简介:1.IntroductionLightrareearthadditioncanremarkablyenhancetheservicelifeofFe-Cr-Alalloyforelectricalheatingelement,butitscontentinthealloymustbecontrolledbelowthelevelof0.1wt-%.Whenthecontentexceedsthat,theperformance
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简介:Fe-Ni-Almixturesashot-pressingsinteringadditivetoTitaniumdiboride(TiB2)werestudied.ItisfoundthatliquidalloyformedunderhightemperaturehardlyhaseffectsonthedensificationbehaviorsofTiB2-independent.Fe-Ni-AladditivejustworksasfillerbetweenTiB2particlesanddoesnotchangetheTiB2-independentsinteringbehaviors.PressingmodehasagreateffectontheliquidflowingbetweenTiB2particles.Multiple-stepspressingmodewillgivemoretimeandspacefortheliquidflowingandimprovetherelativedensityofTiB2-Fe-Ni-Alcermet.
简介:Theimplantedionrange,thedepthprofileandthefilmsttuctureoftheimplantedlayerwerestudied;thecarrierconcentrationandthemobilityweremeasured;theconductivitymechanismofthefilmimplantedFeintoAl2O3ceramicwasdiscussed.TheconclusionisthattheimplantedFe2+ionsmoveintoAl2O3latticeandreplaceAl3+toformsubs-titutionimpuritiessothattheionimplantedlat-tice,ascomparedwiththeoriginalone,presentsaneffectivenegativechargewhichformsanegativechargecenter.Avacancyisboundarroundit,andanacceptorisintroducedintheforbiddenband.
简介:利用喷射沉积工艺制备Al-3.3Fe-10.7Si合金坯,经挤压制成试样。研究了合金组织、韧性及内耗行为,得出该合金在60-250℃温度范围产生的内耗峰,是由于晶界滑动弛豫引起的,弛豫过程激活能为172.2kJ/mol。在内耗峰位置晶界滑动消耗部分振动能,合金韧性在此处出现极大值。
简介:ThemicrostructureandcompositionofTiC-Al2O3/Fefunctionallygradedmaterials(FGM)preparedbyself-propagatinghightemperaturesynthesisandpseudo-hotisostaticpressing(SHS/PHIP)werestudied,andtheresistingthermalshockbehaviorswereanalyzed.TheresultsshowthatTiC-Al2O3/FeFGMhasgradedcompositiondistribution.Nocross-sectioncrackthroughthelayerswasfoundinthetestsofthermalshockandfatigue.
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简介:TheevolutionofmicrostructureandmechanicalpropertiesofAl-0.4Cu-0.14Si-0.05Mg-0.2Fe(wt.%)alloys,micro-alloyedwithZr,TiandSc,wereinvestigated.Theadditionof0.2%ZrtobasealloyacceleratestheprecipitationofSi-richnano-phaseinα-Almatrix,whichplaysanimportantroleinimprovingthemechanicalpropertiesofanalloy.Thetensilestrengthincreasesfrom102MPaforthebasealloyto113MPafortheZr-modifiedalloy.Adding0.2%Zr+0.2%Titobasealloyeffectivelyrefinesa-AlgrainsizeandacceleratestheprecipitationofSiandCuelements,leadingtoheavysegregationatgrainboundary.Byfurtheradding0.2%SctoZr+Timodifiedalloy,thesegregationofSiandCuelementsissuppressedandmoreSiandCuprecipitatesappearedinα-Almatrix.AccompaniedwiththeformationofcoherentAl3Scphase,thetensilestrengthincreasesfrom108MPafortheZr+Timodifiedalloyto152MPafortheSc-modifiedalloy.DuetoexcellentthermalstabilityofAl3Scphase,theSc-modifiedalloyexhibitsobviousprecipitationhardeningbehaviorat350℃,andthetensilestrengthincreasesto203MPaafterholdingat350℃for200h.
简介:FenanowirearraywithstrongshapeanisotropywasemployedasthesoftphaseinNd-Fe-Bbasednanocomposites.TheeffectsoftheFenanowiredistributiononmagneticpropertiesofthenanocompositeswereinvestigatedbymicromagneticsimulation.TheresultsindicatethattheshapeanisotropyofFewiresaddedinthesamedirectionastheuniaxialmagnetocrystallineanisotropyofthehardphasecannotincreasethecoercivityofthenanocomposite.Whenthenanowiresaredistributedperpendiculartotheeasyaxisofthehardphase,theshapeanisotropyofsoftphasecanretardthemomentsfromrotatingtothefullreverseddirection,leadingtoenhancedcoercivity.Inaddition,withincreasingthenanowirediameter,thecoercivityofthenanocompositedecreases,butthedipolarinteractionshowsdifferentrolesinmagneticreversalofnanocompositefordifferentdistributionsofnanowires.ThecurrentresultssuggestthatthecoercivityoftheNd2Fe14B/α-Fenanocompositecanbeenhancedbyintroducingthesoftmagneticnanowirearraywiththediameterlessthantheexchangelengthandwiththelongaxisalongthedirectionotherthantheeasyaxisofhardphase.
