学科分类
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245 个结果
  • 简介:Hybridorganic-inorganicperovskites(e.g.CH3NH3PbI3)haveattractedtremendousattentionduetotheirpromiseforachievingnext-generationcosteffectiveandhighperformanceoptoelectronicdevices.Thesehybridorganic-inorganicperovskitespossessexcellentopticalandelectronicproperties,includingstronglightabsorption,highcarrierabilities,optimizedchargediffusionlengths,andreducedchargerecombinationetc.,leadingtotheirwidespreadapplicationsinadvancedsolarenergytechnologies(e.g.highefficiencyperovskitesolarcells).However,thereisstillalackofinvestigationsregardingfundamentalpropertiessuchasferroelectricityintheseperovskites.Asconventionalferroelectricceramicsarepreparedathightemperatureandhavenomechanicallyflexibility,low-temperatureproceedandflexibleperovskiteferroelectricshavebecomepromisingcandidatesandshouldbeexploitedforfutureflexibleferroelectricapplications.Here,ferroelectricpropertiesinhybridorganic-inorganicperovskitesandseveralstate-of-theartperovskiteferroelectricsarereviewed.Novelferroelectricapplicationsofhybridorganic-inorganicperovskitesarediscussedaswell,providingguidelineforrealizingfuturehighperformanceandflexibleferroelectricdevices.

  • 标签: FERROELECTRICITY FERROELECTRIC materials FLEXIBLE DEVICES ORGANIC-INORGANIC
  • 简介:Citricandmalicacidsatconcentrationsof0.1,1.0,10,and100mmol/LwereaddedtothreeUltisolsandoneOxisol,TheamountofPinsolutionincreasedwithincreasingorganicacidconcentrations,whiletheamountofFe-andAl-boundPdecreased.ThisresultsuggestedthatnaturallyoccurringproductsoforganicmatterdecompositioncouldincreasethePavailabilitytoplantsinsoilswherethereisarelativelylargepoolofFe-andAl-boundP.Theinteractionsbetweencitricandmalicacidsattheaboveconcentrations,andpaddedatratesof10,20,40,and80mg/kgweredetermined.Atzerolevelsoforganicacids,alladdedPbecameeitherlabileorbound,andgreaterproportionsremainedsolubleastheconcentrationoforgaicacidsincreased,whichsuggestedthatorganicacidsreducedfixationofdissolvedPinFe-andAL-richsoils.AgriculturalpracticeswhichincreaseorganicmatterinputonP-deficientacidsoildcoulddecreasePdeficiency,Thiswouldbeimportantinmanytropicalandsubtropicalregionswherethesesoilsarecommon,andwherethecostsoffertilizersandlimearerelativelyhigh.

  • 标签: 氧化土 老成土 酸性土壤 天然有机酸 磷代谢 土壤磷
  • 简介:Theepoxynanocompositeswithsimilaramines(CH_3(CH_2)_(17)NH_2andCH_3(CH_2)_(17)N(CH_3)_3CI)treatedmontmorilloniteclayshavebeeninvestigatedbywide-angleX-rayscattering,transmissionelectronmicroscopy(TEM),differentialscanningcalorimetry(DSC)andthermalgravimetricanalysis(TGA).Differentnanocompositestructures,intercalationandexfoliationwereformedbythereactionofoctadecyltrimethylammoniumchloride-exchangedandoctadecylamine-exchangedclayswithepoxyresinandphenalkamineasthecuringagent,respectively.Resultsshowedthattheexfoliatednanocompositecanbeobtainedwhenoctadecylaminewiththelowerpolaritywasusedasamodifier.However,theintercalatednanocompositecanbeobtainedwhenoctadecyltrimethylammoniumchloridewithhigherpolaritywasusedasamodifier.

  • 标签: 纳米复合结构 有机改性剂 环氧树脂 复合材料结构 十八烷基三甲基氯化铵 插层纳米复合材料
  • 简介:荧光刺激和可溶的有机物(WSOC)样品从20提取了的46水的平均分子的重量在东方中国玷污类型被决定。它被发现所有样品分享类似的光谱学。一种好线性关系不过在350~450nm的范围在全部的器官的碳和刺激之间存在器官的碳的内容和样品的pH在一个宽范围变化。在相对刺激紧张和WSOC和FA的平均分子的重量之间的重要关联都没被发现,但是部分关联为WSOC样品作为控制因素与pH变得重要。相对刺激紧张显示出在学习区域从南方增加到北方的一个一般趋势。pH价值可能在调整起一个重要作用荧光灯WSOC的空间变化。

