简介:ThispaperreviewsthehistoryofdevelopmentandproductionofsilicabricksatLuoyangRefrac-tories(Group)Co.,Ltd,(FormerLuoyangRefrac-toriesFactory).Throughtheimprovementandin-troducingtechnologyfromabroadthecompany'smanagementandqualitystandardonsilicabricksproductionhasreachedahigherlevel.Thephysicalandchemicalspecifications,aswellastheappear-anceofsilicabricksforcokeovens,hotblaststovesandglasskilnshavereachedtheadvancedinterna-tionallevel.NowthecompanyhasbecomeproducingbaseandmainexportingbasevariouskindsofsilicabricksinChina.
简介:以邻苯二甲酸酐和乙二胺为原料,水为介质,先制得N,N’-乙撑双邻苯二甲酰亚胺;然后经溴代及老化处理合成白色阻燃剂N,N’-乙撑双四溴邻苯二甲酰亚胺。此新方法不采用任何有机溶剂和有机助剂,成本低,污染小,产品纯度高,外观洁白,全程总收率大于80%
简介:ThemagnesiabasedcurablespecimenswithdifferentSi3N4contentswerecastedusingsinteredmagnesite(w(MgO)=95%)asstartingmaterial,SiO2micro-powderasbinder,0.3%,4%and5%β-Si3N4powderreplacingtheequaladditionofmagnesiapowderrespectively.Theslagresistancetestwascarriedoutat1550℃for3husingBaosteeltundishslagandstaticcruciblemethod.Theresultindicatesthat:introducingSi3N4couldobviouslyimprovetheslagresistanceofMgObasedcastable,whichincreasedwithincreasingSi3N4.DenseSiO2sinteredlayerformedonthesurfaceofmagnesiabasedcastablebecauseoftheoxidationofSi3N4addition,whichcanpreventthefurtherslagpenetration.Inthedeepinnerofcastable,thepartial-pressureofoxygenwasverylow,soSi3N4canexiststably.Meanwhileinreducingatmosphere,Si3N4washardtobesintered,whichresultedinthelooseinteriorstructureofMgObasedcastable.
简介:ForChina'srefractoriesindustry,thefirsttwodecadesinthenewcenturywouldbeaperiodofstructuraloptimizationwithreorganizationofrefractoriesenterprises,reconstructionofmanufacturingplantsandrestructuringofproductvarieties.Animportantstrategicmeasureshouldbetodevelophighqualitysyntheticrawmaterialsandhighperformancefunctionalproductsmainlybasedonourrichnaturalresourcestocopewithnewdemandsofadvancedhightemperaturetechnologies.
简介:Anewsandwichtesthasbeendevelopedtomeasuretheadherenceofcementclinkeronbasicrefractoriestotesttheircoatability,Statisticaldesingsofexperimentmethod-ologywereemployedforevaluationsofthesandwichtest.Threefractionalfactorialtestsandonefullfactorialtestwereexecutedtoefficientlygeneratedatathatrevealthesignificanceofthemajorfactorsandtheruggednesstotheminorfactors.Itsrepeatabilityandreproducibilityhavebeenstatisticallyconfirmedtobeacceptable,Evaluationsonvariousbasicbricksbythesandwichtestreflecttheircoatingperformanceinrotarykiln.
简介:Si3N4powderandhot-pressedSi3N4ceramicsaddedwithAl2O3areusedforinvestigatetheiroxidationbehviorinairandnitrogenatmosphere(withoxygenpartialpressurePO2=1-10Pa),TheoxidationproductsofSi3N4areexaminedbychemicalanalysi,X-raydiffraction(XRD)andXPSmethod,Also,thermodynamiccalculationismadetoanalyzeoxidationbehaviorofSi3N4.TheresultsshowthatonlypassiveoxidationwilloccurwhenSi3N4isoxidizedinairathightemperature,whereasinN2athightemperature,theactiveoxidationisdominantinspiteoftheexistenceofalittlepassiveoxidation.
简介:ThemechanicalpropertiesofpressurelesssinteringFe-Si3N4bondedSiCandSi3N4bondedSiCwithsamemanufactureprocesshavebeencomparedinthispaper.TheoxidizingmechanismofFe-Si3N4bondedSiCceramicmatrixcompositehasbeeninvestigatedespeciallythroughTG-DSC(thermogravimetricanalysis-differentialscanningcalorimeter)experiment.DuringoxidationprocedurethemainreactionistheoxidationofSiCandSi3N4,SiO2whichformprotectingfilmtopreventfurtheroxidizing.AndresidualironinthesamplesbecomeFe2O3andFe3O4,theoxidationkineticsat1100~1300℃ofre-Si3N4bondedSiChasbeenstudiedespecially.Theweightgainperunitareaatinitialstagechangesaccordingtobeelinerule,inthemiddleaccordingtoconic,andinthelastoxidationperiodfollowsparabolarule.