车站，达拉斯，和Stephenville是与成长得典型地的庄稼相比在不同土壤在温暖季节的长期的switchgrass下面在C水池评估变化镇定的，在2001年2月的TX。采样深度是05，515，和1530厘米。Switchgrass增加了土壤器官的C(SOC)，玷污微生物引起的生物资源C(SMBC)，mineralizableC，和与常规收割相比的微粒有机物C(POM-C)系统。土壤C集中在顺序：长期的沿海的bermudagrass[Cynodondactylon(L.)Pers.]switchgrass1997>常规收割系统。土壤C集中趋于与增加泥土内容增加。更大的微生物引起的生物资源C跟随了达拉斯的顺序>学院车站>Stephenville，并且在达拉斯在Stephenville从约180mgCkg1土壤到1900mgCkg1土壤。微粒器官的C比对管理的另外的部分更敏感，像在与常规收割系统相比的长期的沿海的bermudagrass下面的6褶层一样增加。我们的学习显示进switchgrass生产的常规收割系统的变换能扣押更多的SOC并且改进土壤在南部的美国的生物性质。

简介：Concentrationsoforganicmatter,ironandmanganeseinthedeepseasurfacesedimentsintheNanshaIslandsseaarea,SouthChinaSeaaremeasured.Horizontalandverticaldistributionsofironandmanganesearediscussed.Theverticaldistributionofironandmanganeseinthesedimentsresultsfromreduction,diffusion,andredepositionofmanganese(oriron)oxideandhydroxideinthesediment.Therearethemaximaofironandmanganeseinsolidphaseinthetopofthesediment,whichiscausedbythepenetrationofO2andtheupwardfluxofMn2+(orFe2+).Manganesebacteriaplayaveryimportantroleinthecycleofsolid-phaseironandmanganeseintheoceanenvironment.ManganesebacteriaoxidizeMn2+(orFe2+)indissolvedstatetoMn4+(orFe3+)inoxidizedstateundertheaerobiccondition,whereastheyreduceironandmanganeseinanaerobicconditions.