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500 个结果
  • 简介:Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

  • 标签: Hydrogen oxidation reaction FUEL CELLS Alkaline
  • 简介:Theinterfacialbindingcovalentbonddensity(CBD)andthelocalenvironmentaltotalbondorder(LTBO)oftheNi/Ni3Alinterfacewithdifferentlatticemisfits(δ)werecalculatedbyusingfirst-principlesdiscretevariationXαmethod.ItwasfoundthattheeffectsoflatticemisfitsontheelectronicstructuresofincoherentNi/Ni3Alinterfacewereveryobvious.Ononehand,lessthan-0.6%negativelatticemisfitcanpromotethebindingstrengthofγ/γ′interface.Ontheotherhand,thetotalbondingstrengthofγ/γ′interfacedecreaseswithincreasingδ.Therefore,themagnitudeandsignoflatticemisfitmustbecarefullycontrolledforbalancingthehightemperaturecreepstrengthofNi-basesinglecrystalsuperalloyandthestructuralstabilityofγ/γ′interfacewhenonedesignsanewNi-basesinglecrystalsuperalloy.

  • 标签: γ/γ′ interface LATTICE misfit DV-Xα method
  • 简介:由Synechcoccus在Ni的简历累积上影响因素在这篇论文被学习。当到干燥重量集中ofSynechcoccus的Ni的集体比率是16-18%时,简历累积在附近是在水的solution.Bioaccumulation数量的80min的Ni的使平衡时间到达了最大值。Bioaccumulation数量与增加pH增加了。最佳pHwas9-10和更高的pH导致了Ni的降水(哦)_2。Bioaccumulation数量被在35℃到达他们的optima的温度和轻紧张也影响,无生命的水藻的3000Ixrespectively.Bioaccumulation比生活水藻的大。

  • 标签: 生物积累 矿山排水污染 环境保护
  • 简介:AseriesofNi-Hrechargeablebatterieswithatrademarkof‘JJJ’weresuecessfullydevelopedbyJiangnanTribleJcorporation,GuangdongProvince,andwereputintobatchproductionthisyear.ResearchonNi-HbatteryisoneoftheimportantprojectsinChina’sNationalHigh-TechProgramm.ScientistsinTribleJCorp.startedtheresearchlastyear.Afternearlyoneyear’sarduouswork,theycom-pletedthelabworkontheprojectandcametothe

  • 标签: BATTERY BATCH CORPORATION BATTERY GUANGDONG sized
  • 简介:用浸渍法制备了一系列含镍的催化剂,以TPR、TPD、XRD及XPS等手段分别对Ni/海泡石及Ni/Sm海泡石催化剂进行了表征。结果表明,助剂钐的加入不仅使镍粒变小,而且也降低了镍原子结合能,除此以外,镍的分散亦有提高。TPR与TPD测试表明钐的加入亦能引起峰温的变化。更多还原

  • 标签: 镍催化剂 海泡石 CO2 甲烷化
  • 简介:Mg2Ni氢存储合金的电气化学的性质上的镍涂层的效果在这份报纸被介绍。X光检查衍射(XRD)和扫描电子显微镜(SEM)技术被采用检验赤裸、Ni涂的Mg2Ni合金的水晶结构和表面形态学。合金的电气化学的性质被周期的voltammetry(CV)和电气化学的阻抗光谱学(EIS)描绘。结果显示出那Ni涂层不仅减少费用转移抵抗,而且减少为Mg2Ni合金的H原子散开抵抗。Ni涂层有效地改进了分泌物能力,这也被发现,但是减少同样综合的Ni涂的Mg2Ni合金的骑车的表演。分泌物电流在同样综合的Ni涂的Mg2Ni合金的骑车的表演上有大影响。

  • 标签: 氢贮存合金 化学覆盖层 循环伏安法 电气化学
  • 简介:TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.

  • 标签: 催化剂 催化剂镍 纳米晶体
  • 简介:ElNioorLaNiamanifestinDecemberoverthePacificandwillserveasanindexfortheforecastingofsubsequentIndiansummermonsoon,whichoccursfromJunetomid-September.Inthepresentarticle,anattemptismadetostudythevariationoflatentheatflux(LHF)overthenorthIndianOceanduringstrongElNioandstrongLaNiaandrelateitwithIndianmonsoonrainfall.DuringstrongElNiotheLHFintensityishigherandassociatedwithhigherwindspeedandlowercloudamount.DuringElNioallIndiarainfallishavinganinverserelationwithLHF.SeasonalrainfallishigherinYY+1(subsequentyear)thanYY(yearofoccurrence).HoweverthereisalaginrainfallduringElNioYY+1fromJunetoJulywhencomparedwiththemonthlyrainfall.

