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500 个结果
  • 简介:Atopologymethodispresentedinthispapertorevealflowtructureoccurringinsieturbomachinery,inwhichnearwallflowstructureisrevealedbyusingwalllimitingstreamilinesandspaceflowfeatureisrevealedbyusingspacestreamilinesandcross-sectionstreamlines,Asanexample,acomputationalthree-dimensionalviscousflowfieldinsideatransonicturbinecascadeisstudied.Throughtheanalysis,theformandevolutionofvortexsystemandthewholeprocessofseparationoccurringwithinthiscascadearerevealed.Theapplicationoftopologymethodforanalyzeflowstructureinsideturbomachinmeryisveryimportantforunderstandingflowfeaturesandmechanismofflowlossevenforimprovingthedesignofturbomachineryandincreasingitsefficiency.

  • 标签: 超声速透平机 粘滞流体 拓扑结构
  • 简介:Thebilayerorganiclight-emittingdiode(OLED)withabluefluorescentlanthanumcomplex,tris(1-phenyl-3-methyl-4-isobutyryl-5-pyrazolone)-(2,2′-dipyridyl)lanthanum[La(PMIP)3(Bipy)],asalightemittingmaterialandN,N′-diphenyl-N,N′-bis(3-methylphenyl)-1,1′-biphenyl-4,4′-diamine(TPD)asaholetransportingmaterialemitsbrightgreenlightinsteadofbluelight.Thedataoftheabsorption,thephotoluminescence(PL)andthephotoluminescenceexcitation(PLE)spectraofTPD,La(PMIP)3(Bipy)andthemixtureofTPDandLa(PMIP)3(Bipy)(molarratio1∶1)provethattheelectroluminescentemissionoriginatesfromtheexciplexontheinterfacebetweenTPDandLa(PMIP)3(Bipy).Byimprovingdeviceconfigurationwithtris(8-hydroxyquinoline)aluminum(ALQ)asanelectrontransportingmaterial,amaximumluminanceof800cd/m2wasobtained.

  • 标签: 电致发光 光致发光 镧配合物 双分子层有机发光二极管 1-苯基-3-甲基-4-异丁酰-5-吡唑啉酮)- (2 2'-二吡啶基)
  • 简介:这份报纸被奉献给考虑三维粘滞大规模空气的原始方程。首先,我们比那与更弱的起始的数据为原始方程证明全球well-posedness在[11]。第二,我们获得方程的光滑的答案的存在。而且,我们为大规模空气的原始方程产生的动态系统在V获得紧缩的全球引起注意的人,它改进结果[11]。

  • 标签: 原始方程 三维粘性 大气 原始数据 动力系统 全局吸引
  • 简介:Lens-likevateriteCaCO3microringscomposedofCaCO3nanoparticlesweresynthesizedviaamicro-emulsion-mediatedrouteatroomtemperaturewithethanolandn-hexanolasco-surfactant.Thisprocessdidnotde-mandanyadditionalenergysuchasheatingorcontinuousagitation.Itwasthefirsttimetouseethanolasco-surfactantinthesynthesisofmicroornanomaterials.AndtheethanolwasbelievedtoplayanimportantroleintheaggregationfashionofCaCO3nanoparticles.Moreover,shuttle-shapednanorods,hexagonalnanoplates,andrice-likenanoparticleswerealsofabricatedbymodulatingthegrowthparameters.Additionally,theintroduceofethanolintomicroemulsionsasco-surfactantmaybegeneralizedasanovelgreenroutetocontrolthestructureofotherfunctionalmaterials.

  • 标签: 纳米碳酸钙 微乳液 合成 纳米晶 表面活性剂 可控
  • 简介:讨论一种合理的绿色机房模型,求出了在不同的任务量、分配方式、空调风速和空调温度下机房的平均温度、热点、以及热分布和气流速度分布图。分别用人工神经网络和模拟仿真软件Airpak软件建立模型分析空调的热分布。通过在Airpak中更改机柜发热功率、空调的送风温度、送风速度来模拟仿真不同情况下机房的热循环过程。最后进行改进和优化,使其能够适应更多情况和条件。

  • 标签: 绿色机房 热分布 流场分布 插值 AIRPAK 有限体积法
  • 简介:Inthisletter,Fe2O3UFP(UltrafineParticles)hydrosolandorganosolwithhighthirdorderopticalnonlinearsusceptibility(3)havebeenreportedforthefirsttime.ThesurfacialmodificationofFe2O3UFPwithdodecylbenzenesulfonateions(DBS)canenhancethenonlinearopticalresponsethroughinterfacialconfinementofelectronmotion.Theinvolvedmechanismisdiscussed.

  • 标签: CONFINEMENT INTERFACIAL SUSCEPTIBILITY ULTRAFINE hinder coated
  • 简介:本文探讨(CH3Li)4中键的作用,通过计算,发现(CH3Li)4分子的面甲基结构比顶甲基结构要稳定;指出Li—Li间的成键作用相当强,约为Li2分子中键作用的40%左右,估计(CH3Li)4中的J7Li-6Li值约为1Hz。

  • 标签: 中键探讨
  • 简介:Arabidopsisthalianaisacommonresearchplantofmolecularandcellbiologicalresearchwhichhasshortlifecycleandhugeamountofseeds[1].Gammarayisoneoftheimportantphysicalmutagenswhichiswidelyusedinplantgeneticsandbreedingresearch[2].Thepurposeofthisstudyistoinvestigatethedose-effectofrayradiationsontherootdevelopmentofArabidopsis.Dryseedswereirradiatedbyrayswiththedoserangefrom100to1600Gy.

