简介：(丙烯酸的酸)Chitosan-poly，hydrogel与Eu3+结合了被激进的溶液聚合准备。可被细菌破坏的chitosan，N，N-methylen-diacrylamide，和钾过硫酸盐分别地被用作基本材料，cross-linking代理人，和开始者。结构和hydrogel的热性质被红外线的spectrometry，X光检查衍射，扫描电子显微镜学，和微分扫描热量测定描绘。肿的性质并且荧光灯性能也被描绘。结果证明稀土元素在聚合以后由于化学契约的形成在hydrogel介绍了唯一的分发。hydrogel的玻璃转变温度显著地减少了，它可能更加拓宽它的有弹性的申请的范围。而且，特征荧光灯Eu3+的排放在hydrogel被观察，它优秀光表演是指示的。

简介：ThecopolymerswereformedbythegraftcopolymerizationofPVCwithacrylicrareearth.TheprincipleandmethodofthegraftcopolymerizationofPVCandacrylicrareearthwerediscussed.ThegraftcopolymerswerecharacterizedbyFT-IRspectraandscanningelectronmicroscope(SEM).Thethermalstabilityofthegraft-copolymerswasstudiedbythermogravimetricanalysis(TG).Theexperimentresultsshowthatthethermalresistanceandtoughnessofthegraftcopolymersareobviouslyenhanced.

简介：Anewmethodofpreparationofirradiativematerialbyusingrareearthasluminophorandinorganicpowderasbasenucleuswaspresented.Rareearthwasusedtomakecolloid,whichwasmixedwithbasenucleussolution,wheredeposition/attachmentreactiontookplaceandrareearthwasadheredontothesurfaceofbasenucleus,henceyieldinganewrareearthencapsulatedirradiativematerial.Fluorescentspectrumanalysisshowsthatthismaterialpossessestwoemissionpeaks,onewithin400～500nmandtheotherwithin580～700nm,reflectingtheluminouscharacteristicsoforiginalrareearthmaterial.

简介：ＡｐｐｌｉｃａｔｉｏｎｏｆＲａｒｅＥａｒｔｈｓｉｎＯｉｌＣｏｕｎｔｒｙＴｕｂｕｌａｒＧｏｏｄｓＬｉｎＱｉｎ（林勤），ＹａｏＴｉｎｇｊｉｅ（姚庭杰），ＬｉｕＡｉｓｈｅｎｇ（刘爱生）ＣｈｅｎＮｉｎｇ（陈宁），ＹｅＷｅｎ（叶文），ＹｕＺｏｎｇｓｅｎ（余宗森...

简介：Agriculturalapplicationofrareearth(RE)hasbeengeneralizedforseveraldecades,anditisinvolvedincrops,vegetablesandstockraisinginChina.However,alltheresearchesonREmainlyfocusonthefieldssuchasplantphysiologicalactivity,physiologicalandbiochemicalmechanism,sanitationtoxicologyandenvironmentalsecurity.PlantprotectionbyusingREandtheinducedresistanceofplantagainstdiseasesweresummarized.Themechanismofrareearthagainstplantdiseaseishighlighted,whichincludesfollowingtwoaspects.First,REelementscancontrolsomephytopathogendirectlyandreduceitsvirulencetohostplant.AnotherpossibilityisthatREelementscanaffecthostplantandinducetheplanttoproducesomeresistancetodisease.

简介：稀土元素金属(雷姆)是在高技术，发电，通讯，和防卫工业有普遍、唯一的应用的一系列17个元素。这些资源对突现的持续精力和碳选择技术也枢轴。雷姆的恢复由于它与各种各样的工业应用一起的高市场价格有趣。常规技术，viz。降水，过滤，液体液体抽取，稳固液体的抽取，离子交换，超级批评抽取，电迷，电精制，精制的electroslag，等等，为雷姆的恢复被开发了，不是经济地吸引人的。Biosorption从水的答案为稀土元素金属的恢复代表biotechnological革新以及一个合算的优秀工具。许多biomaterials象水藻那样，真菌，细菌，树脂，激活的碳，等等，被报导了为雷姆的恢复用作潜在的吸附物。影响稀土元素金属并且等温线建模的举起的金属绑定机制，以及参数这里被介绍。这篇文章提供过去的成就和用答应biosorbents能为恢复雷姆用作一个节俭的工具的一些执行的biosorption研究的当前的情形的概述。不同工人报导的试验性的调查结果将提供卓见进这研究边疆。

简介：Basedontheinvestigationoftheluminescenceofaseriesofrareearthorganicchelates,somerelationshipsbetweenluminescenceandthestructureofthechelateswereproposed:theintensityofsensitizedluminescenceofcentrallanthanideions(Ln3+)inarareearthorganicchelatedependson(1)thesuitabilityoftheenergygapbetweentheexcitedtripletenergyleveloftheligandsandthelowestexcitedenergylevelofLn3+ions;(2)therigidityandplanarityofthestructureofthechelatemolecule;(3)theexistenceofasuitablesecondaryligandwhichmayincreaserigidityandthestabilityofthechelatemolecule;and(4)theexistenceofasuitableπ-conjugatedsysteminthechelatemolecule.Accordingtotheaboverelationships,25novelorganicligandsweredesignedandsynthesized,andtheirlanthanidechelateswereprepared.Investigationofthephotoluminescenceforthenewchelatesshowsthatsomeofthechelatesarestronglyluminescent,andareappliedtofluoroimmunoassayfordeterminationofhumanimmunoglobulin(IgG),topreparationoffluorescentplastics,andtodeterminationofgrowthhormoneforplants.Twonovelspectroscopy-probetechniquesforstructureofcoordinationcompoundsandbiologicalmoleculeswereproposedanddevelopedbasedonvibronicspectroscopyofTb3+complexesandfluorescenceofCe3+.

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简介：Theneedformoreactiveandhydrothermallystablefluidcatalyticcracking(FCC)catalyststocombattheeffectofmetalcontaminantshasledtoanincreaseindemandforrareearthoxides.RareearthoxidesenhancecatalystactivityandpreventthelossofacidsitesduringtheFCCunitoperation,especiallywhenheavyresiduewithhighmetalcontentisusedasfeed.Inthispaper,areviewwascarriedouttoshowtheeffectsofrareearthelementsonthestructure,activity,andstabilityofFCCcatalysts.Also,theuseofrareearthelementsasvanadiumtrapswasanalyzedinconjunctionwiththemechanismofcatalystdeactivationbyvanadium.TheobjectivewastoelucidatetheinteractionofvanadiumspecieswiththezeolitecomponentoftheFCCcatalystsandtheroleofrareearthelementsincounteringthedeleteriouseffectsofvanadiumontheFCCcatalysts.

简介：ＧｅｏｃｈｅｍｉｃａｌＢｅｈａｖｉｏｕｒｏｆＲａｒｅＥａｒｔｈＥｌｅｍｅｎｔｓｉｎｔｈｅＥｒｄａｏｇｏｕＧｏｌｄＤｅｐｏｓｉｔＰａｎｇＪｉａｎｇｌｉ（庞奖励）（ＤｅｐａｒｔｍｅｎｔｏｆＧｅｏｇｒａｐｈｙ，ＳｈａｎｘｉＮｏｒｍａｌＵｎｉｖｅｒｓｉｔｙ，...

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简介：ＭｏｄｉｆｙｉｎｇＥｆｅｃｔｏｆＲａｒｅＥａｒｔｈｓａｎｄＴｉｔａｎｉｕｍｏｎＡｕｓｔｅｎｉｔｉｃＭａｎｇａｎｅｓｅＳｔｅｌＺｈｕＲｕｉｆｕ（朱瑞富），ＬüＹｕｐｅｎｇ（吕宇鹏），ＬｉＳｈｉｔｏｎｇ（李士同）ＣｈａｏＺｈｉｑｉａｎｇ（朝志强），Ｗａ...

简介：Themainlycharacteristicoftrappingmaterialsisthetrapdepth.Soitissignificanttocalculatethetrapdepthforthetrappingmaterials.Anewmethodofcalculatingtrapdepth,whichisbasedonenergybandandusingrateequationstoanalyzethermoluminescence,wasbroughtforward.Thismethodwhichusestherateequationsoftheprocessandthethermoluminescencecurvecanreplacetraditionalmethodssuchasfirstorderorsecondorderkinetics.ThetrapdepthofSrAl2O4:Eu2+,Dy3+andSr4Al14O25:Eu2+,Dy3+wasestimatedfromtheglowcurve.Thenthenumevicalsolutionofthetrapdepthcanbeobtained.Fromtheresultsofexperimentsandcalculations,thismethodcanaccuratelyindicatethewholeprocess.

简介：ThekeratinsofwoolunderwentPhotooxidationtoformaweakerluminophorinvisibleblueregion(λmax=420nm),thatreactswithceriumiontoproduceanenhancedluminophorcomplex(λmax=426nm),itmakeswoolwhiteobviously.

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简介：Rareearthcompoundsasmodifiersusedwidelyinmodernfrictionmaterialscanenhancetheinterfacialbindingofconstituentsofmaterialsandimprovethecomprehensivepropertiesofmaterialsevidently.However,therearestillfewreportsonapplicationofrareearthinautomotivefrictionmaterials.Inordertostudytheeffectmechanismofrareearthsinfrictionmaterials,arareearthcompoundwasselectedasadditiveandtheeffectsofmaterialsdopedwithorwithoutrareearthonfrictionandwearpropertiesofmaterialswerestudied.Themicrostructureandwornsurfacemorphologywereobservedbyscanningelectronmicroscopyandthemacroperformancewasdiscussed.Wornsurfaceelementconstitutionofmaterialswasanalyzedbyenergydispersivespectroscopy.Effectmechanismofrareearthsonfrictionandwearbehaviorsoffrictionmaterialswerediscussed.Theresultsshowthatdopingrareearthsinfrictionmaterialscanstabilizefrictioncoefficient,lowerthewearrateofmaterialsandincreasetheimpactstrengthofmaterials.Theflexibilityandfractureresistanceofmaterialsisgreatlyimproved.Wornsurfaceofmaterialsdopedwithrareearthiscompactandthesurfaceadhesionisgreatlyenhanced.

简介：ＴｈｅｒｍｏｃｈｅｍｉｃａｌＰｒｏｐｅｒｔｉｅｓｏｆＳｏｌｉｄＣｏｍｐｌｅｘｅｓｏｆＲａｒｅＥａｒｔｈＮｉｔｒａｔｅｓｗｉｔｈＭｅｔｈｉｏｎｉｎｅＧａｏＳｈｅｎｇｌｉ（高胜利），ＹａｎｇＸｕｗｕ（杨旭武），ＲｅｎＤｅｈｏｕ（任德厚）ＳｈｉＱｉｚ...

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简介：Anincubationstudywasperformedtoelucidateexogenousrareearthelements(RE)influencingonmicrobialbiomass,microbialecophysiologicalparameterscmic/corg,metabolicquotientqCO2andrespiratoryrateinrelationtotemporalavailabilityinpaddysoil.Sixsampleswereaddeddifferentconcentrationsbetween0and2000mg*kg-1REEsinsoil.ResultsshowthatexogenousREhaveslightstimulativeeffectsonmicrobialindicesinpaddysoilatlowconcentrationintheearlystageafteraddingRE,whilehavinginhibitoryeffectsathighconcentration.TheinhibitionisstrengthenedwithincreasingREconcentrationandisweakenedwithincreasingincubationtime.PrincipalcomponentanalysisoftheBIOLOGdataindicatesthatmicrobialcommunitystructureshavechanged,carbonsourcesconsumptionofmicroorganismsinpaddysoilbecomesmuchmorerapidafter8weeks,andunderREstress,thechangeofmicrobialcommunitystructuresisalong-termeffect.