  • 标签: EASTERN China soil water SOLUBLE ORGANIC
  • 简介:在每个分解阶段的森林土壤性质上的崽秋天和它的效果在热带季风被调查三种植园(7年的相思树种植园,15年的相思树种植园和18年的混合种植园)和从孟加拉国的Chittagong多山的区域的一个自然森林(Sitapahar森林)的气候的条件。结果证明有机物的全部的累积与种植园年龄增加了,与年度累积率的减少伴随。在一样的植被类型以内,有山上的显著地改变的腐植质(p≤0.05)的新鲜、部分分解的垃圾的器官的累积放,在底部斜坡上是最高的并且在森林里向山顶逐渐地减少。在土壤有机物的累积的反向的趋势在15年的相思树auriculiformis种植园,燃料木头在哪儿收集了被显示出。在7年、15年的相思树和18年的混合宽广离开的种植园,全部的有机物生产由组成评价新鲜,在土壤的部分并且完全分解的垃圾以及合并有机物是2554.31,705.79和1028.01kg·h−1·a−1,分别地,并且从新鲜垃圾的相应贡献是38.23,19.40和30.48kg·h−1·a−1,分别地。在三种植园和自然森林,在一般水准上,新鲜垃圾组成了32.45%,部分与腐植质13.50%分解了垃圾并且合并了在有0.90厘米的吝啬的崽厚度的土壤54.56%全部的有机物生产的有机物。土壤酸味随有机物的分解舞台的增加增加了。

  • 标签: 干物质积累 大港地区 孟加拉国 森林
  • 简介:AuseofSulfonateesterasalinkerinsynthesisofω-aminoalkanolswasreported.Diolsweretetheredontopolystyrylsulfonylchlorideresin,yieldingsulfonateresins(2).Aftercleavedbydiethylamine,diisopropylamineandpropylaminerespectively,threeω-aminoalkanolswereobtained.

  • 标签: 固相有机物 合成
  • 简介:Thetetravalentmetalsaltsofmonoalkylphosphates[M(R-OPO3)2]areanewkindofstationaryphasesofchromatography-homogeneousbondedphases.Thestudiesonpreparation,structureandgaschromatographicefficiencyofceriumbis(octylphosphate)(COPP)arereportedinthispaper.Byusingchemicalanalysis,infraredspectra,x-raydiffractionanalysis,thestrongevidencethatCOPPhasalayeredstructureoftheα-zirconiumphosphatetypewasdemonstrated,therepetitiveunitisC8H17OPO3CeO3POC8H17andthereisalittlebendingorinterpenetrationofthealkylchainswithinthelayers.ThethermogravimeticanalysisoftheCOPPindicatedthatithasmuchmorethermalstabilitythansilica-basedpackings.ThethermodynamicparametersΔHandmolecularconnectivityindexesx′fortheadsorptionofseveraldozencompoundsontheCOPPhavealsobeendeterminedbygaschromatographicmethod,andthefinelinearitybetweenthemwasshown.

  • 标签: 有机轻元素吸附剂 稀土元素吸附剂 二辛基磷酸铈
  • 简介:Themechanismofcarriertransportinorganiclight-emittingdevicesisnumericallystudied,onthebasisoftrappedcharge-limitedconductionwithanexponentialtrapdistribution.Thespatialdistributionsoftheelectricalpotential,fieldandcarrierdensityintheorganiclayerarecalculatedandanalysed.Mostcarriersaredistributednearthetwoelectrodes,onlyafewofthemaredistributedovertheremainingpartoftheorgaiclayer,Thecarriersareaccumulatedneartheelectrodes,andtheremainingregionisalmostexhaustedofcarriers.Whenthecharacteristicenergyoftrapdistributionisgreaterthan0.3eV.itleadstoareductionofcurrentdensity.Inordertoimprovethedeviceefficiency,organicmaterialswithminortrapsandlowcharacteristicenergyshouldbechosen.Thediffusioncurrentisthedominantcomponentneartheinjectionelectrode.whereasthedriftcurrentdominatestheremainingregionoftheorganiclayer.