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  • 简介:1IntroductionThenickelaloysandcomplexesarewidelyusedasmagnetic,optical,nuclearandsuperconductingmaterials[1,2].Manynickelcom...

  • 标签: Nickel CHLORIDE ELECTROCHEMICAL BEHAVIOR Transfer COEFFICIENT
  • 简介:1IntroductionNorfloxacinbelongstothecompoundoftheseriesofcarbostyrilcontainingfluorine.Itisabroadspectrumantimicrobial,and...

  • 标签: THERMAL DECOMPOSITION Nonisothermal KINETICS Mechanisms Ni()
  • 简介:采用电沉积法在T91钢基体上制备NiNi/CeO2镀层,研究该镀层试样在温度分别为750℃和800℃,ω(Ar)=90%、ω(H2O)=10%气氛中的氧化行为。测量试样氧化动力学曲线并利用X射线衍射仪测定样品氧化后表面产物的相,利用带能谱分析功能EDS的扫描电镜SEM观察样品表面和截面形貌。结果表明:NiNi/CeO2镀层对T91钢高温水蒸气氧化具有一定防护作用;此外,Ni/CeO2镀层中纳米CeO2颗粒抑制了氧化膜的开裂,改善了氧化膜的黏附性,提高了T91钢镀Ni试样的耐高温水蒸气氧化性能。

  • 标签: T91钢 氧化动力学 水蒸气 Ni/CeO2镀层 稀土
  • 简介:通过化学沉积法制备Ni-P、Ni-Mo-P单镀层以及与其成分相同的Ni-P/Ni-Mo-P双镀层。采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10%HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系。结果表明:Ni-P单镀层和Ni-P/Ni-Mo-P双镀层表现为残余压应力,分别为241和206MPa;Ni-Mo-P单镀层呈现出257MPa的残余拉应力。残余压应力阻止镀层中孔洞的生长,保护镀层的完整性。Ni-P/Ni-Mo-P双镀层比它们的单镀层具有更好的耐蚀性。此外,镀层的应力状态影响其腐蚀形式。

  • 标签: 化学沉积 Ni-P/Ni-Mo-P双镀层 残余应力 纳米压痕法 耐蚀性
  • 简介:ThemagnetizationreversalmechanismsforNinanowireswithdifferentdiameterswereinvestigatedbymi-cromagneticsimulations.Theresultsshowthatthereversalmechanismsaresignificantlydependentonthediameterofwire.Forverythinwires,thereversaloccursbypseudo-coherentrotation.Withincreasingdiam-eter,magnetizationreversaltakesplaceviadifferentnucleation(thetransversedomainwallandthevortexdomainwall)andsubsequentpropagation.Thereasonoftransitionfromthetransversedomainwalltothevortexdomainwallisgivenbyanalyticalstudies.Withfurtherincreaseofthediameter,thereversalnucleardomainwallbecomestundish-shapedform.Asthediameterincreases,thewidthofwallbecomeslarger.

  • 标签: 镍纳米线 反磁化 模拟 直径 畴壁 机制
  • 简介:PrecipitationstudywascarriedoutinNi-35at.pctCralloybymeasuringelectricalresistivityatdifferentageingtemperaturesandlongageingtimes.Duringageing,itwasobservedthatelectricalresistivityinitiallyrosewithageingtimeandthenfellafterverylongageingataconstanttemperature.TheinitialincreaseinresistivityduringageingmaybeattributedtotheformationofGPzones/Cr-richprecipitatesatearlystagesbynucleationprocessanddecreaseinresistivity,andafterattainingamaximum,isduetothegrowthofprecipitateparticlesandsubsequentlybycoarseningoftheseprecipitates.TheresultsofelectricalresistivitymeasurementsduringageingwereconfirmedbyX-raydiffractionanalysisindicatingtheformationofaCr-richphaseandaCr3Ni2phaseintheNimatrix.

  • 标签: 镍合金 铬合金 X射线衍射 性质 显微组织 电阻
  • 简介:SPATIO┐TEMPORALDISTRIBUTIONOFNiDEPOSITSTheNidepositsinChinaaredistributedinGansu(Jinchuan),Xinjiang(Karatunggu,Huangshan),Jil...

  • 标签: deep seated liquation injection spatio TEMPORAL
  • 简介:发泡式镉镍电池产品中,相当部分电池在搁置一月左右之后,开路电压下降至1.00~1.10V.分析了电压下降的原因;提出了有效的解决措施;检测改进后的AAK900型电池的荷电保持能力和开路电压,结果表明,以上措施可以有效防止镉镍电池的低电压现象.

  • 标签: CD-NI电池 低电压 开路电压 荷电保持率 电解液 镉镍电池