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简介：AuseofSulfonateesterasalinkerinsynthesisofω-aminoalkanolswasreported.Diolsweretetheredontopolystyrylsulfonylchlorideresin,yieldingsulfonateresins(2).Aftercleavedbydiethylamine,diisopropylamineandpropylaminerespectively,threeω-aminoalkanolswereobtained.

简介：Thetetravalentmetalsaltsofmonoalkylphosphates[M(R-OPO3)2]areanewkindofstationaryphasesofchromatography-homogeneousbondedphases.Thestudiesonpreparation,structureandgaschromatographicefficiencyofceriumbis(octylphosphate)(COPP)arereportedinthispaper.Byusingchemicalanalysis,infraredspectra,x-raydiffractionanalysis,thestrongevidencethatCOPPhasalayeredstructureoftheα-zirconiumphosphatetypewasdemonstrated,therepetitiveunitisC8H17OPO3CeO3POC8H17andthereisalittlebendingorinterpenetrationofthealkylchainswithinthelayers.ThethermogravimeticanalysisoftheCOPPindicatedthatithasmuchmorethermalstabilitythansilica-basedpackings.ThethermodynamicparametersΔHandmolecularconnectivityindexesx′fortheadsorptionofseveraldozencompoundsontheCOPPhavealsobeendeterminedbygaschromatographicmethod,andthefinelinearitybetweenthemwasshown.

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简介：Thisreviewdealswiththepreparationandapplicationofpolymericsulfinateresinsasreactiveintermediateinsolidphaseorganicsynthesisandseparation.

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简介：多孔的碳膜是有利地通过polyacrylonitrile(平底锅)的热分解制作了先锋，它与没有模板的technique-thermally导致的阶段分离被准备。这些碳膜拥有层次毛孔，包括越过在矩阵以及在毛孔墙上的整个膜和小毛孔的细胞的macropores。氮吸附显示micropores(1.47和1.84nm)和mesopores(2.21nm)在碳膜内存在，导致他们象1062m2/g一样大的特定的表面区域。碳膜被用来基于他们层次毛孔结构和大特定的表面区域的优点从水的答案吸附器官的染料(甲基橘子，刚果红，和玫瑰精B)。膜向甲基橘子介绍选择吸附，是特别地引人注目的，其分子的尺寸(1.2nm)是比刚果红(2.3nm)和玫瑰精B(1.8nm)的那些小的。这吸引人的结果能被归因于在分子的尺寸和毛孔之间匹配尺寸，而非静电的吸引力的位的结构。而且，使用的碳膜能容易被改革由盐酸酸，和他们的恢复吸附比率上面甚至在第三个周期维持90%。这个工作可以经由一条没有模板的途径为基于碳的吸附物向一条新线路提供层次毛孔，它能有希望地被使用有选择地在水的自河移开染料沾染物。

简介：OrganicchelatingreagentinfluencesupontheredoxadsorptionofactivatedcarbonfibertowardsAu3-weresystematicallyinvestigated.TheexperimentalresultsindicatedthatthepresenceoforganicchelatingreagentonactivatedcarbonfiberstronglyaffectsadsorptioncapacityofactivatedcarbonfibertowardsAu3+.Thereduction-adsorptionamountofAu3+increasedthreetimesbythepresenceof8-quinolinol.Furthermore,Thereduction-adsorptionamountofAu3+dependedonthepHvalueofadsorptionandtemperature.

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简介：ThedynamiccompetititveadsorptionbehaviorsofdifferentbinaryorganicvapormixturesonACF-Psunderdifferentoperationconditonswereinvestigatedbygaschromatographyinthispaper,Thestudiedmixtruesincludedbenzene/toluene,toluene/xylene,benzene/isopropylbenzeneethlyacetate/tolueneandbenzene/ethylacetate.ExperimentalresultsshowthatvariousACF-Ps,aswithACF-W,canremovebothvaporsinbinaryvapormixtureswithover99%ofremovalefficiencybeforethebreakthroughpointofthemoreweaklyadsorbedvapor,Indynamiccompetitiveadsorption,themoreweaklyweakleadsorbedvapornoeonlypenetratesearly,butalsowillbedisplacedanddesorbedconsequentlybystrongeradsorbateandthereforeproducesarollingupinthebreakthroughcurve,TheACF-Pspreparedatdifferenttemperatuershavesomewhatdifferentadsorptionselectivity,Thefeedconcentrationratioofvapros,thelength/diameterratioandthethickofbedhaveeffectoncompetitiveadsorption.Thecompetitiveadsorptionabilityofavaporismainlyrelatedtoitsboilingpoint.Usually,thehighertheboilingpoint,thestrongerthevaporadsorbedonACF-P.

简介：Acyano-substituteddiarylethlenederivativeaggregation-inducedemission(AIE)dyewithtwoaminoend-groupsand4,4'-(hexafluoroisopropylidene)diphthalicanhydridewerefacilelyincorporatedintoredfluorescentorganicnanoparticles(FONs)viaroomtemperatureanhydridering-openingpolymerizationunderanairatmosphere.TheseobtainedRO-HFDAFONswerecharacterizedbyaseriesoftechniquesincludinggelpermeationchromatography,Fouriertransforminfraredspectroscopy,sizedistributionandzetapotentialmeasurements,UV-Visabsorptionspectrum,fluorescentspectroscopyandtransmissionelectronmicroscopy.BiocompatibilityevaluationandcelluptakebehaviorofRO-HFDAFONswerefurtherinvestigatedtoexploretheirpotentialbiomedicalapplication.WedemonstratedthatsuchFONsshowedhighwaterdispersibility,stableuniformsphericalmorphology(150-200nm),broadexcitationband(350-605nm),intenseredfluorescence(627nm)andexcellentbiocompatibility,makingthempromisingforcellimagingapplications.

