简介：Theorganic/inorganicnanocompositespolymerelectrolytesweredesignedandsynthesized.Theorganic/inorganicnanocom-positesmembranematerialsandtheirlithiumsaltcomplexeshavebeenfoundthermallystablebelow200℃.Theconductivityoftheorganic/inorganicnanocompositespolymerelectrolytespreparedatroomtemperaturewasatmagnituderangeof10-6S/cm.

简介：OrganicmodifierswereeffectivebothtoextendthemigrationtimewindowandtoimprovetheseparationofveryhydrophobiccompoundsinMEKC.Aniterationmethodwasusedtodeterminethemigrationtimeofmicelles.Thequantitativerelationshipbetweenthecapacityfactork’andtheconcentrationoforganicmodifierswasderived,whichwasinvestigatedexperimentally.Thelinearsolvationenergyrelationships(LSER)methodologywasappliedtoMEKC,andgoodlinearrelationshipsbetweenInk’andsolvatochromicparametersof15soluteswereobtainedinthepresenceoforganicmodifierindifferentconcentrations,whichindicatedanewaccessinMEKCtopredictk’fromthestructuralparametersofsolutes.TheeffectofcolumntemperatureTonk’wasalsoinvestigated.

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简介：Theoreticalconsiderationwasproposedforthefrequencyresponseofaseriespiezoelectricsensortothepropertiesofliquidandverifiedexperimentally.Thiskindofsensorhassensitiveandselectivefrequencyresponsetothepermittivityandspecificconductivityofsolutionwithexcellentstability,andwasappliedtothedeterminationofmicro-contentofwaterinorganicsolvents.Thedetectionlimitis0.01g/Lindioxane.

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简介：Thepaperdealswiththedegradationoftheorganiccompoundsinthecokeplantwastewaterbythecombinedprocessofultrasonicirradiationandactivatedsludge.Theinfluencefactorsoftheultrasonicdegradationeffectsuchasairatmosphere,initialconcentration,ultrasonicpowerdensityandthecategoryandconsumptionofcatalystwereinvestigated.Awaterqualitymodelwasusedtoexplainthedegradationofdifferentkindsoforganiccompoundsinthecokeplantwastewaterbyultrasonicirradiation.Afterthewastewaterwastreatedbythecombinedprocessofultrasonicirradiationandactivatedsludge,theCODdegradationefficiencywas95.74%,whichis63.49%higherthanthatbytheprocessofactivatedsludgealone.

简介：ＨＥＡＴＳ　ＯＦ　ＩＮＴＥＲＡＣＴＩＯＮ　ＯＦ　ＯＲＧＡＮＩＣ　ＢＡＳＥＳ　ＷＩＴＨ　ＰＯＬＹＭＥＲ　ＰＲＯＴＥＣＴＥＤ　ＣＡＴＡＬＹＳＴ　ＰＶＣ－ＡｌＣｌ＿３ＨＥＡＴＳＯＦＩＮＴＥＲＡＣＴＩＯＮＯＦＯＲＧＡＮＩＣＢＡＳＥＳＷＩＴＨＰＯＬＹＭＥＲＰＲ...

简介：Opto-thermaltransientemissionradiometry(OTTER)isainfraredremotesensingtechnique,whichhasbeensuccessfullyusedininvivoskinmoisturecontentandskinmoisturedepthprofilingmeasurements.Inpresentpaper,weextendthismoisturecontentmeasurementcapabilitytoanalyzethemoisturecontentoffruit(tomato,grape,etc.)skins,andtostudytherelationshipbetweenfruitsripeningprocessandtheirsurfacemoistureandmoisturedepthprofiles.

简介：Theeffectsofvariousfactorsontheelectrocarboxylationoforganiccompoundswithcarbondioxidecatalyzedbymetalloporphyrinarestudied.Theoptimalpotentialofelectrocar-boxylationis-1.6V(vs.SCE).Aweakproticsolventmethanolcanenhancecatalyticactivity.Tetrabutylammoniumiodideisthebestoneoffiveelectrolytes.Theyieldsandcurrentefficienciesofelectrocarboxylationareincreasedslowlyastheconcentrationofcatalystincreases.

简介：ThemolecularsieveVPI-5wassynthesizedbyusingvariousorganicamines(DEA,Di-PA,DBA,DPenA,TBA,DEOAandTEOA)asthestructure-directingagent.TheuseofDPAenlargedtherangeofthecrystallizationtemperaturefrom110℃to190℃inthesynthesisofVPI-5,whiletheuseofTEOAchangedthecompositionofthereactantsinabroadvariety.DiaminesarethetypicalaminesinthesynthesisofVPI-5.AmongthemDBAandDPAarethemostfavoritestructure-directingagentsforthesynthesisofVPI-5molecularsieve.

简介：Aseriesofnovelamphibiousorganic/inorganichybridprotonexchangemembraneswithH3PO4dopedwhichcouldbeusedunderbothwetanddryconditionswaspreparedthroughasol-gelprocessbasedonacrylatedtriethoxysilane(A-TES)andbenzyltetrazole-modifiedtriethoxysilane(BT-TES).Thedual-curingapproachincludingUV-curingandthermalcuringwasusedtoobtainthecrosslinkedmembranes.Polyethyleneglycol(400)diacrylate(PEGDA)wasusedasanoligomertoformthepolymericmatrix.Themolecularstructuresofprecursorswerecharacterizedby1H,13Cand29SiNMRspectra.Thethermogravimetricanalysis(TGA)resultsshowthatthemembranesexhibitacceptablethermalstabilityfortheirapplicationatabove200oC.Thedifferentialscanningcalorimeter(DSC)determinationindicatesthatthecrosslinkedmembraneswiththemassratiosofbelow1.6ofBT-TEStoA-TESandthesamemassofH3PO4dopedasthatofA-TESpossessthe-Tgs,andthelowestTg(-28.9℃)existsforthemembranewithdoublemassofH3PO4dopedaswell.Thehighprotonconductivityinarangeof9.4―17.3mS/cmwiththecorrespondingwateruptakeof19.1%―32.8%ofthemembraneswasdetectedat90oCunderwetconditions.Meanwhile,theprotonconductivityinadryenvironmentforthemembranewithamassratioof2.4ofBT-TEStoA-TESanddoubleH3PO4loadingincreasesfrom4.89×10-2mS/cmat30℃to25.7mS/cmat140℃.Theexcellentprotontransportabilityunderbothhydrousandanhydrousconditionsdemonstratesapotentialapplicationinthepolymerelectrolytemembranefuelcells.