  • 标签: 有机光发射器件 载流子迁移机制 数字分析
  • 简介:TheroleoforganicmatterintheformationandstabilityofsoilaggregatesinmulberryplantationintheHang-Jia-HuPlain,northernZhejiangProvince,wasevaluatedinthisstudy.Apositivecorrelationwasfoundbetweenwater-stableaggregatecontentsandorganicmattercontentsinthemulberryplantationsoils,whichsupportedthehypothesisthatorganicmatterwasthemaincementingagentinformationofaggregates.Aclosecorrelationwasalsofoundbetweenstabilityofaggregateandorganicmattercontents.Regressionanalysisshowedthattotalnitrogencontentwasalsoanindicatorofwater-stableaggregatecontentandstability.Theaggregatesizedistributionindicatedthatthewater-stableaggregates1~0.25mmindiameterwerethemajorcomponentoftheaggregatesinthemulberryplantationsoils.Theorganicmattercontentsofaggregatesrangingfrom5to0.25mmindiameterincreasedwiththedecreaseofaggregatesizes,andtheaggregates1~0.25mmindiameterhadthemaximumorganicmattercontent.

  • 标签: 桑椹种植地 有机物 土壤 形成 稳定性 水份
  • 简介:在这份报纸,器官的量井设备,无机的半导体类似于type-II量很好,被制作了,在里面它NPB(N,N鈥?Di-[(1-naphthalenyl)-N,N鈥?diphenyl]-(1,1鈥?biphenyl)-4,4鈥?diamine)和Alq3(Tris-(8-quinolinolato)铝)分别地充当潜在的障碍层和潜在的井层。在electroluminescence,有井宽度减少的光谱的蓝移动与不同的井宽度为设备被观察,并且这被量尺寸效果和激子监禁效果的联合解释。有增加应用电压的光谱的蓝移动为一样的设备被观察,并且这以极化效果和量尺寸效果被解释。CLC数字TN383+.1这个工作被中国的国家性质科学基础支持(60576016,10374001),中国(2003CB314707)的国家关键基本研究专辑基础,国家高技术研究和开发中国(2006AA0380412)编程序,北京城市自然科学基础(2073030),中国(10434030)的国家性质科学基础的关键条款,和北京交通大学的优秀医生鈥檚科技革新基础

  • 标签: 有机量子阱场致发光装置 光谱蓝移 势垒层 极化效应
  • 简介:Therectificationratiooforganicmagneticco-oligomerdiodesisinvestigatedtheoreticallybychangingthemolecularlength.Theresultsrevealtwodistinctlengthdependencesoftherectificationratio:forashortmoleculardiode,thechargecurrentrectificationchangeslittlewiththeincreaseofmolecularlength,whilethespin-currentrectificationisweakenedsharplybythelength;foralongmoleculardiode,boththecharge-currentandspin-currentrectificationratiosincreasequicklywiththelength.Thetwokindsofdependenceswitchataspecificlengthaccompaniedwithaninversionoftherectifyingdirection.Themolecularortibalsandspin-resolvedtransmissionanalysisindicatethatthedominantmechanismofrectificationsuffersachangeatthisspecificlength,thatis,fromasymmetricshiftofmoleculareigenlevelstoasymmetricspatiallocalizationofwavefunctionsuponthereversalofbias.Thisworkdemonstratesafeasiblewaytocontroltherectificationinorganicco-oligomerspindiodesbyadjustingthemolecularlength.更多还原

  • 标签: 旋转整流器 分子长度 依赖性 有机共聚物 分子二极管 自旋电流
  • 简介:Factoranalysisisusedtostudytheorganiccompoundsthathavehighdegreeofcorrelationwithbiomassinalgalblooming.Basedonthiscorrelation,theyarenamedcharacteristicorganiccompounds.Thecompoundsfoundaresequalene(SQU),cedrol(CED),2,5-cyclohexadiene-1,4-dione,2,6-bis(1,1-dimthylethyl)(PBQ),phenol,2,6-bis(1,1-dimethylethy-4-methyl)(BHT),3-t-butyl-4-hydroxyanisole(BHA),1,2-benzenedicarboxylieacid,bis-(2-methylpropyl)ester(DIBP),dibutylphthalate(DNBP),respectively.Monitoringthevariationsofconcentrationofthesecharacteristicorganiccompoundsinseawatermayprovidescientificbasisforstudyingandforecastingredtides.

