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80 个结果
  • 简介:ThemethanolicextractfromaChineseendemicChrysanthemumplant,Dendranthemaindicumvar.aromaticum,wasfoundtoshowhighantifeedingactivityagainstPierisbrassicaeL.,andbybioassay-guidedseparation,theactivecomponent,B-ring-homo-tonghaosu,2-(2',4'-hexadiynylidene)-1,6-dioxaspiro-[4,5]-dec-3-ene(2)wasisolated.Itsstructurewaselucidatedbycomparingitsspectroscopicdatawiththoseof2reportedintheliteratures.FurthermorenewconvenienttotalsynthesismethodsofB-ring-homo-tonghaosuwerealsodevelopedtoconfirmitsstructureandmakeitsfurtherapplicationincropprotectionavailable.Inaddition,extensivecomparisonofspectroscopicdatashowedthatthestructureofcompound21reportedinliteratureshouldberevisedto2.

  • 标签: 离析 结构 合成 拒食素
  • 简介:在这份报纸,我们在公制的Lp(R)(1p)得到平均-B宽度和Sobolev班Brp(R)的无限的维的-G宽度的准确价值并且获得准确(N)和强壮的asymptotic(>1)在公制的Lq的Sobolev牛肉熏香肠班Wrpq(R)的无限的维的-G宽度的结果在公制的Lqp(R)(1qp)的(R)和它的双盒子Wrp(R)。

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  • 简介:极其细小磨擦非结晶的合金催化剂被化学减小与KBH4准备。在在气压的cinnamaldehyde的液体阶段加氢期间,Ru-B催化剂准备了展出优秀选择到cinnamyl酒精。当加氢与超声的照耀被执行时,当到cinnamyl酒精的选择仍然保持几乎未改变时,反应率能极大地被提高。加氢率随超声的频率或照耀时间的增加被增加。根据各种各样的描述,例如XRD,XPS,TEM,赌注和ICP,结构、电子的特征上的超声的照耀的效果磨擦催化剂简短被学习。同时,催化表演上的ultrasonication的提升效果也基于cinnamaldehyde的选择加氢被讨论到cinnamyl酒精。

  • 标签: 钌-硼无定形合金 催化剂 超声照射 肉桂醛 肉桂醇 催化加氢
  • 简介:ThispaperreportsastudyofcomplexfocussingacousticfieldsofaconvexphasedarrayprobewidelyusedinultrasonicdiagnosticB-scanner.Thetimedelaynecessaryforelectronicfocussingandforgeometricfocussingofcomplexfocussingisgiven.BymeansofHelmholtz‘sintegralformula,theexpressionsofacousticfieldswereobtainedfortheelectronicfocussingandcomplexfocussing.Withsimpson‘snumericalintegral,agreatdealofcomputationswascarriedoutwithan86/330computer.Bymeansofusingdifferentparameters,anoptimumfocalrangeandbeamwidthofa4sequenceselectronicandcomplexfocussingacousticsystemwasselected.WithanEUB-40ultrasounddiagnosticB-scannerproducedbytheHitachicompany,thelateralfocussingacousticfieldandlateralresolutioninanechoictankwerephotographedbylatticingmethodandtheexperimentalresultiscon-sistentwiththetheory.

  • 标签: SCANNER CONVEX ULTRASONIC CONTOUR DIAGNOSTIC phased
  • 简介:Inthispaper,basedontheimplicitRunge-Kutta(IRK)methods,wederiveaclassofparallelschemethatcanbeimplementedontheparallelcomputerswithNs(Nisapositiveevennumber)processorsefficiently,anddiscusstheiterativelyB-convergenceoftheNewtoniterativeprocessforsolvingthealgebraicequationsofthescheme,secondlywepresentastrategyprovidinginitialvaluesparallellyfortheiterativeprocess.Finally,somenumericalresultsshowthatourparallelschemeishigherefficientasNisnotsolarge.

  • 标签: IMPLICIT Range-Kutta methods NEWTON ITERATIVE process
  • 简介:Anewapproachtodeterminealltheelectro-elasticconstantsofthepiezoelectriccrystalsinclass4mmhasbeenputforward.Asanexample,alltheconstantsofLithiumTetraborate(Li2B4O7)crystalhavebeenmeasuredbymeansoftheapproach.Theoutstandingadvantageoftheapproachisthatiton-lyneedstoemployinmeasurementthreecrystalplatesdifferentlyoriented.

  • 标签: CONSTANTS lithium PIEZOELECTRIC outstanding INFINITE RESONANT
  • 简介:HeteroatomM-ZSM-12zeolites(M=B,Al,Ge,Ga,Fe)arehydrothermallysynthesizedanditisprovedthattheheteroatomMisinvolvedintheframeworkofsynthesizedmolecularsievesbymeansofXRD,IRspectra.TheresultsofadsorptionanddiffusionexperimentsindicatethattheheteroatomMmodifiestheporevolume,specificsurfacearea,andthechannelofZSM-12molecularsieves.

  • 标签: HETEROATOM Zeolites ADSORPTION
  • 简介:运用转移矩阵的技巧,本文给出了戴帽B27N27硼-氮zlgzag纳米管的克库勒结构数的计算公式.在实际计算中,根据管的对称性,转移矩阵的阶得到了显著地降低.

  • 标签: 戴帽B27N27硼-氮zigzag纳米管 克库勒数
  • 简介:关于递推数列Xn+1=(axn+)/(cxn+d)的极限的注记田文平(南京审计学院)关于递推数列Z.+l一;;=:一的极限.文D」给出了下面两个结论:”—”——“”””“”-x+d”“”’””““-“”“““’””“’—””“”结论1设数列?..

