简介：LARED-H程序是一个可用于激光黑腔靶耦合数值模拟研究的二维辐射流体力学程序。黑腔等离子体所形成的复杂流场使单纯的拉格朗日网格在计算中产生严重扭曲，影响计算精度，并导致计算中断。拉氏加网格重分是计算激光黑腔靶耦合常用的算法。对LARED-H程序的积分网格重分方法在网格重构和物理量重映方面作了较大改进，并利用改进后的LARED-H程序模拟了“神光”-Ⅱ和“神光”-Ⅲ条件下的激光空腔靶耦合物理全过程。

简介：BasedupontheHellinger-Reissner(H-R)mixedvariationalprincipleforthree-dimensionalelasticbodies,themodifiedH-Rmixedvariationaltheoremformagnetoelectroelasticbodieswasestablished.Thestate-vectorequationofmagnetoelectroelasticplateswasderivedfromtheproposedtheorembyperformingthevariationaloperations.Tolayatheoreticalbasisofthesemi-analyticalsolutionappliedwiththemagnetoelectroelasticplates,thestate-vectorequationforthediscreteelementinplanewasproposedthroughtheuseoftheproposedprinciple.Finally,itispointedoutthatthemodifiedH-Rmixedvariationalprincipleforpureelastic,singlepiezoelectricorsinglepiezomagneticbodiesarethespecialcasesofthepresentvariationaltheorem.

简介：Poly(azureblueⅡ)(PABⅡ)thinfilmmodifiedelectrodewassuccessfullyassembledonthesurfaceofaglassycarbonelec-tradebymeansofelectrochemicalpolymerization,whichwascarriedoutwithcyclicvoltammetricsweepinginthepotentialrangeof-0.6to+1.3V(vs.SCE)inBritton-Robinsonbuffersolution(pH=9.8)containing1.25x10^-4mol/LazureblueⅡ.TheeffectofpHonthepolymerizationprocessofazureblueⅡandthedeetrochemicalcharacteristicsofthepolymer-modifiedelectrodeswerestudiedindetail.Theexperimentalre-suitsindicatedthattheelectropolymerizatiouofazureblueⅡcouldtakeplaceinbasicorneutralmedia.Thecyclicvoltam-mogramsofpoly(azureblueⅡ)thinfilmmodifiedelectrodeshowedthepresenceoftwocouplesofredoxpeaks.Thefilmmodifiedelectrodeexhibitedpotentandpersistentelectrocataly-sisforoxidationofdihydronicotiamideadeninedinucleotide(NADH)inphosphatebuffermediawithadiminutionoftheoverpotentialofabout410mVandanincreaseinpeakcurrent.ThepresenceofsomedivalentcationsinanelectrolytecangreatlyenhancetheeleetrocotolyficcurrentforoxidationofNADH.TheeleetrocatalyticcurrentincreasedlinearlywithNADHconcentrationfrom1.0×10^-5to8.0×10^-3mol/Linthepresenceof4.0×10^-2mol/LMg^2+cation.Thedetectionlimit(3Sb1/S)WaS5.0×10^-6mol/L,andtherelativestandarddeviationofdeterminationresultswas4.2%forsixsuccessivedeterminationsof5.0×10^-4mol/LNADHinthepresenceofMg^2+cation.

简介：Twofamiliesofcatalysts,basedonPdnanoparticlessupportedonceramicasymmetrictubularaluminamembranes,arestudiesinthedirectsynthesisofH_2O_2.TheyarepreparedbydepositingPdintwoways:(i)reductionwithN_2H_4inanultrasonicbathand(ii)byimpregnation-deposition.Thefirstpreparationleadstolargerparticles,withaveragesizeofaround11nm,whilethesecondpreparationleadstosmallerparticles,withaveragesizearound4nm.Thecatalyticmembranesweretestedasprepared,afterthermaltreatmentinairandafterfurtherpre-reductionwithH_2inmild(100℃)conditions.SampleswerecharacterizedbyTEM,CO-chemisorptionmonitoredbyDRIFTSmethodandTPR,whilecatalytictestshavebeenperformedinasemi-batchrecirculationmembranereactor.Experimentalcatalyticresultswereanalysedusingtwokineticsmodelstoderivethereactionconstantsfortheparallelandconsecutivereactionsofthekineticnetwork.SmallerparticlesofPdshowlowerselectivityduetothehigherrateofparallelcombustion,evenifthebetterdispersionofPdandthushighermetalsurfaceareainthesampleleadtoaproductivityinH_2O_2similarorevenhigherthanthesamplewiththelargerPdparticles.IndependentlyonthepresenceofsmallerorlargerPdnanoparticles,anoxidationtreatmentleadstoasignificantenhancementintheproductivity,althoughthecatalystprogressivelyreducesduringthecatalyticprocess.Theinhibitionoftheparallelcombustionreaction(towater)inducedfromthecalcinationtreatmentremainsafterthein-situreductionoftheoxidizedPdspeciesformedduringthepre-treatment.Thisislikelyduetotheeliminationofdefectsiteswhichdissociativelyactivateoxygen,andtentativelyattributedtoPdsitesabletogivethree-andfour-foldcoordinationofCO.

