简介:Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.
简介:Theinterfacialbindingcovalentbonddensity(CBD)andthelocalenvironmentaltotalbondorder(LTBO)oftheNi/Ni3Alinterfacewithdifferentlatticemisfits(δ)werecalculatedbyusingfirst-principlesdiscretevariationXαmethod.ItwasfoundthattheeffectsoflatticemisfitsontheelectronicstructuresofincoherentNi/Ni3Alinterfacewereveryobvious.Ononehand,lessthan-0.6%negativelatticemisfitcanpromotethebindingstrengthofγ/γ′interface.Ontheotherhand,thetotalbondingstrengthofγ/γ′interfacedecreaseswithincreasingδ.Therefore,themagnitudeandsignoflatticemisfitmustbecarefullycontrolledforbalancingthehightemperaturecreepstrengthofNi-basesinglecrystalsuperalloyandthestructuralstabilityofγ/γ′interfacewhenonedesignsanewNi-basesinglecrystalsuperalloy.
简介:由Synechcoccus在Ni的简历累积上影响因素在这篇论文被学习。当到干燥重量集中ofSynechcoccus的Ni的集体比率是16-18%时,简历累积在附近是在水的solution.Bioaccumulation数量的80min的Ni的使平衡时间到达了最大值。Bioaccumulation数量与增加pH增加了。最佳pHwas9-10和更高的pH导致了Ni的降水(哦)_2。Bioaccumulation数量被在35℃到达他们的optima的温度和轻紧张也影响,无生命的水藻的3000Ixrespectively.Bioaccumulation比生活水藻的大。
简介:AseriesofNi-Hrechargeablebatterieswithatrademarkof‘JJJ’weresuecessfullydevelopedbyJiangnanTribleJcorporation,GuangdongProvince,andwereputintobatchproductionthisyear.ResearchonNi-HbatteryisoneoftheimportantprojectsinChina’sNationalHigh-TechProgramm.ScientistsinTribleJCorp.startedtheresearchlastyear.Afternearlyoneyear’sarduouswork,theycom-pletedthelabworkontheprojectandcametothe
简介:TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.
简介:ElNioorLaNiamanifestinDecemberoverthePacificandwillserveasanindexfortheforecastingofsubsequentIndiansummermonsoon,whichoccursfromJunetomid-September.Inthepresentarticle,anattemptismadetostudythevariationoflatentheatflux(LHF)overthenorthIndianOceanduringstrongElNioandstrongLaNiaandrelateitwithIndianmonsoonrainfall.DuringstrongElNiotheLHFintensityishigherandassociatedwithhigherwindspeedandlowercloudamount.DuringElNioallIndiarainfallishavinganinverserelationwithLHF.SeasonalrainfallishigherinYY+1(subsequentyear)thanYY(yearofoccurrence).HoweverthereisalaginrainfallduringElNioYY+1fromJunetoJulywhencomparedwiththemonthlyrainfall.
简介:1IntroductionThenickelaloysandcomplexesarewidelyusedasmagnetic,optical,nuclearandsuperconductingmaterials[1,2].Manynickelcom...
简介:1IntroductionNorfloxacinbelongstothecompoundoftheseriesofcarbostyrilcontainingfluorine.Itisabroadspectrumantimicrobial,and...
简介:通过化学沉积法制备Ni-P、Ni-Mo-P单镀层以及与其成分相同的Ni-P/Ni-Mo-P双镀层。采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10%HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系。结果表明:Ni-P单镀层和Ni-P/Ni-Mo-P双镀层表现为残余压应力,分别为241和206MPa;Ni-Mo-P单镀层呈现出257MPa的残余拉应力。残余压应力阻止镀层中孔洞的生长,保护镀层的完整性。Ni-P/Ni-Mo-P双镀层比它们的单镀层具有更好的耐蚀性。此外,镀层的应力状态影响其腐蚀形式。
简介:ThemagnetizationreversalmechanismsforNinanowireswithdifferentdiameterswereinvestigatedbymi-cromagneticsimulations.Theresultsshowthatthereversalmechanismsaresignificantlydependentonthediameterofwire.Forverythinwires,thereversaloccursbypseudo-coherentrotation.Withincreasingdiam-eter,magnetizationreversaltakesplaceviadifferentnucleation(thetransversedomainwallandthevortexdomainwall)andsubsequentpropagation.Thereasonoftransitionfromthetransversedomainwalltothevortexdomainwallisgivenbyanalyticalstudies.Withfurtherincreaseofthediameter,thereversalnucleardomainwallbecomestundish-shapedform.Asthediameterincreases,thewidthofwallbecomeslarger.
简介:PrecipitationstudywascarriedoutinNi-35at.pctCralloybymeasuringelectricalresistivityatdifferentageingtemperaturesandlongageingtimes.Duringageing,itwasobservedthatelectricalresistivityinitiallyrosewithageingtimeandthenfellafterverylongageingataconstanttemperature.TheinitialincreaseinresistivityduringageingmaybeattributedtotheformationofGPzones/Cr-richprecipitatesatearlystagesbynucleationprocessanddecreaseinresistivity,andafterattainingamaximum,isduetothegrowthofprecipitateparticlesandsubsequentlybycoarseningoftheseprecipitates.TheresultsofelectricalresistivitymeasurementsduringageingwereconfirmedbyX-raydiffractionanalysisindicatingtheformationofaCr-richphaseandaCr3Ni2phaseintheNimatrix.
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