学科分类
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21 个结果
  • 简介:Anovelfluorescencelifetimeimagingmicroscopy(FLIM)workingwithdeepUV240–280nmwavelengthexcitationshasbeendeveloped.UV-FLIMisusedformeasurementofdefect-relatedfluorescenceanditschangesuponannealingfromfemtosecondlaser-inducedmodificationsinfusedsilica.ThisFLIMtechniquecanbeusedwithmicrofluidicandbiosamplestocharacterizetemporalcharacteristicsoffluorescenceuponUVexcitation,acapabilityeasilyaddedtoastandardmicroscope-basedFLIM.UV-FLIMwastestedtoshowannealingofthedefectsinducedbysilicastructuringwithultrashortlaserpulses.Frequency-domainfluorescencemeasurementswereconvertedintothetimedomaintoextractlongfluorescencelifetimesfromdefectsinsilica.

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  • 简介:FurfuralinaqueoussolutionwastreatedbyUV/O3method.Theresultsshowthattheremovalrateoffurfuralisseverelyenhancedandthesynergismphenomenonappearswhenultravioletandozonearepresenttogether.TheinfluencesofexperimentalparameterssuchaspH,theintensityoflightandthenegative-positiveionsonfurfuraldegradationwereinvestigated.Theresultsindicatethatfurfural(300mg/L)isalmostcompletelydegradedafter3hundertheoptimumconditions.TheintermediateinthefurfuraldegradationwascharacterizedbyGC-MSandIRspectrumandthedegradationmechanismoffurfuralbyUV/O3technologywasproposed.

  • 标签: 全降解 糠醛 技术 协同作用 实验参数 光照强度
  • 简介:在一个给定的空间区域的全部的精力上的限制被就装入那个区域的一个黑洞的团从雷射摄影术给,它导致一种UV/IR关系:在那个区域的最大的精力密度与M在哪儿的p2/L2,Mp是普朗克常数团,L是在考虑下面的那个区域的空间规模。在宇宙假定最大的黑洞在宇宙通过不安的重力的倒塌被形成,然后不安的规模给原因的连接规模RCC。为重力的不安,R为扁平的宇宙的CC−2=马克斯(+2H2,−)。我们分别地由在UV/IR关系选择原因的连接规模为IR截止学习相应真空精力密度的宇宙论的动力学,在象一个独立地保存的精力部件和一个有效动态宇宙论的常数的真空精力密度的情况中。结果仅仅有选择R−2CC当真空密度作为一个独立地保存的精力部件出现时,2=+2H2,能与当前的宇宙论的观察一致。在这种情况中,模型在文学被称为holographicRicci分级的黑暗精力模型。

  • 标签: 红外 全息 紫外 暗能量 碾压混凝土 宇宙常数
  • 简介:Inthispaper,theUV-theoryandP-differentialcalculusareemployedtostudysecond-orderex-pansionofaclassofD.C.functionsandminimizationproblems.Undercertainconditions,somepropertiesoftheU-Lagrangian,thesecond-orderexpansionofthisclassoffunctionsalongsometrajectoriesareformulated.SomefirstandsecondorderoptimalityconditionsfortheclassofD.C.optimizationproblemsaregiven.

  • 标签: 非线性规划 非光滑最优化 最优性条件 UV-分解 D.C.最优化
  • 简介:Fivefluorine-containingvinylethermonomerswerepreparedbythereactionbetween2-vinyloxyethanol,afluorinatedalcoholandhexafluorobenzeneinthepresenceofsodiumhydrideindimethylformamide.Tworepresentativepropertiesofthesemonomers,UV-curingbehaviorinitiatedbyacationicphoto-initiatorPAG201andsurfacefreeenergyofcoatingfilms,wereinvestigated.Photo-polymerizationproceededbothrapidlyandcompletelywithahighdouble-bondconversion(>90%)andafastcuringrate(maximumcuringtime<21s)forthreemonomers.Thesurfaceenergiesofthemonomersandtheresultingpolymerfilmsweretheninvestigated.TheminimumsurfacefreeenergyoftheUV-curedhomopolymerfilmsreaches7.1mJ/m2.X-rayphotoelectronspectroscopydatashowthatthelowsurfacetensionisinfluencedbyfluorinecontentinthesoftsegmentsandfluorinatedchains'migrationtothesurface.Thefivemonomersexhibitlowviscosity,lowsurfaceenergy,goodthermalstabilityandgoodphoto-polymerizationproperties,whichmakethemgreatcandidatesforUVcoatingandphotoresistapplications.