简介：ThispaperinvestigatestherobuststochasticstabilityandH∞analysisforstochasticsystemswithtime-varyingdelayandMarkovianjump.Byusingthefreeweightingmatrixtechnique,i.e.,He’stechnique,andastochasticLyapunov-Krasovskiifunctional,newdelay-dependentcriteriaintermsoflinearmatrixinequalitiesarederivedforthetherobuststochasticstabilityandtheH∞disturbanceattenuation.Threenumericalexamplesaregiven.Theresultsshowthattheproposedmethodisefficientandmuchlessconservativethantheexistingresultsintheliterature.更多还原

简介：为electrophilic硝代的一个选择、有效的过程用N2O5被描述为一个绿nitrating代理人，是的H沸石在温和条件下面的稳固的酸催化剂和形状控制代理人。

简介：Ionothermalsynthesiswasusedtoprepareanovelaminoacidcontaininghybridzincophosphatemonomer,[Zn(HPO4)(H2PO4)][C6H10N3O2](denotedasZnPO-CJ58).Theinorganicframeworkof[Zn(HPO4)(H2PO4)]·[C6H10N3O2]consistsof4-memberedringsformedbyZnO3OHisandPO2(OH)2tetrahedra.TheHPO4andaminoacidmoietieshangontheZncenter.Suchaframeworkisstabilizedbyextensivemultipointhydrogenbondsinvolvingthephosphateunitsandhistidinemoleculestoformapseudo-3Dsupramolecularstructure.ItisnoteworthythatZnPO-CJ58isthefirstzincphosphateclusterwithaminoacidactingastheligand.Itexhibitsphotoluminescenceexcitedatawavelengthof220nm.Interestingly,ZnPO-CJ58cantransformintoalayeredstructure(C6H10N3O2)Zn2·(HPO4)(PO4)·H2O(ZnPO-CJ36)throughfurtherreactingwithwaterorzincacetatedihydrateinwaterat85℃for1h.Thisworkwillbehelpfulforthesynthesisofcrystallineinorganic-organichybridmaterialswithbiofunctionalmolecules.

简介：利用水热法首次合成了具有两种配位环境Cd原子的新型杂多蓝化合物[NH3（CH2）2NH3]5[Cd（H2O）][CdMo12^vO30（HPO4）6（H2PO4）2]·5H2O．通过元素分析、ICP、TG和X射线单晶衍射确定了其组成，使用IR和EPR进行了结构表征．通过N2吸附脱附测定了比表面积和孔径，为催化研究提供了基础数据．结果表明：该晶体为三斜晶系，P-1，空间群；晶胞参数a=1．2002（2）nm，b=1．4651（3）nm，c=2．1192（4）nm，V=3．5642（12）nm^3，p=83．01（3）°，Z=2，F（000）=2932，R1=0．0300，wR2=0．0716．

简介：The2-Dheteronuclearcoordinationpolymer{[Ag4Fe2(SCN)12(H2O)2][(inaH)2(H2O)2]}n(1)(inaHistheabbreviationofprotonatedisonicotinicacid)withchemicalformulaC24H20Ag4Fe2N14O8S12hasbeensynthesizedandcharacterizedbysinglecrystalX-raydiffraction,elementalanalysisandIRspectroscopy.TheAgES2ringsconnecttwokindsofoctahedralgeometriesofFe(Ⅲ)ions,[Fe(NCS)6]^3-and[Fe(H2O)E(NCS)4]^-unitswithbridgingthiocyanateionsleadingto2-D[Ag4Fe2(SCN)12(H2O)2]^2-anionframework.Fourkindsofringsincludingtheunprecedentedthirty-twomemberedAg4Fe4(SCN)8ringssharecomersoredgesinthe2-Danionlayerstructure.AllthiocyanatescoordinatetothemetalionsaccordingtotheHSABprinciplewithNatomsbindingtotheFe(Ⅲ)ionsandwithSatomsbindingtoAg(I)ions.Pronoatedinacationsstabilizethelayerstructureascounterionsandhydrogenbondswereformedwithinthepronoatedinacationsdimerandbetweenthedimersandthelatticewaters.Crystaldata:Mr=1560.44,triclinic,P-↑1,a=0.76082(1)nm,b=0.9234nm,c=1.85611(4)nm,α=103.0170(10)°,β=93.7780(10)°,γ=97.4080(10)°,V=1.25385(3)nm^3,Z=1,μ(MoKα)=2.650mm^-1,Dc=2.067g·cm^-3,F(000)=758,R1=0.0412,wR2=0.1003.

