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简介：Theorganic/inorganicnanocompositespolymerelectrolytesweredesignedandsynthesized.Theorganic/inorganicnanocom-positesmembranematerialsandtheirlithiumsaltcomplexeshavebeenfoundthermallystablebelow200℃.Theconductivityoftheorganic/inorganicnanocompositespolymerelectrolytespreparedatroomtemperaturewasatmagnituderangeof10-6S/cm.

简介：Apreliminaryinvestigationonshort-wavelengthablationmechanismsofpoly(methylmethacrylate)(PMMA)andpoly(1,4-phenyleneetherether-sulfone)(PPEES)byextremeultraviolet(EUV)radiationat13.5nmusingatable-toplaserproducedplasmafromagas-pufftargetatLLG(Gttingen)andat46.9nmbya10HzdesktopcapillarydischargelaseroperatedattheInstituteofPhysics(Prague)ispresented.Ablationofpolymermaterialsisinitiatedbyphotoinducedpolymerchainscissions.TheablationoccursduetotheformationofvolatileproductsbytheEUVradiolysisremovedasanablationplumefromtheirradiatedmaterialintothevacuum.Ingeneral,cross-linkingofpolymermoleculescancompetewiththechaindecomposition.Bothprocessesmayinfluencetheefficiencyandqualityofmicro(nano)structuringinpolymermaterials.WavelengthisacriticalparametertobetakenintoaccountwhenanEUVablationprocessoccurs,becausedifferentwavelengthsresultindifferentenergydensitiesinthenear-surfaceregionofthepolymerexposedtonanosecondpulsesofintenseEUVradiation.

简介：OrganicmodifierswereeffectivebothtoextendthemigrationtimewindowandtoimprovetheseparationofveryhydrophobiccompoundsinMEKC.Aniterationmethodwasusedtodeterminethemigrationtimeofmicelles.Thequantitativerelationshipbetweenthecapacityfactork’andtheconcentrationoforganicmodifierswasderived,whichwasinvestigatedexperimentally.Thelinearsolvationenergyrelationships(LSER)methodologywasappliedtoMEKC,andgoodlinearrelationshipsbetweenInk’andsolvatochromicparametersof15soluteswereobtainedinthepresenceoforganicmodifierindifferentconcentrations,whichindicatedanewaccessinMEKCtopredictk’fromthestructuralparametersofsolutes.TheeffectofcolumntemperatureTonk’wasalsoinvestigated.

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简介：AuseofSulfonateesterasalinkerinsynthesisofω-aminoalkanolswasreported.Diolsweretetheredontopolystyrylsulfonylchlorideresin,yieldingsulfonateresins(2).Aftercleavedbydiethylamine,diisopropylamineandpropylaminerespectively,threeω-aminoalkanolswereobtained.

简介：Thetetravalentmetalsaltsofmonoalkylphosphates[M(R-OPO3)2]areanewkindofstationaryphasesofchromatography-homogeneousbondedphases.Thestudiesonpreparation,structureandgaschromatographicefficiencyofceriumbis(octylphosphate)(COPP)arereportedinthispaper.Byusingchemicalanalysis,infraredspectra,x-raydiffractionanalysis,thestrongevidencethatCOPPhasalayeredstructureoftheα-zirconiumphosphatetypewasdemonstrated,therepetitiveunitisC8H17OPO3CeO3POC8H17andthereisalittlebendingorinterpenetrationofthealkylchainswithinthelayers.ThethermogravimeticanalysisoftheCOPPindicatedthatithasmuchmorethermalstabilitythansilica-basedpackings.ThethermodynamicparametersΔHandmolecularconnectivityindexesx′fortheadsorptionofseveraldozencompoundsontheCOPPhavealsobeendeterminedbygaschromatographicmethod,andthefinelinearitybetweenthemwasshown.

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简介：Themechanismofcarriertransportinorganiclight-emittingdevicesisnumericallystudied,onthebasisoftrappedcharge-limitedconductionwithanexponentialtrapdistribution.Thespatialdistributionsoftheelectricalpotential,fieldandcarrierdensityintheorganiclayerarecalculatedandanalysed.Mostcarriersaredistributednearthetwoelectrodes,onlyafewofthemaredistributedovertheremainingpartoftheorgaiclayer,Thecarriersareaccumulatedneartheelectrodes,andtheremainingregionisalmostexhaustedofcarriers.Whenthecharacteristicenergyoftrapdistributionisgreaterthan0.3eV.itleadstoareductionofcurrentdensity.Inordertoimprovethedeviceefficiency,organicmaterialswithminortrapsandlowcharacteristicenergyshouldbechosen.Thediffusioncurrentisthedominantcomponentneartheinjectionelectrode.whereasthedriftcurrentdominatestheremainingregionoftheorganiclayer.