  • 标签: 递推数列 极限 充分必要条件 通项公式 线性递归方程 共轭复根
  • 简介:Thetitlecomplexi-C4H9Co(salen)(Py)(Py=pyridine.salen=dianionofdisalicylideneethylenediamine)hasbeenfirstsynthesized.ItscrystalstructurehasbeendeterminedbyX-raydiffractionmethod.ThecrystsisaremonoclinicwithspacegroupP21/C.Theunitcellparametesarepresented.ThestructurehasbeenrefinedtoafinalRof0.038.

  • 标签: refined PYRIDINE MONOCLINIC compl alkyl DALTON
  • 简介:6/3-(4-Chlorophenyl)-s-triazolo[3,4-b][1,3,4]thiadiazoles(2a-e)and(5a-e)weresynthesizedrespectivelybyintermolecularcyclizationof5-aryl/4-chlorophenyl-4-amino-3-mercapto-1,2,4-triazoles(1a-e)and(4)with4-chlorobenzoicacid/arylacids,whichwerecondensedwithpiperazineunderphasetransfercatalystTBABtoyieldthecorrespondingfreebasesofmonopiperazinederivativesandfollowedtoformwater-solublesalts(3a-e)and(6a-e)withhydrochloricacidingoodyields.Theinvitrobiologicalresultsshowedthatpiperazinegroupconjugatedwiththeabovefusedheterocyclesplayedanimportantroleinantibacterialactivity.ThestructuresofnovelcompoundswereconfirmedbyIR,1HNMR,MSandelementalanalysis.

  • 标签: 哌嗪 相转移 可溶性 抗菌活性 催化合成 药物
  • 简介:The2-C,methylenegroupof1-aroyl-1,2-dihydro-3H-naphtho[2,1-b]pyran-3-ones(2)havebeenshowedtopossessasuperiorreactivitytowardsmanyoforganicreagents.Thena-phthopyrones(2)condensedwitharomaticaldehydestogivethe2-arylidinederivatives(3).Bromin-ationof2gave1,2-dibromo(4)or5-bromo(5)derivativesdependingonthereactionconditions.Thebasecatalyzedadditionorcycloadditionofnaphthopyrones(2)to4-methoxybenzalacetophenonegavetheexpectedMichaeladduct(6)orthecyclicadducts(7-9)dependingonthetypeofcatalyticbaseandreactionconditions.Structuresoftheproductshavebeenestablishedbyelementalanalyses,IRand~1HNMRspectroscopicmethods.

  • 标签: PYRAN REACTIVITY aldehydes aromatic bromo catalyzed
  • 简介:3-(2-Hydroxyphenyl)-6-(4-nitrophenyl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine,C16H11N5O3S,waspreparedbythecyclizationof3-(2-hydroxyphenyl)-4-amino-5-mercapto-1,2,4-triazolewith2-bromo-4-nitroacetophenone.Thecompoundwascharacterizedbymeansofelementalanalysis,IR,1HNMR,13CNMR,massspectrometry,andX-raydiffraction.ThecompoundcrystallizesinamonoclinicsystemwithspacegroupCc,a=2.1853(4)nm,b=2.1192(5)nm,c=1.3526(3)nm,β=95.21(2)°,V=6.238(2)nm3,Dcalcd.=1.505Mg/m3,Z=16,F(000)=2916,R1=0.0501,wR2=0.0427.Acomparisonbetweenthecrystalstructuresof1,2,4-triazolo[3,4-b][1,3,4]thiadiazineand1,2,4-triazolo[3,4-b][1,3,4]thiadiazolewasmadeinthestructuralview.Atwo-dimensionalnetworkisformedbyhydrogenbondsandπ-πstackinginteractions.

  • 标签: 晶体结构 [1 3 4]噻二嗪 制备 光谱表征 Π-Π相互作用
  • 简介:8,8′-Dibromo-6,6′,7,7′-tetramethoxy-5,5′-diisopropyl-3,3′-oxydimethylenedinaphtho[2,1-b:2′,1′-d]furan,C32H30Br2O;M.W.=670;triclinic;spacegroupP1;a=8.896(2),b=10.216(1),c=10.423(1)A,α=108.48(1),β=119.36(1),γ=99.26(1);V=723.5A3;Z=1,Dcal.=1.479g.cm-3.MoKα=28.11cm-1,F(000)=326,T=293K.Thestructurewassolvedbydirectmethodandfull-matrixleast-squaresrefinementconvergedatR=0.034for2377observedreflections.Theoxygenatominseven-memberedringexistsinadisorderedarrangement.Bothbisnaphthaleneandoxygen-containingfive-memberedringhaveplanarconformationswithdihedralangle6°,showingmarkedaromaticfeature.

  • 标签: FURAN derivative dibromo-6 6 TRICLINIC membered planar
  • 简介:Halfsandwichirondicarbonylcomplex[η5-C5H3(t-Bu)2]Fe(CO)2Cl(1)reactswith1,2-dilithiumdiselenocarboraneLi2Se2C2B10H10(2)togiveabinuclearironcarboranecomplex[η5-C5H3(t-Bu)2]2Fe2(CO)3*Se2C2B10H10(3).TheX-raydiffractionanalysisofcomplex3revealsthatoneoftheironatomsischiral.

  • 标签: Carborane Halfsandwich IRON complex Chirality Molecular