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简介：TheCW-CO2laserdrivengasreactionwasappliedtopreparenano-sizedSiCpowder,SiH4andC2H4ofhighpurties,asstartingmaterials,weremixedtacertainrationandintroducedintotheresactioncell.Thegasesflewacrossthelaserbeamorthogonallyandthuswereheatedbylaserbeam.Thenano-sizedSiCultrafinepowderwswereformedthroughthermicgasreation.Thefinalproductivityofthisprocesswas97%,Theobtainedpowderswerecharacterizedandanalyzed.ChemicalanalysisrevealedthattheSiCcontentwas95.38wt%,Oxygen,theprimaryimpurity,weighted1.32%whiletraceimpurities,suchascalcium,magnesiumandothermetals,wereonly0.03%,XRD,XPSandTEMindicatedthatthpowderparticleswerenearlysphericalandnotagglomerated.Theparticlesizerangedfrom10nmto25nmwithanaverageof15nm,Theparticlestredtobenoncrystalline.

简介：CurrentlytheservicelifeofCDQshaftsinChinaismainlyrestrictedbythepropertiesoftheinclinedfluebricks.Inthiswork,basedonthesystematicanalysisofthedamagemechanismofinclinedfluerefractories,highperformancemullite-SiCbricksweredeveloped.Thebrickswereproducedbycorundum,andalusite,SiCandotherhighpurityrawmaterials.Metalsiliconandaluminaultramicropowderwereaddedtoformdispersionmulti-phasestructure,fortifyingthematrixandimprovingthemicrostructure.Theproductshaveexcellentpropertiessuchaslowporosity,highdensity,goodwearresistance,highrefractorinessunderload,andgoodthermalshockresistance.Theproductscanreplacetheordinarymullite-SiCbricksandobtainagoodservicelife.

简介：SinteringadditivestogelcastingSialon-SiCweredecidedbytheoptimizingexperiments.TheresultsshowthatSoalon-SiCcanbesinteredunder1450℃andsinteringtemperaturedecreasesby100℃,when2%～3%TiO2orGuangxiclayisusedassinteringadditive.

简介：HightemperatureoxidationbehavioroftwokindsofnitridebondedSiCbasedrefractorieswasinvestigatedat11001500℃bymeansofX-raydiffractometer,scanningelectronicmicroscopyandthermogravimetry.Theresultsshowthat:(1)withthetemperatureincreasing,theoxidationmassincrementrateofthespecimenincreasesfirstandthendecreases,andoxidationpassivationoccurs;(2)theoxidationresistanceofSiAlONbondedSiCrefractoriesissuperiortothatofSi3N4bondedSiCrefractories;(3)hightemperatureoxidationresultsintheincreaseofcompressivestrengthatroomtemperatureofSiCbasedrefractoriescomparedwithspecimenbeforeoxidation;thecompressivestrengthofSiAlONbondedSiCspecimensoxidizedathightemperaturesdecreaseswiththeincreaseofthetemperatureasaresultofformationandburstofsurfacebubble,whilethedecreaseofcompressivestrengthofSi3N4bondedSiCspecimensoxidizedathightemperaturesisowingtotheincreaseoftheconsistencyofnet-likecrackassociatedwithcristobalitetransformationduringcooling.

简介：Lowcement(LC)andultra-lowcement(ULC)bauxite-SiCcastablesareimportantandhighperformancemonolithicrefiactoriesandtheyhavebeenwidelyusediniron-makingandincineratorlinings.Inthiswork,rheo-logicalbehaviorofLCandULCbauxite-basedSiC-contain-ingcastableshasbeenstudied,includingtheeffectsofSiCcontentandcementcontentonrheologicalpropertiesofthecastables.TheresultsshowthatwithanincreaseofSiCandcementcontent,rheologicalpropertiesofthecastablesdeteriorate.Ontheotherhand,moderateamountsofSiC(4%～8%)andofcalciumaluminatecement(2%～4%)haveveryslightinfluenceonrheologicalproperties,(i.e.whenthecastablesareshearedtheirtorqueandyieldtorqueonlyslightlyincreasewiththeshearingspeed).Therheologicalcharacteristicsofthecastablesfol-lowBinghamfiuidandalwaysshowshearthinningbehav-ior.

简介：ThecombinationofSiCandandalusitewithcalciumaluminatebinderforcastablesinhighcorrosivegasifyingenvironmentsisapromisingalternativerefractorysystemformanydifferentslagsystems.Aftersintering,aglassyprotectivelayerhasbeenidentified.Besidetheinteractionsoftherefractorieswithintermediateslagalsothethermomechanicalproperties,thethermalshockperformanceandthemicrostructurehavebeenevaluatedasafunctionofdifferentbindersystems.

简介：ThemechanicalpropertiesofpressurelesssinteringFe-Si3N4bondedSiCandSi3N4bondedSiCwithsamemanufactureprocesshavebeencomparedinthispaper.TheoxidizingmechanismofFe-Si3N4bondedSiCceramicmatrixcompositehasbeeninvestigatedespeciallythroughTG-DSC(thermogravimetricanalysis-differentialscanningcalorimeter)experiment.DuringoxidationprocedurethemainreactionistheoxidationofSiCandSi3N4,SiO2whichformprotectingfilmtopreventfurtheroxidizing.AndresidualironinthesamplesbecomeFe2O3andFe3O4,theoxidationkineticsat1100～1300℃ofre-Si3N4bondedSiChasbeenstudiedespecially.Theweightgainperunitareaatinitialstagechangesaccordingtobeelinerule,inthemiddleaccordingtoconic,andinthelastoxidationperiodfollowsparabolarule.

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简介：TheAl2O3-SiCcompositepowderswerepreparedinargonatmosphereusingcoalgangueandcarbonaceousmaterials

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简介：IntheprocessofsynthesisofnanometerSiCprecursorswithsol-gelofSiO2andlignin,theproductsofallsizesrequiredcanbecontrolledbytheconcentrationofreac-tants,pH,temperature,ractionandageingtime,andsoon.Thebestconditionsinthisreserchare:theconcentrationofNa2SiO3andorganicmattersare4.50%and26.4%respectively,pH=3.3,T=65℃，ageingtimeis30min,driedat150℃，thesizeofSiCprecursorsisabout2.0μm。

简介：Inthisstudy,inordertoevaluatetheperformanceofhomogenizedbauxite,twoAl_2O_3-SiC-Ccastableswerepreparedusinghomogenizedbauxiteandbrownfusedcorundumasaggregates,respectively.5mass%andalusitewasintroducedintothetwocastablessoastoresearchtheeffectandmechanismofandalusiteinAl_2O_3-SiC-Ccastables.Theresultsshowedthat:(1)comparedwiththebrownfusedcorundumbasedcastables,thehomogenizedbauxitebasedcastableshadhighercoldstrengthafterheattreatment,butlowerhotmodulusofrupture;(2)additionof5mass%andalusitecouldenhancethecoldandhotmodulusofrupture,improvethethermalshockresistance,andoptimizethemicrostructureofspecimens;(3)themullitizationofandalusitewasnotobviousinthecastablesfiredat1100-1400℃.

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简介：MicrostructureandgrainboundarycharacterofhotpressedbinaryAl2O3(mullite,ZrO2)-SiCompositesandquaternaryAl2O3-mullite-ZrO2-SiCcompositewerestudiedbyelectronmicroscopyandmicroanalysis,ResultssuggestthatthereexistgrainboundarysolidsolutionsduetoelementaldiffusionnearSiCandmatrixoxidesgrainboundaries.

简介：LowcementAl2O3-SiO2castableswaspreparedusingsupergradebauxite(w(Al2O3)>85%)asaggregate,brownfusedcorundum,siliconcarbide,Secar71CAcement,α-Al2O3micropowderandmicrosilicaasfinepowders.TheinfluenceofSiC(0,5wt%,10wt%,and15wt%)onresistancetoPbO-richslagwasinvestigatedbystaticcrucibleslagtest(1300℃for5h,inair).TheslagcorrosionmechanismofthecastableswasanalyzedbymeansofSEM,EDSandXRD.TheresultsshowthattheresistanceofAl2O3-SiO2castablestoPbO-richslagisimprovedobviouslybytheadditionofSiC.ThecorrosionmechanismofthePbO-richslagcanbediscribedasthatPbOintheslagreactswithSiO2andCaOinAl2O3-SiO2castables,forminglow-meltingcompounds(suchasPbO·SiO2and2PbO·SiO2).

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