学科分类
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67 个结果
  • 简介:Nano-sizedhexagonalmagnesiumhydroxide(Mg(OH)2)withgooddispersibilitywassynthesizedbyadoubleinjection-hydrothermalmethod,utilizingpolyvinylpyrrolidone(PVP)asanadditiveandwithoptimizedprocessingparameters.SEMandBETanalysisshowedthatthemeanparticlesizeandspecificsurfaceareaoftheMg(OH)2particleswere174nmand50.77m2/g,respectively.TheFT-IRspectraandtheXRDpatternsshowedthatPVPwasadsorbedonthesurfaceoftheMg(OH)2crystal,thuseffectivelylimitingparticleagglomerationandhinderingcrystalgrowthalongthe(101)plane.TGAshowedadecreaseinthedecompositiontemperatureandanincreaseintheweightlossoftheMg(OH)2particlesduetoadditionofPVP.

  • 标签: 纳米尺寸 氢氧化镁 六边形 可控制备 MG(OH)2 聚乙烯吡咯烷酮
  • 简介:从理论上推导了声学超表面对平面声波的作用模型,该理论模型计及声波高阶衍射模态,从而能够计及超表面微结构之间的声学干扰.通过与数值结果对比,该模型预测的反射频率精度得到了一定程度的提高,并能够分辨出相邻孔声场之间的耦合模态.讨论了声学超表面吸声特性与阻抗特性对高超声速边界层内Mack第2模态的抑制机理,研究发现通过设计超表面阻抗特性,使得入射声波与反射声波在壁面处相位相反,同样可以抑制Mack第2模态.基于理论模型,分别优化设计得到最优的微结构几何尺寸,并通过对Mach6平板边界层流动进行稳定性分析,验证了超表面不同声学特性的抑制效果.

  • 标签: 声学超表面 Mack第2模态 稳定性分析 高超声速边界层流动 直接数值模拟
  • 简介:W,N共同做TiO2nanoparticles被一个solgel方法综合。准备样品被X光检查衍射(XRD)描绘,域排放扫描电子显微镜学(FE-SEM),传播电子显微镜学(TEM),Fourier变换红外线的光谱学(英尺红外),X光检查光电子光谱学(XPS)和弥漫的反射spectrophotometry(医生)。结果证明共同做的光催化剂是有22.5nm的最小的粒子尺寸的实质上一致的球形的粒子。比作未做的TiO2,N-TiO2和P-25,W的吸收边,N共同做转移到更长的波长的TiO2和它为在Xe灯(350W)下面的甲基橘子(瞬间)的降级的photocatalytic活动更高。

  • 标签: N-TiO2 光催化剂 共掺杂 场发射扫描电子显微镜 光驱动 傅里叶变换红外光谱
  • 简介:从地下的管子的漏能导致被破坏并且引起损坏到邻近的基础结构的基础。包围漏的区域的土壤粒子能从由漏的液体的土壤矩阵被动员,代替,并且甚至洗了,产生虚空或洞。用acoupled的二维的模拟分离元素方法和格子Boltzmann方法(DEMLBM)被用来调查一个土壤床题目的行为到局部地注射的液体,它在一根管子中代表一条漏缝。内部粒子的表面精力的各种各样的价值也被采用为连贯的粒子的机械效果建模。结果建议内部粒子的表面精力极大地关于漏的液体影响床反应,包括开始洞,洞形状和它的进化率的过量压力。

  • 标签: 土壤颗粒 注射液 格子BOLTZMANN方法 行为 二维 管道泄漏
  • 简介:在现在的纸,包含三个任意的函数为的一个一般解决方案概括(2+1)维的KdV-mKdV方程,它被导出从概括(1+1)维的KdV-mKdV方程,首先借助于Wiess被介绍,小鼓,Carnevale(WTC)截断方法。然后有考虑的几条能量守恒定律的multisymplectic明确的表达被介绍为概括(2+1)维的KdV-mKdV方程基于桥的multisymplectic理论。随后,源于以便以Jacobi椭圆形的功能的合理功能模仿周期的波浪答案一般答案,一个半含蓄的multi-symplectic计划被构造那等价于Preissmann计划。从数字实验的结果,我们能断定multi-symplectic计划能精确地模仿周期的波浪答案概括(2+1)维的KdV-mKdV方程当时近似保存能量守恒定律。

  • 标签: KDV-MKDV方程 KDV-MKDV方程 广义 PREISSMANN格式 JACOBI椭圆函数 辛方法
  • 简介:一系列碳nanotubes/TiO2nanotubes(CNTs/TNTs)合成光催化剂被CNT的加入成功地在HNO3洗准备过程。分别地,这些光催化剂被XRD,N2物理吸附,UVvis弥漫的反射光谱学,TEM和拉曼光谱学描绘,他们的photocatalytic活动被把methy1橘子(瞬间)用作模型混合物测试。另外,合并的CNT的数量的效果,锻烧温度和在合成光催化剂的photocatalytic活动的催化剂的数量系统地被调查。结果证明CNTs/TNTs合成展览高得多的photocatalytic活动比TNT或CNT的独自一个。