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简介：Therectificationratiooforganicmagneticco-oligomerdiodesisinvestigatedtheoreticallybychangingthemolecularlength.Theresultsrevealtwodistinctlengthdependencesoftherectificationratio:forashortmoleculardiode,thechargecurrentrectificationchangeslittlewiththeincreaseofmolecularlength,whilethespin-currentrectificationisweakenedsharplybythelength;foralongmoleculardiode,boththecharge-currentandspin-currentrectificationratiosincreasequicklywiththelength.Thetwokindsofdependenceswitchataspecificlengthaccompaniedwithaninversionoftherectifyingdirection.Themolecularortibalsandspin-resolvedtransmissionanalysisindicatethatthedominantmechanismofrectificationsuffersachangeatthisspecificlength,thatis,fromasymmetricshiftofmoleculareigenlevelstoasymmetricspatiallocalizationofwavefunctionsuponthereversalofbias.Thisworkdemonstratesafeasiblewaytocontroltherectificationinorganicco-oligomerspindiodesbyadjustingthemolecularlength.更多还原

简介：Photoniccrystalslabsintegratedintoorganiclight-emittingdiodes(OLEDs)allowfortheextractionofwaveguidemodesandthusanincreaseinOLEDefficiency.WefabricatedlinearBragggratingswitha460-nmperiodonflexiblepolycarbonatesubstratesusingUVnanoimprintlithography.Ahybridorganic–inorganicnanoimprintresistisusedthatservesalsoasahighrefractiveindexlayer.OLEDscomposedofapoly(3,4-ethylenedioxythiophene)polystyrenesulfonate(PEDOT:PSS)polymeranode,anorganicemissionlayer[poly(p-phenylenevinylene)(PPV)-derivative'SuperYellow'],andametalcathode(LiF/Al)aredepositedontotheflexiblegratingsubstrates.TheeffectsofphotoniccrystalslabdeformationinaflexibleOLEDarestudiedintheoryandexperiment.Thesubstratedeformationismodeledusingthefinite-elementmethod.Theinfluenceofthechangeinthegratingperiodandthewaveguidethicknessunderbendingareinvestigated.Thechangeinthegratingperiodisfoundtobethedominanteffect.Atanemissionangleof20°achangeintheresonancewavelengthof1.2%ispredictedforastrainof1.3%perpendiculartothegratinggrooves.ThisvalueisverifiedexperimentallybyanalyzingelectroluminescenceandphotoluminescencepropertiesofthefabricatedgratingOLEDs.

简介：Thisreviewdealswiththepreparationandapplicationofpolymericsulfinateresinsasreactiveintermediateinsolidphaseorganicsynthesisandseparation.

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简介：由使用不同器官的ligands，二3D无机器官的混合混合物公司(C4H4N2)(VO3)21；公司(C12H12N2)(VO3)22被热水的反应综合；由X光检查晶体学描绘了。水晶数据：1。水晶系统斜方晶，空格组Pnna，a=10.188(2)，b=11.497(2)，c=7.3975(15)，V=866.5(3)[3]，Z=4，Dcalcd=2.705g/cm[3]；2。水晶系统三斜晶系，空间组P1(号码2)，a=8.3190(17)，b=8.4764(17)，c=11.183(2)，α=95.48(3)°，β=92.03(3)°，γ=107.24(3)°，V=748.0(3)[3]，Z=2，Dcalcd=1.958g/cm[3]。化合物1的框架包含两个{公司(C4H4N2)}；无限的metavanadate链。化合物2的水晶结构被构造与无机{CoV2O6}由器官的1,2二度(4-pyridyl)到对面连接的层乙烷ligands。二混合物对约410°C热地稳定；350°C分别地。他们的光乐队差距决心是2.13eV；由UV-VIS-NIR弥漫的反射系列的2.12eV，它揭示了他们半导体的性质；光吸收特征。

简介：Anorganicsilaneacrylateresin（PMBK）wassynthesizedbyfree-radicalsolutionpolymerizationusingmethylmethacrylate,butylacrylateand（3-methacryloxypropyl）trimethoxysilaneasmonomers.Aluminum（Al）particleswerethenencapsulatedininorganic-organichybridfilmsthatwerepreparedbyhydrolysisandcondensationofPMBKandtetraethylorthosilicate（TEOS）onthesurfaceofAlpigments.CharacterizationresultsshowedthatPMBKandTEOScouldsimultaneouslyhydrolyzeandcondensewithhydroxylgroupsonthesurfaceoftheAlparticlestoformcompositeAlparticlescoatedwithinorganic-organichybridfilms.ComparedwithrawAlparticles,thecorrosionresistanceandadhesivepropertiesofpaintfilmscontainingthecompositeAlparticleswereimprovedgreatly,whiletheglossinessofthepaintfilmsdecreasedslightly,from48.6°to47.0°.Inalkalinemedia（pH11）,thevolumeofevolvedH2ofcompositeAlparticleswasonly3.5mL,whereasthatofrawAlwas83.5mL.TheglossinessofpaintfilmscontainingcompositeAlparticlesdecreasedby1.66%afterimmersioninalkalinemediafor24h,whereasthatofrawAldecreasedby14.82%.Peel-offtestsofthepaintfilmsshowedthatthecompositeparticlesmovedslightlyawayfromthepaintfilms.Incontrast,therawAlparticleswereseriouslydesquamated,suggestingencapsulationofhybridfilmscangreatlyimprovetheadhesivepropertiesofAlparticlesinpaintfilms.

简介：我们报导紫外(紫外)分层的器官无机的perovskite材料的轻导致的对光反应变色行为(C4H9NH3)2CuCl4,与紫外光在照耀以后从黄改变了到褐(10mW/cm2)并且部分在黑暗中通过存储恢复了。(C4H9NH3)2展出的CuCl4在286nm集中的二个不同吸收乐队(乐队我)并且384nm(乐队II)它被归因于导致相片的激子在无机的层由器官的层夹了的2D形成了。乐队的蓝移动我当样品为时间的不同长度在紫外光下面被照耀时，从象乐队的紧张的减少一样的287～269nm，我和乐队II能被发现。在弄歪的CuCl64−八面体的N-H⋯Cl氢契约以及长Cu-Cl契约的颤动的紧张的同时的变弱能从Fourier变换被检测红外线(FTIR)系列，它结果不对称的Cl-Cu⋯Cl契约和产生对光反应变色行为的起诉分发的变化。

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