简介:TheLa-CosubstitutedSr_(1–x)La_xFe_(12–x)Co_xO_(19)(x=0–0.5)ferriteswithappropriateBi_2O_3additivewerepreparedbyconventionalsinteringmethodandmicrowavesinteringmethodatlowsinteringtemperaturescompatiblewithLTCC(lowtemperatureco-firedceramics)systems,andtheirsinteringbehaviorwaschieflyinvestigated,includingthecrystalstructure,saturationmagnetizationMs,magneticanisotropyfieldHa,intrinsiccoercivityHci,andCurietemperatureTC.ExperimentresultsclearlyshowedthatthepureM-typecrystalphasewassuccessfullyobtainedwhentheLa-Cosubstitutionamountxdidnotexceed0.3.However,thesingleM-typephasestructuretransformedtomultiphasestructurewithfurtherincreasedx,wheretheM-typephasecoexistedwiththenon-magneticphasesuchasα-Fe_2O_3phase,La_2O_3phase,andLaCoO_3phase.AppropriateLa-CosubstitutionimprovedtheMs(〉62emu/g),Ha(〉1400kA/m),andHci(〉320kA/m)fortheferriteswithxvaryingfrom0.1to0.3,buttheTCdecreasedwithincreasingsubstitutionamount.Moreover,themicrowavesinteredferritescouldprovidelargerHciandsimilarMscomparedwiththeconventionalsinteredferrites.
简介:La公司代替了M类型钡铁酸盐(欺骗)由传统的稳固的状态被准备在低温度(1173K)的方法和sintered。X光检查衍射(XRD),扫描电子显微镜学(SEM)和颤动的样品磁强计(VSM)被采用在样品的结构和磁性上调查La公司的影响。由在为在空中的6h的1173K的sintering,有Ba(LaCo)xFe122xO19(x=0.00.5)的化学作文的单个阶段M类型钡铁酸盐被形成。M-H曲线证明钡铁酸盐的磁性被La公司替换显然完成。浸透磁化(女士)和coercivity(Hc)分别地到达了65.15Am2/kg和4165Oe的最大的价值。这行为被归因于La公司替换和粒子尺寸的地点。SEM表明铁酸盐粒子的形状被La公司替换影响。
简介:TheeffectofLaelementonthemechanicalpropertiesandconstitutionnearbygrainboundaryinaCo-basesuperalloyCo-22Ni-22Cr-14kduring760℃ageinghasbeeninvestigatedbyAESandmaterialtesting.ResultsshowthatelementLacanbeinastateofsolidsolutionandsegregatesmainlyatthevicinityofgrainboundaries.ThepriorsegregationofLaatomscanaffectsegregationbehaviourofotherelements,sothatexertsinfluenceonmicrostructureofthealloy,ParticularlyincreasingofLacontentcandecreasePconcentrationatthevicinityofgrainboundariesbutnotdecreaseSconcentration.StogetherwithLaproducecosegregationeffect.ThecontentofLahasnoobviouseffectonhightemperaturestrength.WhenthecontentofLacomesupto0.02wt-%,itcanobviouslyimprovethehightemperatureductility.
简介:Low-CoLa1.8Ti0.2MgNi8.9Co0.1alloyswerepreparedbymagneticlevitationmeltingfollowedbyannealingtreatment.TheeffectofannealingonthehydrogenstoragepropertiesofthealloyswasinvestigatedsystematicallybyX-raydiffraction(XRD),pressure-compositionisotherm(PCI),andelectrochemicalmeasurements.TheresultsshowthatallsamplescontainLaNi5andLaMg2Ni9phases.LaCo5phaseappearsat1,000℃.Theenthalpychangeofallhydridesiscloseto-30.6kJ·mol-1H2ofLaNi5compound.Annealingnotonlyincreaseshydrogencapacityandimprovescyclingstabilitybutalsodecreasesplateaupressureat800and900℃.Afterannealing,thecontractionofcellvolumeandtheincreaseofhydridestabilitycausethehighratedischargeabilitytoreduceslightly.Theoptimumalloyisfoundtobeoneannealedat900℃,withitshydrogencapacityreachingupto1.53wt%,anddischargecapacityremaining225.1mAh·g-1after140charge–dischargecycles.
