学科分类
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185 个结果
  • 简介:从微观的角度研究了根系——土壤复合体的宏观力学性质,并通过计算机模拟试验,研究了土壤和根系——土壤复合体的应变。结果表明,生态防护对加固土壤、保护边坡体有可支持的力学依据,能够有效的提高土壤的力学性质。

  • 标签: 生态防护 土壤-根系复合体 细观力学 虚拟试验 宏观力学
  • 简介:用摩擦磨损试验对转矩流变仪-模压成型方法制备的Ekonol/POM和Ekonol/G/MoS2/POM复合材料在不同加载条件下的摩擦学性能进行了研究。结果表明:在标准加载条件下,POM及其复合材料的摩擦系数和磨损量都是随着Ekonol含量的增加而呈现先下降后上升的趋势;在特殊加载条件下,随着载荷的增加,POM及其复合材料的摩擦系数呈先增大后减小趋势,而材料的磨损量则随着载荷的增加而增大,经测定得出的ZOGM20的极限PV值比POM提高14.5%。

  • 标签: 加载条件 聚甲醛复合材料 摩擦学特性
  • 简介:金属基复合材料的综合性能优越,但应用成本过高,为解决这个矛盾,科学家们竞相开展研究。本研究用熔铸重力浇注方法制取了综合性能优越的Gr(石墨)-Al-Si复合材料。为该材料用作汽车活塞的产业化开辟了一条廉价之路;为进一步作缸套材料等奠定了基础。

  • 标签: 熔铸 石墨-铝硅 金属基复合材料 产业化
  • 简介:Aseriesofnovelbluelong-lastingphosphorescencephosphorsSr6Al18Si2O37:Eu2+,RE3+(RE3+=Ho3+,Gd3+,Dy3+andPr3+)werepreparedbytheconventionalhigh-temperaturesolid-statereactioninareductiveatmosphere.TheirpropertiesweresystematicallyinvestigatedutilizingX-raydiffraction(XRD),photoluminescence,phosphorescenceandthermoluminescence(TL)spectra.ThephosphorsemittedbluelightthatwasrelatedtotheemissionofEu2+dueto5d-4ftransition.Brightbluelong-lastingphosphorescence(LLP)couldbeobservedaftertheexcitationsourcewasswitchedoff.Fortheoptimizedsample,thebluelong-lastingphosphorescencecouldlastfornearly4hinthelightperceptionofthedark-adaptedhumaneye(0.32mcd/m2).TheeffectsofRE3+ionsonphosphorescencepropertiesofthephosphorswerestudied,andtheresultsshowedthattheco-dopingofRE3+ionsgreatlyenhancedtheintensityofthepeakaround315Kwhichwasrelatedtothelonglastingphosphorescenceofthephosphorsatroomtemperatureandconsequentlyimprovedtheperformanceofthebluephosphorescencesuchasintensityandpersistenttime.

  • 标签: 荧光粉 长余辉 磷光 蓝色 发光特性 高温固相反应
  • 简介:EffectofCe-Mg-Si(lightRE)andY-Mg-Si(heavyRE)nodulizersonthemicrostructuresandmechanicalpropertiesofheavysectionductileironwasinvestigatedtodevelopthematerialofspent-nuclear-fuelcontainers.Twoas-castsweretreatedbythesamequalitypercentageoflightREandheavyRE,respectively.Fourpositionswerechosentostandfordifferentsolidificationcoolingratesofspecimens.Thetensilestrength,elongationandimpacttoughnessofspecimenstreatedbyheavyREwereallhigherthanthoseofthespecimenstreatedbylightRE.Withthedecreaseofcoolingrate,themechanicalpropertiesoftwospecimensdecreased,andthefracturemorphologychangedfromductilefracturetobrittlefracture.TheimprovingeffectofmechanicalpropertiesbetweenheavyREandlightREwasobviousduetothebetteranti-degradationpropertyofheavyRE.Whilethesolidificationprocesslastedformorethan250min,theimprovingeffectwasnotobviousduetoseriousspheroidalizationdecaying.

  • 标签: 大断面球铁 机械性能 微观结构 球化剂
  • 简介:NanosizedBaCeo.95Yo.o5O3-δpowderswiththehomogeneouscompositionweresynthesizedbyanewcombustionprocessbasedonthePechinimethod.Apolymericprecursorsolwasformedbyuseofcitricacidandethyleneglycolasthechelatingagentsofmetalions.Theperovskite-typeBaCeo.95Yo.o5O3-δpowderswithuniformshapeandsmallerthan40nminsizedwereobtainedthroughthecombustionofthepolymericprecursorsolattheexistenceofnitricacidandammoniumhydroxide.Itwasfoundtheparticlesizecouldbecontrolledbymodulatingthequantitiesofnitricacidandammoniumhydroxide,thequantitiesoftheresidue,carbonateionswerealsoaffectedbythequantitiesofthecitricacidandethyleneglycol.