简介：4-hydroxy-4'-nitroazobenzene(NHA)and4-amino-4'-nitroazobenzene(DO3)werepreparedrespectivelyfromp-nitrophenylamineasaprecursorcompound.Twokindsofdopedorganic/inorganichybridnonlinearoptical(NLO)materialscontainingNHAandDO3weresynthesizedbySol-Gelprocess.ThepreparationandpropertiesoftwoNLOmaterialswerestudiedandcharacterizedbyFTIR,1H-NMR,UV-VIS,SEM,DSCandSHGmeasurements.TheresultsshowthatthemaximumdopingamountsofNHAandDO3intwodopedhybridNLOmaterialsare7.2(wt)%and11.3(wt)%respectively,andthecorrespondingsecond-orderNLOcoefficients(d33values)are2.91×10-8esuand6.14×10-8esu.TwodopedNLOmaterialshaverelativelygoodRTstability,after90daysatRTthed33valuescanmaintainabout85%oftheirinitialvalues,butafter10hat100℃canonlymaintainabout50%oftheirinitialvalues.Inthisreport,thereasonsforhigh-temperatureinstabilityofdopedmaterialswerediscussed,andthepossibleimprovementswerealsosuggested.

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简介：利用methoxysilyl一半的水解作用和冷凝作用，器官无机的混血儿(N-isopropylacrylamide-co-acrylamide-co-3-(trimethoxysilyl)propylmethacrylate)poly，P(NIPAM-co-AM-co-TMSPMA)microgels经由二个不同方法被准备。第一个方法是microgels是从crosslinkable的fabricated以后线性P(NIPAM-co-AM-co-TMSPMA)terpolymer在terpolymer的更低的批评答案温度(LCST)上面的水的答案。为第二个方法，microgels被常规表面活化剂直接综合NIPAM，AM，和TMSPMA的免费乳剂copolymerization。结果的P(NIPAM-co-AM-co-TMSPMA)microgels的水动力学直径和稳定性强烈取决于microgel的pH和温度水的答案。microgels的水动力学直径与增加测量温度减少了。microgels的阶段转变温度被发现在34附近吗？？

简介：一系列新奇低乐队差距施主领受人(D-A)类型在主要的链(M1)并且在由电子缺乏的领受人块组成的器官的共聚物(BT-F-TPA，BT-CZ-TPA和BT-SI-TPA)悬挂(M2)是与不同电子富人一起的polymerized施主(M3M5)块，即，9,9-dihexyl-9H-fluorene，N-alkyl-2,7-carbazole，和2,6-dithinosilole，分别地经由铃木方法。这些聚合物展出了相对低的乐队差距(1.651.88eV)和宽广吸收范围(680740nm)。作为电子施主合并这些聚合物的体积异质接面(BHJ)太阳能电池，相配与[6,6]-phenyl-C61-butyric酸甲基酉旨(PC61BM)或[6,6]-phenyl-C71-butyric酸甲基酉旨(PC71BM)作为在不同重量的电子领受人，比率下面被制作并且测试与白光的照明的AM1.5的100mW/cm2。包含施主BT-SI-TPA和领受人PC71在1:2重量比率的BM显示出1.88%的最好的力量变换效率(PCE)值，与开的电路电压(Voc)=0.75V，短路电流密度(Jsc)=7.60妈/厘米2,并且充满因素(FF)=33.0%。

简介：Efficientdeep-redorganiclight-emittingdiodes(OLEDs)wereinvestigatedbasedontheblendofpoly[2-methoxy-5-(2'-ethyl-hexyloxy)-l,4-phenylenevinylene](MEH-PPV)with4,7-bis(5-(7-(9H-carbazol-9-yl)-9,9-dioctyl-9H-fluoren-2-yl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole(compound1).Byoptimizingtheblendratio,theturn-onvoltageofthedeviceswassignificantlyreducedfrom4.9Vto2.4V.Ahighestexternalquantumefficiencyof2.56%wasachievedatablendratioof95:5(wt)forcompound1:MEH-PPV.TheCIEcoordinatewasmeasuredtobe(0.70,0.30),withtheluminescencepeakataround680nm.Basedonexperimentalobservationstheimprovementmechanismisdescribed.

简介：Two-dimensional(2D)materialshavebeendemonstratedtoexhibituniquepropertiesoriginatingfromits2Dnature.Inrecentyears,theconstructionof2Dmaterialshasbecomeatopicofgreatinterest.Thisarticlesummarizestherecentadvanceof2Dsupramolecularorganicframeworks(SOFs)whicharehomogeneouslyconstructedinsolutionphasethroughself-assemblyofrationallydesignedbuildingblocks.These2DSOFsaresolubleandstillmaintainstablenetworkstructuresinsolutions,whichexhibituniquenessnotonlyinstructuresbutalsoinproperties.Inthisconcisereview,theSOFs-relatedbackgroundisbrieflyintroducedfirstly,followedbyoutliningtheresearchprogressofsoluble2DSOFsfromtheperspectiveofmonomerdesign,assembly,andstructuralcharacterization.Thearticleendswithapersonaloutlookonthefuturedevelopmentofthisnewclassofsupramolecularpolymers.

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简介：ItwasgenerallyconsideredthatcontaminationofthegeltypepolystyrenestrongbasicanionexchangeresinbyorganicmatterinnaturalwateristheresultofionexchangeandVanderwaal′sadsorptiononit.Onthebasisoflaboratoryandindustrialexperiments,thispaperconfirmedthattheinterreactionbetweenorganicmatterandresinpolymermatrixisprimarilycontroledbyaVanderwaal′sadsorption.