简介:Aneffectivedispersion-strengtheningphaseinAl-8Fe-2Mo-2Zr-2Nd-0.7Ti-1.6SialloywasidentifiedtobeanagedprecipitatephasewithpossiblechemicalstoichiometryofAl20(Ti,Mo)2Ndandfcccrystalstructurewithao=1.455nm.ThestructurewasdeterminedtobeFm3mspacegroup.
简介:TheinteractionbetweenZn-AleutecticalloyandAl2O3p/6061Alcompositesinthevacuumfurnacewasinvestigated.Greatattentionhasbeenpaidtotheelementsdiffusion,themicrostructureandformationoftheinterfacebetweenZn-AIeutecticalloyandAl2O3p/6061Alcomposites.ExperimentalresultsshowthatZn-AleutecticalloyhasagoodwettingabilitytoAl2O3p/6061Alcompositesandthewettingangledecreaseswithincreasingthetemperatureinvacuum.Aftertheinteraction,aninteractionlayerformsbetweenZn-AIalloyandAl2O3p/6061Alcomposites.Thephasesintheinteractionlayermainlyconsistofα-Al(Zn),Al2O3andCuZn5resultedfromthediffusionofelementsfromtheZn-Alalloy.SeveralporositiesdistributeintheregionneartheinterfaceoftheZn-Alalloy/interactionlayer.TheamountofshrinkagevoidsintheinteractinglayerisrelevanttothepenetrationofZnelementintoAl2O3p/6061Alcompositeswhichisafunctionoftemperature.SoitisnecessarytolowerheatingtemperatureinordertolimittheZnpenetration.
简介:AresearchonkineticsofAlevaporationfromliquidU—Alalloyswasmadeinavacuuminductionmelting(VIM)furnaceat1673—1843K.TheevaporationrateofAlwasfoundtobefirstorderwithrespecttoAlcontentinthemelt.TheoverallmasstransfercoefficientofAlwasdeterminedanditwasfoundthattheevaporationrateofAlincreasedwithincreasingtemperatures.TheapparentactivationenergyofAlevaporationat1673-1843Kwas171.5kJmol-1.ThevalueofmasstransfercoefficientofAlintheliquidphasewasestimatedtobe3.77×10-6,7.41×10-6,and9.40×10-6ms-1at1673,1753,and1843K,respectively.Meanwhile,ratedeterminingstepswerediscussedanditwasconcludedthattheevaporationrateofAlismainlycontrolledbyliquidphasemasstransfer.
简介:我们集中于与Ni-Al金属间化合的混合物扔合金由的ligth重量的表面加强在原处改进非铁的扔的表面性质的燃烧反应部件。在我们的以前的工作,元素的Ni和艾尔粉末紧缩的绿色被SHS(自我繁殖的高温度合成)反应到形式Ni3Al金属间化合的化合物有熔融的艾尔合金并且同时的热的反应与艾尔扔结合了合金。但是象微小的裂缝和孔那样的一些缺点在反应协议被仍然是。我们因此使用了压力阻止热裂缝并且与液体艾尔合金充满毛孔由压榨扔过程。压缩艾尔合金与Ni3Al金属间化合的混合物结合了是sectioned并且由光显微镜学和扫描电子显微镜学(SEM)观察了。在结合的接口附近并且在反应协议形成的intermetallics的stoichiometric作文被散光谱学(版本)和电子探查的精力识别微分析(EPMA).Si富人层被艾尔的顺序的团结在结合的接口附近在艾尔合金方面上形成合金。在反应Ni3Al协议观察的孔与液体艾尔合金被充满。从熔融的艾尔合金的Si粒子在反应Ni3Al金属间化合的协议的毛孔被检测。扔合金和Ni3Al金属间化合的化合物的艾尔被把压力用于液体艾尔合金很很熟加入。
简介:ItwasshownbyTEMandX-rayanalysisthatNi3AlisthemainphaseoftheintermetallicsynthesizedundercompressionfromthepowdermixtureofNiwithAlalloyedbyB.TheNi3Bisasecondaryphase.ThevalueofthelatticeparameteroftheintermetallicNi3AlwithandwithoutBincreaseswhentheconcentrationofAlincreases.TheincreaseinAlconcentrationfrom23.5to25.0intheinitialpowdermixtureleadstodecreasingthesolubilityofBintheNi3Alphase.
简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof