简介:Thispresentstudyinvestigatedtheabilityofvarioussoyproteinhydrolysates(SPHs)inbindingcalcium.ItwasdemonstratedthattheamountofCa-bounddependedgreatlyontheSPHsobtainedusingdifferentproteases,whichincluded:neutrase,flavourzyme,proteaseMandpepsin.ThemaximumlevelofCa-bound(66.9mg/g)occurredwhenproteaseMwasusedtohydrolyzesoyprotein.PeptidefragmentsexhibitinghighCa-bindingcapacityhadmolecularweightsofeither14.4or8-9kDa.ThelevelofCa-boundincreasedlinearlywiththeincrementofcarboxylcontentinSPHs,andfurtherdeamidationonSPHsfromproteaseMimprovedCa-bindingofthehydrolysate.
简介:Anewmethodforthedeterminationoftracecalciumbysolidsubstrate-roomtemperaturephosphorimetryisestablished.ItisbasedonthefactthatchromeazurolsazurolS-phenanthroline-NaCMC(CAS-phen-NaCMC)systemcanemitstrongandstableroomtemperaturephosphorescence(RTF)onthesolidsubstrateinthefilterpaper.Ca2+andphenanthrolinecanformcomplexionCa(phen)32+,whichwillformcomplex[Ca(phen)3(CAS)2]withCAS.Intheresult,thenumberofCASmoleculesineachspotincreased,causingsharpincreaseoftheRTPsignaloftheCAS-phen-NaCMCsystem.
简介:Theinfluencesofmagnesiumandferricionsintheirdifferentratiosontherateofgypsumcrystallizationwerestudiedundertheconditionssimilartothoseofwetflue-gasdesulfurization(WFGD).TheresultsshowthatadditionofbothMg2+andFe3+increasedinductiontimeanddecreasedthegrowthefficiencyupto50%comparedwiththebaseline(withoutimpurities)dependingontheconcentrationandthetypeofimpurity.TheeffectsofMg2+andFe3+onthesurfaceenergyandtherateofnucleationwereestimatedbyemployingtheclassicalnucleationtheory.Thesurfaceenergydecreasedby8%and14%withtheadditionof0.02mol/Lmagnesiumorferricions,respectively,comparedtothebaseline.Mg2+andFe3+madethegrowthrateofthe(020),(021)and(040)facesofgypsumcrystalamuchgreaterreduction,whichleadstotheformationofneedlecrystalscomparedtothebaselinewhichfavorstheformationofplateorflakes.Furthermore,anedgedetectionprogramwasdevelopedtoquantifytheeffectsofimpuritiesonthefiltrationrateofgypsumproduct.Theresultsshowthattheinhibitionefficiencyofthepresenceof0.02mol/LMg2+andFe3+onthefiltrationrateofgypsumcrystalrangesfrom22%to39%.
简介:SimultaneousBiparametricDeterminationofTotalCalciumandPotassiuminBiologicalFluidsbyFlowInjectionAnalysis──UseofPowell'sMethod...