  • 标签: 无机非金属纳米材料粉末 钙钛矿氧化物 BaCeo.95Yo.o5O3-δ 燃烧合成 稀土元素
  • 简介:ToevaluatethepossibilityofusingGd-Si-Gealloysinmagneticrefrigerators,samplesofGd-Si-GealloysweremadeofdomesticGd.Themagnetocaloriceffectofsampleswasestimatedbymagneticentropychange(-ΔSm)calculatedfromM-HcurvesaccordingtoMaxwellrelation.ThefirstorderphasetransformationwasdestroyedduetotheimpuritiesinthecommercialGd,sothatnogiantmagnetocaloriceffectwasfound.ThesamplesmadeofpurifiedGdexhibitfirstorderphasetransformation,andthe-ΔSmisbasicallyconsistentwiththepublisheddataofAmeslaboratory,USA.ThisworkprovesthatGd-Si-GealloysmadeofdomesticGdcanbeutilizedinmagneticrefrigerators.

  • 标签: 金属材料 稀土元素 巨磁致发热效应 钆-硅-锗合金 钆杂质 稀土元素
  • 简介:MossbauerEffectofRapidlyQuenchedAl-Fe-V-Si-MmAlloysWangJianqiang(王建强),ChaoYuesheng(晁月盛),ZengMeiguang(曾梅光),ZhangBaojin(张宝金),Ch...

  • 标签: M SSBAUER SPECTROSCOPY Misch METAL Al-Fe-V-Si-Mm
  • 简介:TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.

  • 标签: 无机非金属材料 陶瓷 稳定设备 稀土
  • 简介:针对方大特钢公司60Si2Mn弹簧扁钢产品出现剪切端面裂纹问题,进行裂纹检测、剪切温度试验和不同温度下力学性能检测;分析发现剪切时的温度对裂纹产生的影响,发现剪切裂纹是剪切应力作用于偏析较严重部位形成的裂纹源在残余应力释放过程中扩展形成的横向裂纹.根据分析结果,在生产实践中分别对炼钢、轧制工序采取相应措施,有效控制了弹簧扁钢的剪切端面裂纹.

  • 标签: 弹簧扁钢 裂纹 剪切温度 偏析 原因分析
  • 简介:Differentrareearth(RE=La,Ce,Pr,Nd,Sm,Y)andCumodifiednickelcatalystsforhydrogenproductionfrommethanedecompositionweresynthesizedbyasol-gelprocessandmethod.ThecatalystswerecharacterizedoranalyzedthroughBrumauer-Emmett-Teller(BET),X-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM)techniques.Andthehydrogenproductionperformancewasalsoevaluatedbyafixed-bedandmicro-reactiontechniquewithCH4→C+H2asaprobereaction.Theresultsshowedthatrareearthmodificationhadplayedagreatrolefornickelcatalysts,forexample,smallernickelparticles,goodthermalstability,highactivity,etc.Lawasthebestadditiveamongrareearthmodification.TheSEMofrareearthmodifiedcatalystsshowedorderedflower-likestructureandrareearthmodificationmadethenickelparticlesmovetothesurfaceofcatalysts.Inaddition,theSEMofnano-carbonswasalsochangedbyrareearthmodificationwithlong,narrownano-carbonfibersortubesobtained.Solidcarbonformationwaspreventedbyrareearthmodification.

  • 标签: 稀土改性 镍催化剂 分解 甲烷 产氢 SEM分析
  • 简介:以Fe、C包覆金红石型TiO2(Fe-C-R)为光催化剂,以阿特拉津作模型污染物,研究了Fe-C-R可见光催化H2O2降解阿特拉津的反应特性。表明Fe-C-R能可见光催化H2O2降解阿特拉津,反应45min,阿特拉津的降解率达98%;通过对反应体系的荧光光谱分析显示,阿特拉津的降解涉及羟基自由基(·OH)的产生与参与,并且与单纯的金红石型TiO2(R)降解阿特拉津的反应机理是不同的。

  • 标签: FE C包覆金红石型TiO2 可见光催化 阿特拉津 过氧化氢 羟基自由基
  • 简介:SrB6O10:Tb黄磷被高温度的稳固的州的反应综合。合作掺杂物,Tb集中和照耀在SrB6O10的TL上开暴露的Ce或李的影响:Tb被调查。当合作掺杂物不能改进SrB6O10的敏感,结果显示出那Ce或李:Tb黄磷。TL反应取决于Tb集中,0.02是在从0.01~0.10的集中范围的最佳。用最佳Tb集中,我们计算了SrB6O10的运动参数:采用山峰形状方法的Tb,并且建议服从第二的黄磷订动力学。TL排放紧张线性地依赖于在50~的剂量范围以内的照耀剂量200Gy。典型Tb(3+)离子排放在TL排放光谱被观察。

  • 标签: 热致发光 稀土 掺杂 SrB6O10:Tb