简介：用均值-回复过程刻画股票价格变化,本文研究了股票收益可预测金融市场中的连续时间资产负债管理问题。运用动态规划方法,求得了最优资产负债管理策略的闭合解。结果表明,最优策略是风险溢价的线性函数,随着投资期限的缩短,股票上的投资金额不断降低。数值分析表明,投资期限、股票风险溢价和债务对于最优资产配置策略和股票风险溢价不确定性跨期对冲需求都存在显著影响。

简介：本文提出一种ＧＰＳ动态定位滤波的新方法。该方法直接从ＧＰＳ接收机输出的定位结果入手，将各种误差因素的影响等效为输出定位结果的总误差，视为有色噪声，建立线性卡尔曼滤波模型对位置和速度信息进行估计。与以往采用的非线性卡尔曼滤波器相比，滤波后定位误差明显减小，且模型简单，系统运算量降低，实时性较好。另外，为了提高滤波器的动态性能，还提出了一种有效的次优加权自适应卡尔曼滤波算法

简介：本文讨论如何利用GPS接收机的高精度定位信息来标定和补偿捷联惯性导航系统(SINS,以下用缩写代替)的积累误差。文中叙述了GPS/SINS组合系统的主要特点、组成、设计和实现,同时给出了实验室静态测试数据和跑车试验中的主要结果。

简介：在B型关联分析基础上给出了同异反同一度和综合同一度的概念，论证了同异反动态关联分析的性质及其求解方法，为研究事物的发展态势提供了一种动态分析方法。

简介：ThispaperproposesanadaptivejointsourceandchannelcodingschemeforH.264videomulticastoverwirelessLANwhichtakesintoaccounttheusertopologychangesandvaryingchannelconditionsofmultipleusers,anddynamicallyallocatesavailablebandwidthbetweensourcecodingandchannelcoding,withthegoaltooptimizetheoverallsystemperformance.Inparticular,sourceresilienceanderrorcorrectionareconsideredjointlyintheschemetoachievetheoptimalperformance.Andachannelestimationalgorithmbasedontheaveragepacketlossrateandthevarianceofpacketlossrateisproposedalso.Twooverallperformancecriteriaforvideomulticastareinvestigatedandexperimentalresultsarepresentedtoshowtheimprovementobtainedbythescheme.

简介：Arylhalidesareakindofextremelyvaluablecompoundsusedintransition-metal-catalyzedcouplingreactions,aswellasimportantstructuremotifsinmanynaturalproductsandmanufactureddrugs[1,2].Theclassicalapproachforpreparationofhaloarenesiselectrophilicaromaticsubstitution(EAS)usingvarioushalogenatingreagentsoroxidativehalogenationswithhalogenatingreagentgeneratedinsitufromhalidesandoxidants,suchasperoxide,oxygenandmeta-cholorperoxybenzoicacid(mCPBA)[3,4].However,harshreactionconditionsarerequiredforhalogenationoflessactivearomatics.orthoMetalationfollowedbyhalogenquenchingisanotherapproachforhalogenationofaromatics[5].However,thereareobviousdrawbacksforthesemethods,suchaslowregioselectivity,harshconditionsandevendangerousprocedures.Therefore,thedevelopmentofanalternativeandpracticalwayremainschallengeinorganicsynthesis.

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简介：Afacileandconvenientsynthesismethodhasbeendevelopedforsubstitutedquinoxalinesand2H-benzo[b][1,4]oxazinesfromthereactionsofα-bromoketoneswithbenzene-1,2-diamineand2-aminophenol,respectively,whichwerecatalyzedbytetrabutylammoniumbromide(TBAB)inaqueousbasicmedia.