  • 标签: 有机化合物 海藻 雪松醇 赤潮
  • 简介:Soilsamplesat0-10cmindepthwerecollectedperiodicallyatpairedfieldsinCorvallis,Oregon,USAtocomparedifferencesinsoilmicrobialandfaunalpopulationsbetweenorganicandconventionalagroecosystems.Resultsshowedthattheorganicsoilecosystemhadasignificantlyhigher(P<0.05)averagenumberorbiomassofsoilbacteria;densitiesofflagellates,amoebaeofprotozoa;somenematodes,suchasmicrobivorousandpredaceousnematodesandplant-parasiticnematodes;aswellasCollembola.GreaternumbersofRhabditida(suchasRhabditisspp.),werepresentintheorganicsoilecosystemwhilePanagrolaimusspp.werepredominantintheconventionalsoilecosystem.TheomnivoresandpredatorsofAcarinaintheMesostigmata(suchasDigamasellidaeandLaelapid),andProstigmata(suchasAlicorhaiidaeandRhagidiidae),werealsomoreabundantintheorganicsoilecosystem.However,fungivorousProstigmata(suchasTerpnacaridaeandNanorchestidae)andAstigmata(suchasAcarida)weresignificantlyhigher(P<0.05)intheconventionalsoilecosystem,whichsupportedthefindingthattotalfungalbiomasswasgreaterintheconventionalsoilecosystem.Seansonalvariationsofthepopulationdependedmostlyonsoilmoistureconditionandfoodwebrelationship.ThepopulationdeclinedfromMaytoOctoberforbothagroecosystems.However,higherdiversitiesanddensitiesofsoilbiotasurvivedoccurredintheorganicsoilecosysteminthedryseason.

  • 标签: 土壤生物区 农业生态系统 俄勒冈州 美国 有机质 微生物种群
  • 简介:ThecyclicvoltammetryandpotentiostaticelectrolysiswereusedtoinvestigatethepreparingofDy-BialloyfilmsinLiCl-DMSO(dimethylsulfoxide)system.Theeffectsofseveralfactorsincludingthepotentialofdeposition,concentrationsofmainsalts,andtheconcentrationratioofDyCl3toBi(NO3)3werestudied.Dy-Bialloyfilmscontaining4.82%-80.62%(massfraction)dysprosiumwerepreparedinDyCl3-Bi(NO3)3-LiCl-DMSOsystembycontrollingthesystemcompositionanddepositionconditions.Thefilmsaregray,uniform,metalliclusterandadherefirmlytothecoppersubstratesanalyzedbySEM(scanningelectronmicroscope),EDS(X-rayenergydispersiveanalysis),andXRD(X-raydiffraction).Afterheattreatmentat718Kforlh,thealloyphaseofDy-BiwasfoundinXRDpatterns.

  • 标签: 镝-铋合金膜 电化学沉积 有机电解质 制备 二甲亚砜 循环伏安法
  • 简介:ThehybridsensitizerrhodamineBandcoumarinoreosinandcoumarinisusedtosensitizenanocrystallineporousfilms.Absorptionofthenanocrystallinephotovoltaiccell(NPC)isimprovedinvisiblelight.TheperformanceofthesecellsismoreeffectivethanthatofcellssensitizedonlybysensitizerrhodamineBoreosin.Inthesimulativesolarlight,cellsensitizedbyhybridsensitizerrhodamineBandcoumarincangetopencircuitvoltage(VOC)of550mVandshortcircuitcurrent(ISC)of0.1375mA/cm2.

  • 标签: 太阳能电池 感光剂 纳米晶 多孔渗水薄膜
  • 简介:Photoniccrystalslabsintegratedintoorganiclight-emittingdiodes(OLEDs)allowfortheextractionofwaveguidemodesandthusanincreaseinOLEDefficiency.WefabricatedlinearBragggratingswitha460-nmperiodonflexiblepolycarbonatesubstratesusingUVnanoimprintlithography.Ahybridorganic–inorganicnanoimprintresistisusedthatservesalsoasahighrefractiveindexlayer.OLEDscomposedofapoly(3,4-ethylenedioxythiophene)polystyrenesulfonate(PEDOT:PSS)polymeranode,anorganicemissionlayer[poly(p-phenylenevinylene)(PPV)-derivative'SuperYellow'],andametalcathode(LiF/Al)aredepositedontotheflexiblegratingsubstrates.TheeffectsofphotoniccrystalslabdeformationinaflexibleOLEDarestudiedintheoryandexperiment.Thesubstratedeformationismodeledusingthefinite-elementmethod.Theinfluenceofthechangeinthegratingperiodandthewaveguidethicknessunderbendingareinvestigated.Thechangeinthegratingperiodisfoundtobethedominanteffect.Atanemissionangleof20°achangeintheresonancewavelengthof1.2%ispredictedforastrainof1.3%perpendiculartothegratinggrooves.ThisvalueisverifiedexperimentallybyanalyzingelectroluminescenceandphotoluminescencepropertiesofthefabricatedgratingOLEDs.

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