  • 标签: 乙烯基醚 表面性能 UV涂料 固化行为 聚合物膜 阳离子光引发剂
  • 简介:ThecaptureoforthophosphatesandtotalphosphorusfromthePudongCanalriverinthePudongDistrictofShanghaibyTiO2nanoparticlesisstudiedusingarotatingphotoreactorandthenano-TiO2photocatalystDegussaP25.TheeffectsofUVirradiationintensityinarangeof20-74mW/cm2.theloadingoftheTiO2nanoparticlesinarangeof0.05-0.1g/L,irradiationtimeupto4h,andpHvaluesinarangeof2-10.5onthecaptureefficiencyareinvestigated.TheresultsshowthatthecaptureoforthophosphatesandtotalParesignificantlyenhancedbyUVirradiation;ataloadingof0.1g/Landanirradiationintensityabove36mW/cm2,orthophosphatesandtotalphosphorusarerapidlycapturedbyTiO2nanoparticles,causinganobservedreductionfrom0.4mg/Ldownto0.02mg/L.pHvaluesinarangeof2-10.5havelittleeffectonthecaptureefficiencyoforthophosphatesandtotalphosphorus.

  • 标签: 纳米二氧化钛光催化剂 紫外光照射 捕获 总磷 二氧化钛纳米粒子 地表水
  • 简介:TheparametricoptimizationoftheNe-CuBrUVlaserexcitedbylongitudinalpulseddischargeisanalysedbyusingaself-consistentkineticmodel.Consistentcharacteristicsoftheoptimizationprocessareobtainedbycomparingwiththeexperimentalresults.Simulationresultsshowthatneonionscomeintobeingalongwithconsiderabledepletionoftheground-statecopperatoms.Andtheoptimizationofthedischargetubediameteristhetradeoffbetweenthespecificoutputphotondensityandthetotalactivevolume.Boththeoptimalneongaspressureandtheoptimalreservoirtemperatureresultfromthebalancebetweentheneoniondensityandtheground-statecopperatomdensitytoarriveatamaximumoftheirproduct.

  • 标签: 溴化亚铜 输出功率 紫外激光 动力学分析 NE 参数优化
  • 简介:银电影(Ag)和有厚度~的silvergold电影(AgAu)15nm在通过热蒸发的Bk7眼镜上是涂的。在做5.2%的黄金以后,Ag电影的谷物尺寸从13.6把nm归结为9.1nm,也,表面粗糙从1.45nm减少到0.94nm。一盏紫外灯被用作照耀光来源在空气加速腐蚀过程。当AgAu电影更不降级时,在17h以后,照耀,纯银电影表面拐弯黑暗,和发射度从350把nm归结为500nm,几乎微不足道的在紫外放射以后。另外的X光光电子光谱学和原子力量显微图数据被提供显示出电影和他们的表面形态学的原子内容。小谷物尺寸和合金电影的高收拾行李密度在空气与氧阻止银的反应,这被建议,它导致AgAu电影的高稳定性。

  • 标签: 紫外光辐照 超薄银膜 银金合金薄膜 耐久性研究
  • 简介:Fe2O3solwiththeparticlediameterof3-5nmwasflocculatedbytheadditionofSDS,andtheflocculateformedwasredispersedbythefurtheradditionofthatsurfactant.ThusthesurfactantbilayerwasformedonthesurfaceofFe2O3.Theemulsionpolymerizationofstyrene(St)adsolubilizedonthesurfactantadsorbedbilayerwascarriedoutbyinitiatorpotassiumpersulfate(KPS).TheUV-Visandsurfacephotovoltagespectra(SPS)indicatethattheFe2O3particleswereencapsulatedinpolystyrene(PSt)successfully.