  • 标签: 复合光催化剂 碳纳米管 甲基橙 降解效率 光催化活性 透射电子显微镜
  • 简介:Theboundaryelementmethodwasimprovedforthe2Delasticcompositeswithrandomlydistributedinclusions.Thisproblemcanbereducedtoaboundaryintegralequationforamulti-connecteddomain.Further,consideringthematricesofthetractionsanddisplacementsforeachgroupoftheidenticalinclusionwerethesame,aneffectivecomputationalschemewasdesigned,sincetheordersoftheresultingmatrixequationscanbegreatlyreduced.Numericalexamplesindicatethatthisboundaryelementmethodschemeismoreeffectivethantheconventionalmulti-domainboundaryelementmethodforsuchaproblem.Thepresentschemecanbeusedtoinvestigatetheeffectivemechanicalpropertiesofthefiber-reinforcedcomposites.

  • 标签: 包含 数字模拟 边界元素 2D弹性 光学纤维
  • 简介:这份报纸为为敏化染料的太阳能电池(DSSC)经由一起沉淀为TiO2nanoparticles准备建模并且优化作为一条有效途径论述反应表面方法论(RSM)性能。钛(IV)二度--(acetylacetonate)di-isopropoxide(DIPBAT),isopropanol和水分别地被用作先锋,溶剂和合作溶剂。象准备因素与的水,老化温度和锻烧温度的臼齿的比率主要并且粒子特征和表演上的相互作用效果被调查。粒子特征被X光检查diffractometry(XRD)以主要、第二等的尺寸,晶体取向和形态学决定并且扫描电子显微镜学(SEM)。乐队差距精力和DSSC的力量变换效率被用于表演研究。根据在反应表面方法论(RSM)的变化(ANOVA)的分析,所有三个独立参数是统计上重要的,最后的模型是精确的。模型在1:10:500的DIPBAT-to-isopropanol-to-water的臼齿的比率的最佳的条件下面预言了最大的力量变换效率(0.14%),变老36潰獳獥楳湯的温度吗?

  • 标签: 染料敏化太阳能电池 TIO2纳米粒子 光电性能 性能优化 纳米颗粒 功率转换效率
  • 简介:WithTi(OBu)4asprecursor,andHAcascomplexingagent,pureandW-dopedTiO2gelatinswerepreparedbyasol-gelmethod.Duringtheprocessofgelformation,metalionsweredispersedintheporousTiO2matrix.Then,powdersofnano-TiO2andW-dopednano-TiO2werepreparedbydrying,grindingandheattreatmentatdifferenttemperatures.Thegrainsizeandstructureofthesamples,pureTiO2andW-doped,andtreatedatdifferenttemperatures,werestudiedbyX-raydiffraction(XRD),BeckmanCoulterSorptionAnalysisandTEM.Resultsshowedthat,withincreasingtemperature,theTiO2transformedfromanatasetorutileandthegrainsizeincreased.ThistransformationandgraingrowthofTiO2couldberetardedbydopingwithW.

  • 标签: 相位结构 二氧化钛 纳米结构 凝胶体 掺杂
  • 简介:部分地,聪明切割的过程,缺陷由尺寸描绘了的结合的效果和在切开前后的内部压力上的2纸被使用破裂力学模型学习。有大尺寸的结合的缺陷是容易的引起缺点生长的严重偏差,这被发现,当切开时,导致薄层的一个非转移的区域。在结合的缺陷的内部压力是很小的一个实际聪明切割的过程,大界面的缺点总是在切开的过程支持缺点生长。同时,增加结合的缺陷的内部压力减少在切开前的缺点生长和它的偏差。stiffener限制的松驰的机制被建议澄清结合的缺陷的效果。而且,当结合的缺陷是在场的时,切开的过程的进步被分析。在切开以后,有大尺寸和高内部的压力的那些结合的缺陷在高温度的退火期间为薄电影的blistering是脆弱的。

  • 标签: 粘结缺陷 智能剥离 断裂力学分析 分裂过程 内部压力 技术
  • 简介:Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.

  • 标签: Y2O3:Eu 无火焰 单粒子 颗粒尺寸效应 晶体结构测定 电子背散射衍射
  • 简介:一个热水的方法准备的象花的SnO2nanopowders是经由受精与钯修改的表面。晶体结构,形态学,和样品的表面化学状态借助于X光检查衍射(XRD)被描绘,扫描电子显微镜学(SEM),和X光检查光电子光谱学(XPS)分别地。煤气的察觉到表演也被调查。为220渠湡瑯'T獥?的热水的温度?呎?乔?

  • 标签: 纳米粉体 SNO2 表面改性 气敏性能 粉体制备 X射线光电子能谱
  • 简介:3-DevolutionofKarmanvortexfilamentsandvortexfilamentsinbraidregionsintheturbulentwakeofa2-Dcirculaxcylinderisinvestigatednumeri-callybasedoninviscidvortexdynamicsbyanalyzingtheresponseoftheinitially2-Dspanwisevortexfilamentstoperiodicspanwisedisturbanceofvaryingmagnitude,wavelengthandinitialphaseangles.Ourresultsrevealakindof3-Dvortexsysteminthewakewhichconsistsoflargescalehorseshoe-shapedvorticesandsmallscaleλ-shapedvortexfilamentsaswellasvortexloops.Themechanismandthedynamicprocessaboutthegenerationofstreamwisevorticalstructureandthe3-Dcoherentstructurearereported.

