简介：ＡｐｐｌｉｃａｔｉｏｎｏｆＲａｒｅＥａｒｔｈｓｉｎＯｉｌＣｏｕｎｔｒｙＴｕｂｕｌａｒＧｏｏｄｓＬｉｎＱｉｎ（林勤），ＹａｏＴｉｎｇｊｉｅ（姚庭杰），ＬｉｕＡｉｓｈｅｎｇ（刘爱生）ＣｈｅｎＮｉｎｇ（陈宁），ＹｅＷｅｎ（叶文），ＹｕＺｏｎｇｓｅｎ（余宗森...

简介：Theneedformoreactiveandhydrothermallystablefluidcatalyticcracking(FCC)catalyststocombattheeffectofmetalcontaminantshasledtoanincreaseindemandforrareearthoxides.RareearthoxidesenhancecatalystactivityandpreventthelossofacidsitesduringtheFCCunitoperation,especiallywhenheavyresiduewithhighmetalcontentisusedasfeed.Inthispaper,areviewwascarriedouttoshowtheeffectsofrareearthelementsonthestructure,activity,andstabilityofFCCcatalysts.Also,theuseofrareearthelementsasvanadiumtrapswasanalyzedinconjunctionwiththemechanismofcatalystdeactivationbyvanadium.TheobjectivewastoelucidatetheinteractionofvanadiumspecieswiththezeolitecomponentoftheFCCcatalystsandtheroleofrareearthelementsincounteringthedeleteriouseffectsofvanadiumontheFCCcatalysts.

简介：ＡｐｐｌｉｃａｔｉｏｎｏｆｔｈｅＥｕ３＋ＩｏｎｆｏｒＳｉｔｅＳｙｍｍｅｔｒｙＤｅｔｅｒｍｉｎａｔｉｏｎＢｉｎｎｅｍａｎｓＫ，Ｇｏｒｌｌｅｒ－ＷａｌｒａｎｄＣ(ＵｎｉｖｅｒｓｉｔｙｏｆＬｅｕｖｅｎ，ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，Ｃｏ?..

简介：Terfenol-D杆是否应该被把压成薄片，具有在为动态应用设计一个magnetostrictive致动器的开始的担心。迭合能减少旋涡水流损失，而且减少GMM杆的僵硬。常规方法由是复杂的女性(有限元素的方法)或一个的经验。在这篇文章，在杆的剖面图的磁场分发的一条分析途径被描述，并且如果Terfenol-D杆应该被把压成薄片，它作为一个参考方法被介绍给法官。数字评估和试验性的结果证明了途径的合理性和可获得性。

简介：Nd:钇铝柘榴石先锋粉末被同类的降水，和Nd综合:钇铝柘榴石透明陶艺被真空sintering为5h在1700°C作好准备。陶器的材料被轻发射度和地排放枪环境扫描显微镜描绘。用统计和立方米科学理论，学习在在轻发射度和立体声之间的量的关系上被执行在三维的欧几里德几何学的空格的逻辑参数。这被发现Nd的发射度:有在厚度的1公里的钇铝柘榴石分别地在可见、在红外线附近的波长是大约45%和58%。发射度线性地与增加相等的范围直径增加并且当相等的范围直径是20μm时，到达单个水晶的理论价值。有每统一谷物和分离谷物的体积增加吝啬的特定的区域的发射度减少，和有增加的发射度减少在Nd意味着谷物的免费距离:钇铝柘榴石陶艺。

简介：Ａｐｐｌｉｃａｔｉｏｎｏｆ２４１ＡｍＥＤＸＲＦｔｏＤｅｔｅｒｍｉｎｅＨｅａｖｙＲａｒｅＥａｒｔｈｓｉｎＲＥＳｅｐａｒａｔｉｏｎＰｒｏｃｅｓｅｓｂｙＳｏｌｖｅｎｔＥｘｔｒａｃｔｉｏｎＪｉａＪｉａｎｇｔａｏ（贾江涛），ＭａＸｉａｏｔａｏ（马小桃），Ｙａ...

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简介：AnovelTb（III）ternarycomplexTb（p-BBA）_3MAAwassynthesizedwith4-benzoylbenzoicacid（p-BBA）andmethacrylicacid（MAA）asligands.ThecomplexwascharacterizedbyIR,UV-visible,thermogravimetricanalysisandfluorescencespectroscopy.Monitoredat544nm,thecomplexdisplayedwideandstrongexcitationbandat300–400nm,whichmatchedwellwiththe365nm-emittingUVchip.Thecomplexexhibitedexcellentgreenemissionat544nm（~5D_4→~7F_5transitionofTb~（3＋））underanexcitationat365nm.Besides,thecomplexshowedhighthermalstability.Itsintramolecularenergytransferprocesswasfurtherdiscussed.Furthermore,thecomplexalsohadhigherfluorescencelifetime（1.38ms）andhigherquantumyield（0.372）.Finally,electroluminescentpropertiesindicatedthatwhenusedtofabricateLEDwith365nmUVchip（powerefficiencyis18.6lm/W）,thecomplexremaineditsfavorableopticalperformance.TheseresultsimpliedthatTb（p-BBA）_3MAAcouldbeusedasagreenphosphorforNUV-basedwhiteLED.

简介：AseriesofCeB6-dopedandCeO2-dopedCa1-xSiAlN3:xCe3+（denotedasCASN:Ce3+@CeB6andCASN:Ce3+@CeO2,respectively）weresynthesizedbyalloy-nitridationmethodunderhigh-puritynitrogenatmosphere.Themorphologies,crystalphases,andluminescencepropertieswereinvestigatedindetail.WithanincreaseintheconcentrationofCeB6,theunitcellvolumeofCASN:Ce3+@CeB6slightlyincreasesduetothesubstitutionbetweenions,whichleadstoachangeofmicrostructurearoundCe3+.CASN:Ce3+@CeB6efficientlyemitsyellow-orangelightwithamaximumemissionintensityataround550nmforthecontentxof0.01（beingincomparablesituation,CASN:Ce3+@CeO2isx=0.04）whenexcitedat460nm.ComparedwithCASN:Ce3+@CeO2,theredemissioncomponentofCe3+inCASN:Ce3+@CeB6ismuchstronger.Thisisascribedtoenergytransferofintra-Ce3+（withinoneCe3+ion）andinter-Ce3+（betweenCe3+andCe3+ions）.Inaddition,thereplacementsofN3-（0.132nmforCN=4）andO2-（0.124nmforCN=4）byB2-（0.140nmforCN=4）,whichcanleadtoamarkedexpansionofthehostlatticeandadecreaseoftheoxidationofsamples,arealsoresponsiblefortheincreaseofredemissioncomponent.Furthermore,CASN:Ce3+@CeB6phosphorhasanexcellentthermalstabilitybecauseofthepartialsubstitutionofCe-O（Ce-N）bondsbymorecovalentCe-B.Asaresult,theoutstandingluminescentpropertiesofCASN:Ce3+@CeB6phosphormakeitpracticaltouseinthesinglephosphor-coatedhigh-color-renderingpowerwhiteLED.

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