简介:PolycrystallineNd3+andLa3+co-dopedyttriananopowderNd3+:Y1.90La0.10O3fortransparentceramicswassynthesizedbyco-precipitationmethodusingoxalateacidastheprecipitantand(NH4)2SO4astheelectricalstabilizerunderultrasonicradiation.Nanopowderscalcinedatdifferenttemperatureswerecharacterizedwiththermalgravimetric-differentialthermalanalysis(TG/DTA),X-raydiffraction(XRD),transmittingelectronmicroscopy(TEM),energydispersivespectrometry(EDS)andspectralanalysistechniques.Th...
简介:Thispaperreportsonthelongevityofglycerol-dry(CO2)reformingoverthelanthanum(La)promotedNi/Al2O3catalysts.TheXRDresultsshowedthattheNiparticlewaswell-dispersedinthepresenceofLapromoter.Inaddition,viatheNH3-TPDanalysis,itwasfoundthattheLapromoterhasreducedtheacidityofNicatalystwhichmayhaveexplainedthemitigationofcarbonlaydown.Itwasdeterminedthatthe3.0wt%La-promotedNi/Al2O3catalystpossessedthelargestBETspecificsurfaceareaof97m2g-1.Consequently,ityieldedthebestcatalyticlongevityperformancewithconversionattainedmorethan90%,evenafter72hofreactionduration.Significantly,itcanbeconfirmedthatthepresenceofCO2duringtheglyceroldryreformingwasessentialinreducingcarbondeposition,mostlikelyviagasificationpathway.Thishasensuredastabilityofcatalyticactivityforalongreactionperiod(72h).
简介:ThestructureandelectrochemicalcharacteristicsofLa0.7Mg0.3Ni2.875Co0.525Mn0.1-boroncompositewasstudiedsystematically.TheAB3typehydrogenstoragealloysLa0.7Mg0.3Ni2.875Co0.525Mn0.1weresuccessfullysynthesizedbymeansofinter-mediaalloyLa2Mg17.Thealloyswerecompositedwithboronatdifferentweightrate.FromtheXRDanalyses,eachalloyofthisseriesismainlycomposedof(La,Mg)Ni3phaseandtheLaNi5phase,andthephaseabundanceofeachphasevarieswiththeboronweightrate,moreover,aftercomposition,thecandcellvolumesof(La,Mg)Ni3phaseincrease,andtheLaNi5phasekeepthesame,whichindicatethattheboronmayenter(La,Mg)Ni3phase.Theelectrochemicalstudiesshowthatthemaximumdischargecapacityofthecompositesdecreases,butthecyclinglifeimproved.Andthehighratedischargeabilityandexchangeimpendencespectroscopy(EIS)oftheAB3alloysanditscompositewerealsostudied.
简介:Sincethe1980s,IhavetrampedthemountainsandriversofnearlyalltheTibetan-inhabitedareas.WhattouchesmedeeplyisthatwhereverIwent,Iwouldfindholymountains,holyriversandholylakes.Invisibledeitiescanbefoundeverywhereatanytime.Likeman,theyarehierarchical.Smallholymountainsservelargeholymountainsandperformdutiesforthem.Thefourlargestholymountainsare:MagyiabenriMountainintheeast,
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简介:通过气雾化方法制备Al86Ni7Y4.5Co1La1.5(摩尔分数,%)合金粉末。首先,将粉末进行不同时间的球磨,然后在不同的烧结温度及保压时间等条件下对粉末分别进行热压烧结和放电等离子烧结。通过X射线衍射仪(XRD),扫描电镜(sEM)以及透射电镜(TEM)对粉末和块体材料的显微组织和形貌进行表征。结果表明:在特定球磨参数下球磨100h以上可以产生非晶,而且通过放电等离子烧结可以得到非晶/纳米晶块体材料,然而这种材料的相对密度较低。通过热压烧结可制备抗压强度为650MPa的Al86Ni7Y4.5Co1La1.5纳米块体材料。
简介:Afewhours'drivetookmetoaplacecalledBingzhongluo,thelargestpieceofflatlandinthecanyon,wheretheNujiangRivertakestwoabruptturns,formingthefirstbendontheNujiangRiver,whichisabestknownscenicspotinChina.Atthesideoftheriverthereisatabletofpurewhitemarbleinscribedwithwordspaintedinbrightred,reading:“Bingzhongluo,theShangri-La.”
简介:ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.