简介:Adiode-pumpedalkalilaser(DPAL)providesthesignificantpromiseforhigh-poweredperformances.Inthispaper,amathematicalmodelisintroducedforexaminationofthekineticprocessesofadiode-pumpedcesiumvaporhollow-corephotonic-crystalfiber(HC-PCF)laser,inwhichthecesiumvaporisfilledinthecenterholeofaphotonic-bandgapfiberinsteadofaglasscell.Theinfluenceofdeleteriousprocessesincludingenergypooling,photo-ionization,andPenningionizationonthephysicalfeaturesofafiberDPALisstudiedinthisreport.Ithasbeentheoreticallydemonstratedthatthedeleteriousprocessescannotbeignoredinahigh-poweredfiber-DPALsystem.
简介:Lithium-sulfur(Li-S)batteriesbelongtooneofthepromisingtechnologiesforhigh-energy-densityrechargeablebatteries.However,sulfurcathodessufferfrominherentproblemsofitspoorelectronicconductivityandtheshuttlingofhighlydissolublelithiumpolysulfidesgeneratedduringthecycles.Loadingsulfurintoporouscarbonshasbeenprovedtobeaneffectiveapproachtoalleviatetheseissues.Mesoporousandmicroporouscarbonshavebeenwidelyusedforsulfuraccommodation,butmesoporouscarbonshavepoorsulfurconfinement,whereasmicroporouscarbonsareimpededbylowsulfurloadingrates.Here,acore-shellcarbon,combiningboththemeritsofmesoporouscarbonwithlargeporevolumeandmicroporouscarbonwitheffectivesulfurconfinement,waspreparedbycoatingthemesoporousCMK-3withamicroporouscarbon(MPC)shellandservedasthecarbonhost(CMK-3@MPC)toaccommodatesulfur.Aftersulfurinfusion,theas-obtainedS/(CMK-3@MPC)cathodedeliveredahighinitialcapacityofupto1422mAh·g-1andsustained654mAh·g-1reversiblespecificcapacityafter36cyclesat0.1C.Thegoodperformanceisascribedtotheuniquecore-shellstructureoftheCMK-3@MPCmatrix,inwhichsulfurcanbeeffectivelyconfinedwithinthemeso/microporouscarbonhost,thusachievingsimultaneouslyhighelectrochemicalutilization.
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简介:Weperformmicromagneticsimulationsontheswitchingofmagneticvortexcorebyusingspin-polarizedcurrentsthroughathree-nanocontactgeometry.Oursimulationresultsshowthatthecurrentcombinationwithanappropriatecurrentflowdirectiondestroysthesymmetryofthetotaleffectiveenergyofthesystemsothatthevortexcorecanbeeasiertoexcite,resultinginlesscriticalcurrentdensityandafasterswitchingprocess.Besidesitsfundamentalsignificance,ourfindingsprovideanadditionalroutetoincorporatingmagneticvortexphenomenaintodatastoragedevices.
简介:Inthepresentwork,core-shellNi@SiO2catalystswereinvestigatedinordertoevaluatetherelevanceofcatalyticactivityandsurfacestatesofNicoreaswellasNinanoparticlessizetocatalyticpartialoxidationofmethane(POM).ThecatalystswerecharacterizedbyN2adsorption,H2-TPR,XRD,TEMandXPStechniques.Thecatalyticperformanceofthecore-shellcatalystswasfoundtobedependentonthesurfacestatesofcatalyst,whichinfluencedtheformationofproducts.Itwasconsideredthatcarbondioxideformedontheoxidizednickelsites(NiO)andcarbonmonoxideproducedonthereducedsites(Ni).ThesurfacestatesofactivemetalinthedynamicwereinfluencedbothbythesizeofNicoreandtheporosityofsilicashell.However,thecatalyticactivitywouldbedebasedwhenthesizeofNicorewasunderacertainextent,whichcanbeascribedtothefactthecarbondepositionincreasedwiththeincreasingcontentofNiO.TheeffectsofsurfacestatesofNi@SiO2catalystonthecatalyticperformancewerediscussedandthereactionpathwayoverNicoreencapsulatedinsidesilicashellwasproposed.