  • 标签: THREE-DIMENSIONAL evolution COHERENT structure WAKE flow
  • 简介:Nanostructuredtransitionmetaloxidesarepromisingalternativeanodesforlithiumionbatteries.Li-ionstorageperformanceisexpectedtoimproveifhighpackingdensityenergyparticlesareavailable.Herein,Mn2O3microsphereswithaca.18μmdiameterandatappeddensityof1.33g/cm3weresynthesizedbyafacilesolvothermal-thermalcoversionroute.SphericalMnCO3precursorswereobtainedthroughsolvothermaltreatmentandtheydecomposedandconvertedintoMn2O3microspheresatanannealingtemperatureof700C.TheMn2O3microspheresconsistedofMn2O3nanoparticleswithanaverage40nmdiameter.TheseporousMn2O3microspheresallowgoodelectrolytepenetrationandprovideanionbufferreservoirtoensureaconstantelectrolytesupply.TheMn2O3microsphereshavereversiblecapacitiesof590and320mAh/gat50and400mA/g,respectively.Wethusreportanefficientrouteforthefabricationofenergyparticlesforadvancedenergystorage.

  • 标签: MN2O3 锂离子电池 溶剂热合成 负极材料 微球 过渡金属氧化物
  • 简介:TiO2-loadedactivatedcarbonfibers(ACF)werepreparedbyahydrothermalmethod.Thesampleswerecharacterizedbyscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),Fouriertransforminfrared(FT1R)spectrometryandUV-visdiffusereflectancespectra(DRS).SEMimagesshowedthattheTiO2nanoparticlesweredepositedonthesurfaceofACF,andtheparticlesizeandloadingamountofTiO2werevariedbychangingtheinitialconcentrationoftetrabutyltitanate(TBOT).TheresultsofanashexperimentshowedthattheloadingamountsofTiO2were18.4%,43.3%,52.5%,75.1%,and91.1%forinitialconcentrationsofTBOTof0.07,014,0.21,0.28,and0.35mol/L,respectively.PhysicalinteractionsplayedanimportantroleintheformationofTiO2/ACFcompositefibersthatabsorbUVandvisiblelight.ComparedwiththoseofACF,improvedadsorptionandphotocatalyticactivitytowardRhodamineB(RhB)wereobservedforTiO2/ACFcompositefiber.TheRhodamineBcouldberemovedefficientlybyTiO2/ACFcompositefibers,andtheTiO2loadingamounthadasignificanteffectonthephotocatalyticactivityofTiO2/ACFcompositefibers.

  • 标签: 纳米TiO2 光催化活性 可见光照射 吸附性能 负载量 活性炭纤维
  • 简介:Fortwo-dimensionnonlinearconvectiondiffusionequation,atwo-gridmethodofcharacteristicsfinite-elementsolutionwasconstructed.Inthismethodthenonlineariterationsisonlytoexecuteonthecoarsegridandthefine-gridsolutioncanbeobtainedinasinglelinearstep.Forthenonlinearconvection-dominateddiffusionequation,thismethodcannotonlystabilizethenumericaloscillationbutalsoacceleratetheconvergenceandimprovethecomputationalefficiency.Theerroranalysisdemonstratesifthemeshsizesbetweencoarse-gridandfine-gridsatisfythecertainrelationship,thetwo-gridsolutionandthecharacteristicsfinite-elementsolutionhavethesameorderofaccuracy.Thenumericalexampleconfirmsthatthetwo-gridmethodismoreefficientthanthatofcharacteristicsfinite-elementmethod.

  • 标签: 有限元分析 非线性传递 扩散方程 迭代法 稳定性
  • 简介:Aself-adaptiveprecisealgorithminthetimedomainwasemployedtosolve2-Dnonlinearcoupledheatandmoisturetransferproblems.Byexpandingvariablesatadiscretizedtimeinterval,thevariationsofvariablescanbedescribedmoreprecisely,andanonlinearcoupledinitialandboundaryvalueproblemwasconvertedintoaseriesofrecurrentlinearboundaryvalueproblemswhicharesolvedbyFEtechnique.Inthecomputation,noadditionalassumptionandthenonlineariterationarerequired,andacriterionforself-adaptivecomputationisproposedtomaintainsufficientcomputingaccuracyforthechangesizesoftimesteps.Inthenumericalcomparison,thevariationsofmaterialpropertieswithtemperature,moisturecontent,andbothtemperatureandmoisturecontentaretakenintoaccount,respectively.Satisfactoryresultshavebeenobtained,indicatingthattheproposedapproachiscapableofdealingwithcomplexnonlinearproblems.

  • 标签: 有限元分析 非线性传输 自适应系统 热量转移 离散特性