  • 标签: EFFECT IRRADIATION GROWTH
  • 简介:MalignanttumorsorcancershavebecomeoneofthemostfrequentcausesofdeathinChina;cancertherapiesareattractingmuchattention.Becauseofthenoninvasivenatureofradiationtherapy,lesserphysiologicalandpsychologicalburdenisplacedonpatientsthancomparedtothatresultingfromsurgicalorpharmaceuticaltreatments.Hadrontherapy(heavyiontherapyandprotontherapy)isconsideredsuperiorapproachforthetreatmentoftumorslocatedinhighlysensitivetissues(brain,neck,eyes),pediatriccancers,andalsotumorsthatareresistanttoradiotherapy.

  • 标签: NANOPARTICLES HADRON THERAPY
  • 简介:6/3-(4-Chlorophenyl)-s-triazolo[3,4-b][1,3,4]thiadiazoles(2a-e)and(5a-e)weresynthesizedrespectivelybyintermolecularcyclizationof5-aryl/4-chlorophenyl-4-amino-3-mercapto-1,2,4-triazoles(1a-e)and(4)with4-chlorobenzoicacid/arylacids,whichwerecondensedwithpiperazineunderphasetransfercatalystTBABtoyieldthecorrespondingfreebasesofmonopiperazinederivativesandfollowedtoformwater-solublesalts(3a-e)and(6a-e)withhydrochloricacidingoodyields.Theinvitrobiologicalresultsshowedthatpiperazinegroupconjugatedwiththeabovefusedheterocyclesplayedanimportantroleinantibacterialactivity.ThestructuresofnovelcompoundswereconfirmedbyIR,1HNMR,MSandelementalanalysis.

  • 标签: 哌嗪 相转移 可溶性 抗菌活性 催化合成 药物
  • 简介:Novelsulfur-containingcompounds(3a–3c,4a–4c)wereobtainedinethanolwith1,3-diphenyl-2-propanoneasthestartingmaterial.Theadvantagesofthisprocedureweremildreactionconditions,simpleprotocol,andhighyields.ThestructuresoftheproductswerecharacterizedbyIR,1HNMR,MSandelementaryanalysis.Thecrystalofthenewcompound4abelongstomonoclinic,spacegroupC2witha=18.727(3),b=6.5179(9),c=13.7576(18),b=131.0610(10)°,V=1266.2(3)A3,Z=2,Dc=2.136g/cm3,μ=1.078mm-1,F(000)=843,R=0.0490andwR=0.1247for3211observedreflectionwithI>2δ(I).X-rayanalysisrevealsthatthemoleculeisnotsymmetrical,themolecularstructureisstabilizedbyweakp–pstackinginteractions,andnoclassicalhydrogenbondscanbeobserved.

  • 标签: 硫醇 苄基 显示 合成 寺院 结构稳定
  • 简介:Thesynthesisof(S)-2-(3-arylacrylamido)-3-{4-[2-(5-methyl-2-phenyloxazol-4-yl)ethoxy]phenyl}propanoicacidsisdescribed.TheirstructureswereconfirmedbyH-NMR.

  • 标签: 丙酸 合成方法 分子结构 核磁共振
  • 简介:用微波高温固相法合成了Er^3+单掺Lu2O3,Li^+与Er^3+共掺Lu2O3及Li^+,Zn^2+,Mg^2+掺杂Lu2O3∶Er^3+的荧光粉。实验表明金属离子Li^+、Zn^2+、Mg^2+、Er^3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li^+掺杂可以有效改善粉体的分散性和形貌,Li^+,Zn^2+,Mg^2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100nm。379nm激发下,Li^+与Er^3+共掺样品发光较单掺Er^3+样品在565nm处的发光增强了4.5倍,而Li^+、Zn^2+、Mg^2+与Er^3+共掺样品较其发光增强5.3倍。980nm激发下,Li^+与Er^3+共掺样品,Li^+、Zn^2+、Mg^2+与Er^3+共掺样品的发光分别比单掺Er^3+样品在565nm处发光增强23倍与39倍,在662nm处发光强度分别增强20倍与43倍。379nm激发下,较单掺Er3+的样品,掺杂Li^+的样品和Li^+,Zn^2+,Mg^2+和Er^3+共掺的样品荧光寿命均有所增加,而Zn^2+、Er^3+共掺及Mg^2+、Er^3+共掺样品的荧光寿命则有所缩短。

  • 标签: 微波高温固相法 Li^+ Zn^2+ Mg^2+掺杂Lu2O3∶Er^3+荧光粉 发光强度 上转换发光 荧光寿命
  • 简介:The2-C,methylenegroupof1-aroyl-1,2-dihydro-3H-naphtho[2,1-b]pyran-3-ones(2)havebeenshowedtopossessasuperiorreactivitytowardsmanyoforganicreagents.Thena-phthopyrones(2)condensedwitharomaticaldehydestogivethe2-arylidinederivatives(3).Bromin-ationof2gave1,2-dibromo(4)or5-bromo(5)derivativesdependingonthereactionconditions.Thebasecatalyzedadditionorcycloadditionofnaphthopyrones(2)to4-methoxybenzalacetophenonegavetheexpectedMichaeladduct(6)orthecyclicadducts(7-9)dependingonthetypeofcatalyticbaseandreactionconditions.Structuresoftheproductshavebeenestablishedbyelementalanalyses,IRand~1HNMRspectroscopicmethods.

  • 标签: PYRAN REACTIVITY aldehydes aromatic bromo catalyzed