  • 标签: FE2O3 nanoparticles Encapsulation Composite MICROSPHERES
  • 简介:TheeffectsofmagneticfieldonthegraftratioandstereoregularityofgraftsofPVA-g-MMAinthepresenceofbenzophenoneduringUVirradiationarediscussed.BymeansofIR,itwasfoundthatthegraftratiowasincreasedwiththeincrementofmagneticfieldstrength.Furthermore,applicationofrelativeweakmagneticfieldof0.4Teslahadbeenshowntosubstantiallyenhancethestereo-regularityofgraftcopolymer.Themaximumstereo-regularityappearedwhenthegraftratioapproachedto85%withthemagneticfieldof1.2Tesla(T).Theresistancetomoistureandheatresistanceofthegraftedcopolymerinthepresenceofmagneticfieldwerealsoimproved.

  • 标签: Magnetic field GRAFT COPOLYMERIZATION Methyl METHACRYLATE
  • 简介:AsimplespectrophotometricassayofH2O2andglucoseusingAgnanoparticleshasbeencarriedout.RelyingonthesynergisticeffectofH2O2reductionandultraviolet(UV)irradiation,Agnanoparticleswithenhancedabsorptionsignalsweresynthesized.H2O2servedasareducingagentintheAgnanoparticlesformationinwhichAg+wasreducedtoAg0byO2àgeneratedviathedecompositionofH2O2inalkalinemedia.Ontheotherhand,photoreductionofAg+toAg0underUVirradiationsalsocontributedtothenanoparticlesformation.ThesynthesizednanoparticleswerecharacterizedbyTEM,XPS,andXRD.TheproposedmethodcoulddetermineH2O2withconcentrationsrangingfrom5.010à7to6.010à5mol/L.Thedetectionlimitwasestimatedtobe2.010à7mol/L.SincetheconversionofglucosetogluconicacidcatalyzedbyglucoseoxidasewascompaniedwiththeformationofH2O2,thesensingprotocolhasbeensuccessfullyutilizedforthedeterminationofglucoseinhumanbloodsamples.Theresultswereingoodagreementwiththosedeterminedbyalocalhospital.Thiscolorimetricsensorthusholdsgreatpromisesinclinicalapplications.

  • 标签: 银纳米粒子 葡萄糖利用 过氧化氢 H2O2 UV 分光光度测定法
  • 简介:Wehavesuccessfullydemonstratedthathighqualityandhighdielectricconstantlayerscanbefabricatedbylowtemperaturephoto-inducedor-assistedprocessing.Ta2O5andZrO2havebeendepositedatt<400℃bymeansofaUVphoto-CVDtechniqueandHfO2byphoto-assistedsol-gelprocessingwiththeaidofexcimerlamps.TheUVannealingofas-grownlayerswasfoundtosignificantlyimprovetheirelectricalproperties.Lowleakagecurrentdensitiesontheorderof10-8A/cm2at1MV/cmfordepositedultrathinTa2O5filmsandca.10-6A/cm2forthephoto-CVDZrO2layersandphoto-irradiatedsol-gelHfO2layershavebeenreadilyachieved.TheimprovementintheleakagepropertiesoftheselayersisattributedtotheUV-generatedactiveoxygenspeciesO(1D)whichstronglyoxidizeanysuboxidestoformmorestoichiometricoxidesonremovingcertaindefects,oxygenvacanciesandimpuritiespresentintheas-preparedlayers.Thephoto-CVDTa2O5filmsdepositedacross10.16-cmSiwafersexhibitahighthicknessuniformitywithavariationoflessthan±2.0%beingobtainedforultrathinca.10nmthickfilms.Thelamptechnologycaninprinciplebeextendedtolargerareawafers,providingapromisinglowtemperatureroutetothefabricationofarangeofhighqualitythinfilmsforfutureULSItechnology.

  • 标签: 溶胶-凝胶法 化学气相沉积 电介质 氧化物薄膜 低温 紫外线诱导