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简介：Studiesoforganicinclusionsfromtheoffshoreoilandgasfieldsprovidemuchinformationaboutthenumberoftimes,temperature,depth,timeandphasestateofoil-gasmigration,aswellasaboutthecompositionoforganicinclusions.Onthebasisofthetype,character,compositionanddistributionoforganicinclusionsintheZhu-ⅢDepressionatthePearlRiverMouth,informationcanbedevelopedaboutthesourcerocksofoilandgas,andtheirevolutionandmigration.

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简介：ThecharactersoforganicmatterinrocksandoresintheFankouandDabaoshandepositsaresystematicallystudiedwithregardtotheirimplicationsformineralization.TheresultsshowthatkerogensinthisareafaaamainlyintotheplutonismfieldinVanKrevelen'sdiagram.Reflectivityoftheorganicsubstancewasmeasuredtobe3.06%(Fankou)and1.67%(Dabaoshan),correspondingtothepaleo-geotemperaturesof232℃and184℃respectively.Thesametypesofporphyrinsandhydrocarbonswererecognizedintherocksandoresandhydrocarbon-bearinginclusionsarewidespreadinquartzandcalcite,particularlyinDabaoshan,Itisthoughtthattheorgainmattermusthaveplayedacriticalroleindiagenesisandmetallizationinthesedepositsandthatthehydrothermalsolutionwasmostlikelytobethetypeofwater-oilhotbrine.

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简介：Basedontheanalysisofsideritedistribution,occurrence,chemicalcompositionk,structurealcharacteristics,carbon-oxygenisotopiccharacteristicsandrelationshipbetweensideriteandhematite,thispaperpresentsasystematicstudyofsideriteintheregionstudied.suggestingthatthesideriteintheXuanlongareageneticallyresultedfromorganicallyreducedprimaryhematiteduringthediagenesis.Theferricandferrousrelationsdirectlydependonorganiccontents.Inthepresenceoforganicmatterferrousironcanbeconvertedtoferricironthroughorganicreduction.Theaboveconclusionhasalsobeenprovedbyorganicgeochemistry.data.

简介：Understandingtheeffectsoforganicacids（OA）onthetransformationofFeandMntosurfacewaterfromtheweatheringcoalgangueisofgreatbene?ttoriskassessmentandremediationstrategiesforcontaminatedwaterandsoil.BasedontheinvestigationonsurfacewaterinthecentralcoaldistrictsoftheGuizhouProvince,18watersampleswerecollectedforheavymetalanalysis.TheresultsindicatedthatthepHvalueofsurfacewaterislow（3.11–4.92）,andFeconcentration(1.31–5.55mgL-1)andMnconcentration(1.90–5.71mgL-1)were,onaverage,10.86and34.33timesthelimitofSurfaceWaterQualityStandards,respectively.InordertoevaluatetheeffectsoftheOAonthedissolutionofFeandMnfromtheweatheringcoalgangue,columnelutionandbatchleachingexperimentswereconducted.Theresultsshowthatthelowmolecularweightoforganicacids（LMWOAs,i.e.,oxalic,tartaric,malicandcitricacids）andfulvicacidssigni?-cantlyacceleratedthedissolutionofFeandMn;inaddition,whentheconcentrationofOAreached25mmolL-1,theconcentrationsofFe,andMnwere1.14–67.08and1.11–2.32timesashighasthosein0.5mmolL-1OA,respectively.Furthermore,themigrationofFeandMnwassigni?cantlyin?uencedbythepHandEh,especiallyforFe;theionMnwasdissolvedfromtheganguemoreeasilythantheionFeinthecolumnleaching,whichwascontrarytotheresultsofbatchleaching.

