学科分类
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7 个结果
  • 简介:Theoxidationbehaviorofthreebiodieselsofdifferentorigins,viz.rapeseedoilderivedbiodiesel,soybeanoilderivedbiodieselandwasteoilbasedbiodiesel,weretestedonanoxidationtester.Thechemicalcompositionsofthebiodieselswerecharacterizedbygaschromatography.Thereafter,thestructuraltransformationoffattyacidmethylester(FAME)ofthebiodieselswasanalyzedbyaninfraredspectrometerandanultravioletabsorptionspectrometer.TheresultsdemonstratedthattheoxidationbehaviorofbiodieselsofdifferentoriginswascloselyrelatedtothecompositionanddistributionofFAMEs.HigherconcentrationofunsaturatedFAMEwithmulti-doublebondsexhibitedpooreroxidationresistance.Furthermore,cis-transisomerizationtransformationoccurredintheunsaturatedFAMEmoleculesandconjugateddouble-bondproducedduringtheoxidationprocessofbiodiesel.Greatercis-transvariationscorrespondedtodeeperoxidationdegree.ThehigherthecontentofunsaturatedFAMEwithmulti-doublebondsinabiodiesel,themoretheconjugateddoublebondswasformed.

  • 标签: 生物柴油 氧化行为 结构转变 光谱分析 脂肪酸甲酯 共轭双键
  • 简介:Inordertomeettheurgentneedforreducingolefincontentincrackednaphtha,theinfluenceoffeedstockcharacteristicsontheolefincontentwasdiscussed.ThedifferenttypesandperformanceofcatalystsdevelopedbyRIPPwereintroduced.Moreover,someeffectiveoperationapproachesincommercialunitswerepresentedtoserveasareferencetotherefinersforcatalystselection.

  • 标签: FCC汽油 流化床加氢裂化 石蜡 影响因素
  • 简介:以便为汽油质量遇见需求升级,SINOPECAnqingBranch同伴与MGD技术翻新了DCC单位并且与MIP技术装备了FCC单位。当为他们的经济好处的最大化集中于他们的特定的特征和方法时,这篇文章以技术和经济在theMIP和DCC/MGD过程的商业申请上做分析和比较。

  • 标签: MIP DCC/MGD 安庆石化公司 技术经济分析
  • 简介:这篇文章总结进程单位的精力消费和在最近的年里构造或修理的10个Mt/a类精炼厂的全面精力消费。节省在这些精炼厂的设计采用的措施的精力被分析并且讨论。最后,这篇文章也做评价并且以后在精炼厂为能量守恒在目的上提出建议。

  • 标签: 能源储备 炼油企业 处理单元 指示剂
  • 简介:TheSargentdividingwallcolumncanimplementfourproductsseparationsequencesinonecolumnbasedonFullyThermallyCoupledDistillationColumn.TheinitialdesignparametersarerequiredforthedesignoptimizationordynamiccontroloftheSargentdividingwallcolumn,andinordertomaketherigoroussimulationoftheSargentdividingwallcolumnmoreconducivetoconvergence,atencolumnmodelforcomplexSargentcolumnisestablishedinthispaper,andtheshortcutdesignmethodofthismodelisproposed.TheinternalminimumvaporandliquidflowareobtainedbytheUnderwoodequationsandthemassbalancemethodandtheV-minmethod.Theseparationfora4-componentshortcutmixtureofpentane,hexane,heptaneandoctanewasconsidered,whiletheinitialvaluesofdesignparametersandtheratioofvapor-liquiddistributionofeachcolumnwerecalculatedbyusingtheshortcutdesignmethodofatencolumnmodel.Andbycomparingtheshortcutcalculationswithrigoroussimulationresults,thepracticalityandreliabilityofshortcutcalculationswereverified.Thereasonforenergysavingwasanalyzedbasedonback-mixing.AvirtualheatexchangerisproposedtomaketheSargentdividingwallcolumnmoreenergyefficient.

  • 标签: Sargent dividing WALL COLUMN shortcut design
  • 简介:<正>TherulesofMIPreactionsforcatalyticcrackingofsulfurcompoundsanditsinfluenceonthesulfurcontentintheMIPnaphthawerestudied.ThemamfactorsinfluencingthesulfurcontentintheMIPnaphthawerethoughttobethesulfurcontentoffeedstockandwerecloselyrelatedwiththeolefincontentofnaphtha.TakingintoaccountthecharacteristicfeaturesofMIPprocess,themethodsforreducingthesulfurcontentintheMIPnaphthawerecomprisedofdecreasingthesulfurcontentoffeedstockbyhydrotreatinganddecreasingtheolefincontentofnaphthathroughpromotinghydrogentransferreactions.Therefore,theEuroⅣcleangasolinewithlowsulfurcontentandlowolefincontentcouldbeobtaineddirectlythroughtheMIPtechnology.

  • 标签: FCC MIP process GASOLINE SULFUR content