A New Combustion Process for Nanosized BaCeo.95Yo.o5O3-δ Powders

(整期优先)网络出版时间:2004-05-15
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NanosizedBaCeo.95Yo.o5O3-δpowderswiththehomogeneouscompositionweresynthesizedbyanewcombustionprocessbasedonthePechinimethod.Apolymericprecursorsolwasformedbyuseofcitricacidandethyleneglycolasthechelatingagentsofmetalions.Theperovskite-typeBaCeo.95Yo.o5O3-δpowderswithuniformshapeandsmallerthan40nminsizedwereobtainedthroughthecombustionofthepolymericprecursorsolattheexistenceofnitricacidandammoniumhydroxide.Itwasfoundtheparticlesizecouldbecontrolledbymodulatingthequantitiesofnitricacidandammoniumhydroxide,thequantitiesoftheresidue,carbonateionswerealsoaffectedbythequantitiesofthecitricacidandethyleneglycol.