简介：这研究处理了土壤的分发特征器官的碳(SOC)和有在六个土壤剖面的深度的稳定的碳同位素组成(delta~(13)C价值)的变化，包括在西南中国的石灰岩地区常见的地形区域的二个土类和三植被型。植物主导的种类的delta~(13)C价值，叶发出，土壤被测量使用封口试管高温度的燃烧方法。玷污石灰石土壤剖面的内容都在11.4g/kg上面的器官的碳，与在表面土壤的71.1g/kg的最高的价值。然而，内容在三黄壤侧面在2.9g/kg和46.0g/kg之间变化。C土壤有机物(SOM)珍视的最大、最小的delta~(13)之间的差别为三黄壤侧面每千每千从2.2改变到2.9。但是它为石灰石土壤剖面每千每千从0.8改变到1.6。对比研究在器官的碳的垂直模式和在黄壤和石灰石土壤之间的SOM的delta~(13)C价值显示了那在那里存在的重要差别。这差别可以反映地点特定的因素，例如土类，植被型，土壤pH，和粘粒含量，等等，哪个控制在侧面包括SOM和土壤碳周转率的不同器官的部件的内容。在SOM的稳定的碳同位素的垂直变化模式有一不同地区性，在石灰岩地区常见的地形区域的特性。

简介：Themechanismandsignificanceofsecondhydrocarbon-generationfromorganicmattertrappedinfluidinclusionsincarbonaterocksarediscussed.Thetypesoforganicmatterandtherelationshipbetweenthemarealsoreviewed.Theorganicmattertrappedininclusionsandcrystals,whichaccountformorethan20%ofthetotalorganicmatterincarbonaterocks,maybeofgreatsignificanceinthegenerationofhydrocarbons.High-temperatureoilresultingfromsecondhydrocarbon-generationshouldbeanimportanttarget,inadditiontonaturalgas,inoilgasprospectinginregionsofhigh-maturitycarbonaterocks.

简介：Thebulkcompositionoforganicmatterandsaturatedandaromatichydrocarbonsex-tractedfrom16samplescollectedfromtwoKupferschieferprofilesintheRudnamine,SouthwestPolandhasbeenanalyzedtostudytheroleoforganicmatterduringbasemetalenrichmentintheKupferschiefershale.Theresultsindicatedthattheextractyieldsandsaturatedhydrocarbonyieldsdecreasedwithincreasingbasemetalcontents.GCandGC/MSanalysesindicatedthatn-alkanesandalkylatedaromaticcompoundsweredepletedandmayhaveservedashydrogendonatorsforthermochemicalsulfatereduction.Theenrichmentofbasemetalsiscloselyconnect-edwiththedestructionofhydrocarbons.

简介：Organicmatterwasexperimentallyextractedbysupercriticalfluids(CO2+1%isopropanol)frompetroleumsourcerocksofdifferentthermo-maturitiesatdifferentburieddepthsinthesamestratigraphicunitintheDongyingBasin.Theresultsshowthatsupercriticalfluidextraction(SFE)ismoreeffectivethanSoxhletextraction(SE),withhigheramountsandgreatervarietiesofhydrocarbonsandsolubleorganicmatterbecomingextractive.ThesupercriticalCO2extractionisthereforeconsideredmorevaluableinevaluationofpetroleumsourcerocksandoilresources,particularlythoseofimmaturetypes.

简介：Inordertobetterunderstandthecompositionalandstructuralcomplexityofdissolvedorganicmatter（DOM）macromoleculesandprovidemechanisticinformationonthebindingofhydrophobicorganiccontaminants（HOCs）toDOM,wefractionatedlargeamountsoflakewaterintothreehydrophobicDOM-fractions.Thevariationofthepartitioningcoef?cients(KDOC)ofpyreneatdifferentpHlevelswasexaminedby?orescencequenchingtitration.Resultsshowthat,relativetothemorepolaracidicDOM-fractions,thehydrophobicneutralfractionexhibitsahighersorptionabilitytopyrene.Generally,thesorptionofpyrenetothethreehydrophobicfractionsisstronglypH-dependent.TheKDOCvaluesofpyrenegenerallyincreasewithdecreasingpHlevels,whichisespeciallyobviousinthesorptionofpyrenetothefulvicacidfractions,suggestingthatthebindingiscontrolledbyhydrophobicinteractions.Themechanismsunderlyingthebindingofpyrenetothehydrophobicfractionswerealsodiscussed.Ourdataarebene?cialtofurtherunderstandingthebindingofHOCstoDOMandhowithasbeenaffected,whichmayresultinmoreaccuratepredictionsofKDOC.