简介：Anewinorganic-organichybridtetravanadate[Co(2,2′-bpy)3]2V4O12·11H2O(1)hasbeenpreparedandcharacterized.X-Raydiffractionstudyrevealsthatcompound1containsclassicalclusteranions[V4O12]4–,coordinatedcations[Co(2,2′-bpy)3]2+andelevenwatermolecules,inwhichaninterestingdecamerwaterclusterisformed.Thehybridnanoparticleswerefirstlyusedasabulk-modifiertofabricateachemicallymodifiedpasteelectrode(1-CPE).Theelectrochemicalbehaviorandelectrocatalysisof1-CPEhavebeenstudiedindetail.Theresultsindicatethat1-CPEhasagoodelectrocatalyticactivitytowardthereductionofbromateina0.5mol/LH2SO4aqueoussolution.1-CPEshowsremarkablestabilitythatbeascribedtothehydrogenbondinginteractionsbetweenV4O12clusterandwatercluster,whichareveryimportantforpracticalapplicationinelectrodemodification.

简介：Theeffectsofpeptides,aminoacidsandorganicbasesasanaxialligandonreactionac-tivitiesintheelectrocarboxylationofbenzylchloridewithCO2catalyzedbyCoTPParereported.Theimidazoleorganicbase,peptidecontaining—SHandaminoacidcontainingimidazolylen-hancethecatalyticactivity.TheeffectofimidazoleamountsonthecatalyticactivityofCoTPPisstudied.

简介：三新混合器官/无机的聚合ligand交换chiral静止阶段被激进的链转移反应和表面grafting在硅石胶化上开发，并且成功地为dl氨基的酸和dl氢氧根酸的enantioseparations使用了。决定被使用包含2.0×的水完成10?是的CuAc2的4mol/L一个活动阶段，40°C的列温度，1.0mL/min和察觉在的流动率紫外254nm。在l异构体前的d异构体的elution顺序为除了dl职业人员，解决的所有dl氨基的酸被观察。

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简介：在这个工作，二个chemometrics方法被申请建模和一些器官、无机的混合物的electrophoretic活动性的预言。连续设计算法，特征选择(矿泉)策略，被用作描述符选择和模型发展方法。然后，支持向量机器(SVM)和多重线性回归(MLR)当模特儿被利用构造非线性、线性的量的structureproperty关系模型。用SVM模型获得的结果与用MLR获得的那些相比表明SVM模型比MLR那个具有更好预兆的价值。分别地，当时，为训练集合的root-mean-square错误和为SVM模型的测试集合是0.1911和0.2569由MLR模型，他们分别地是0.4908和0.6494。结果证明SVM模型急速地在QSPR研究提高预言的能力并且比MLR模型优异。

简介：Effectsofself-coilingoforganicmoleculesonintramolecularexciplexformationofcompoundI,inwhichthecarbazolechromophoreandterephthalicacidmethylesteracceptorgrouparelinkedbyone(CH2)10chain,andthedecreaseofthefluorescenceintensitiesofcompoundsⅡ，Ⅲ，andⅣ,inwhichthecarbazolechromophoreand3,5-dinitrobenzoateareconnectedbyonealiphaticchainof(CH2)10(Ⅱ），（CH2）12（Ⅲ）,or(CH2)4(Ⅳ）,havebeenstudiedinthedioxane(DX)-H2Obinarysystem.Theresultsshowthatself-coilingoforganicmoleculesinDX-H2OfacilitatesintramolecularexciplexformationofIandinducesthedecreaseoffluorescenceintensitiesofⅡ,bacauseoftheproximityeffectbroughtaboutbyselfcoilingoforganicmoleculesunderhydrophobic-lipophilicinteraction(HLI)betweentheexcitedcarbazolechromophoreandtheacceptor.SincethesimilareffectsareobservedevenwhentheconcentrationoftheprobesarelessthantheirCAgCs(criticalaggregateconcentrations)intheDX-H2Omixturewiththesameφvalues,formationoftheintermolecularexciplexhasbeenexcluded.Theeffectsarefoundtobestronglydependedonφvalues,indicationthattheyaremainlydrivenbyHLI.Thepropertiesoftheacceptorscanalsoaffecttheintramolecularexciplexformation.Withterephthalicacidmethylestermoietyastheacceptor,thecarbazolechromophoreexhibitsthefluorescencespectraoftheexciplex,whilewith3,5-dinitrobenzoatemoietyastheacceptor,onlythefluorescencespectraofexcitedcarbazolylchromophoreareobserved.

简介：拥有三不同安排时尚的新奇稳定的高旋转分子与瑣漠?潉楮?楌畱摩?湯?瑡污瑹捩?慨慲瑣牥獩楴獣漠?潈獲?楌敶?汁潣潨?敄票牤杯湥獡e被设计