简介：Inorganic-richgasshales,claymineralsandorganicmatter(OM)havesignificantinfluencesontheorigin,preservation,andproductionofshalegas.Becauseofthesubstantialroleofnanoscaleporesinthegeneration,storage,andseepageofshalegas,weexaminedtheeffectsofclaymineralsandOMonnanoscaleporedistributioncharacteristicsinLowerPaleozoicshalegasreservoirs.UsingtheNiutitangandLongmaxishalesasexamples,wedeterminedtheeffectsofclaymineralsandOMonporesthroughsedimentationexperiments.Fieldemission–scanningelectronmicroscopycombinedwithlow-pressureN2adsorptionofthesamplesbeforeandaftersedimentationshowedsignificantdifferencesinporelocationandporesizedistributionbetweentheNiutitangandLongmaxishales.NanoscaleporesmostlyexistedinOMintheLongmaxishaleandinclaymineralsorOM–claycompositesintheNiutitangshale.Thedistributiondifferenceswereattributedlargelytovariabilityinthermalevolutionandtectonicdevelopmentandmightaccountforthedifferenceingas-bearingcapacitybetweentheNiutitangandLongmaxireservoirs.Inthenanoscalerange,mesoporesaccountedfor61–76%oftotalnanoscaleporevolume.ConsiderablydevelopednanoscaleporesinOMweredistributedinabroadsizerangeintheLongmaxishale,whichledtogoodporeconnectivityandgasproduction.Numerousnarrowpores(i.e.,pores\20nm)inOM–claycompositeswerefoundintheNiutitangshale,andmightaccountforthisshale’spoorporeconnectivityandlowgasproductionefficiency.Enhancingtheconnectivityofthemesopores(especiallypores\20nmandthosedevelopedinOM–claycomposites)mightbethekeytoimprovingdevelopmentoftheNiutitangshale.ThefindingsprovidenewinsightintotheformationandevolutionarymechanismofnanoscaleporesdevelopedinOMandclayminerals.

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简介：AbstractTheGartnerkofelboreholeisoneofthemostthoroughlystudiedanddescribedPermo-Triassicsectionsintheworld.Detailedbulkorganiccarbonisotopestudiesshowanegativebaseshiftfrom-24%0to-28%0intheLatestPermianwhichlattervaluepersistsintotheEarliestTriassicafterwhichitdecreasesslightlyto-26‰.Twostronglynegativepeaksof〉-38‰intheLatestPermianandalesserpeakof-31‰intheEarlyTriassicaretoonegativetobeduetoagreaterproportionofmorenegativeorganicmatterandmustbeduetoverynegativemethaneeffects.TheoverallchangetomorenegativevaluesacrosstheBulla/Teseroboundaryfitstherelativeriseinsealevelforthistransitionbasedonthefacieschanges.ApositiveshiftinorganiccarbonisotopevaluesattheLatePermianEventHorizonmaybeduetoanincreaseinland-derivedorganicdetritusatthislevel-afeatureshownbyallTethyanPermo-Triassicboundarysectionsthoughtheseothersectionsdonothavethesamevalues.Carbonatecarbonisotopetrendsaresimilarinallsectionsdroppingby2-3unitsacrossthePermo-Triassicboundary.Gart-nerkofelcarbonateoxygenvaluesaresurprisingly,con-sideringtheubiquitousdolomitization,compatiblewithvalueselsewhereandindicatereasonabletropicaltemper-aturesof60~CintheLatestPermiansabkhasto20-40℃intheoverlyingmarinetransitionbeds.Increasedland-derivedinputattheLatePermianEventHorizonmaybeduetooffshoretransportbytsunamiswhosedepositshavebeenrecognizedinIndiaatthislevel.