学科分类
/ 17
330 个结果
  • 简介:THEREVISEDSTRUCTUREOFGNETIFOLINA¥ZhiMinWANG;XiaoTianLIANGandShuFengCHEN(InstituteofMateriaNedica,Chinese.AcademyofMedicalScie...

  • 标签:
  • 简介:Potassiumα-andβ-trivanadoenneatungstogermanateswerepreparedandcharacterizedbymeansofelementalanalysis,IR,51Vand183WNMRspectraandpolarography.Thesinglecrystalstructureofa-isomerwasdetermined.ThefinalRis0.083.TheresultsshowthattwopreparedheteropolyanionshaveKegginstructure,anda-isomerbelongstoA-typeandhasstrongeroxidizingabilitythanβ-isomer.

  • 标签: CRYSTAL STRUCTURE Trisubstituted COMPOUND Tungstogermanate
  • 简介:Theelectrochemicaloxidationofdiphenylamineinacetonitrileproducesanadherentuniformpolymerfilmwhichexhibitsmutiplecolourvariation(yellow-green-blue)inawiderangeofpotentialscan.Thepolymerizationmechanismandthestructureofthepolymerwerestudiedbycyclicvoltammetry,FT-IRandinsituESR.Theresultsindicatethattheelectrochemicalpolymerizationofdiphenylaminebelongstoacationicradicalpolymerizationprocess.Duringelectrolysis,onlyoligomerswereinitialyproduced,thenpolymerfilmwasformedontheelectrodesurface.Theelectropolymerizationperformsviathe4,4’C-Cphenyl-phenylcouplingmechanism.

  • 标签: DPA ELECTROCHEMICAL POLYMERIZATION MECHANISM ESR.
  • 简介:Itisknownthatnearlyuncoupledirreduciblestochasticmatricesmustpossesssub-dominanteigenvaluesnearλ=1.Itisnaturetoaskwhethertheconverseistrue.HortfielandMeyer[2]gaveapositiveanswer.TheyintroducedthenotionofuncouplingmeasureofStochasticmatrices.Forann×nstochasticmatrixPtheuncouplingmeasureofPisde-finedasσ(p)=min((sumfromi∈M1,j∈M1(Pij))+(sumfromi∈M1,j∈M1(Pij)),wheretheminimumistakenoverall

  • 标签:
  • 简介:<正>Weobtaimanewsubstitutionformodulesoverexchangeringssatisfvingrelatedcompara-bilitv.Alsoweinvestigatethestructureofmodulesoverexchangeringssatisfyingpowercomparabilityandprovideanewclassofexchangeringssatisfyingrelatedcomparability.

  • 标签: RELATED comparability POWER comparability EXCHANGE RING
  • 简介:WhenthePoissonmatrixofPoissonsystemisnon-constant,classicalsymplecticmethods,suchassymplecticRunge-Kuttamethod,generatingfunctionmethod,cannotpreservethePoissonstructure.Thenon-constantPoissonstructurewastransformedintothesymplecticstructurebythenonlineartransform.ArbitraryordersymplecticmethodwasappliedtothetransformedPoissonsystem.TheEulerequationofthefreerigidbodyproblemwastransformedintothesymplecticstructureandcomputedbythemid-pointscheme.Numericalresultsshowtheeffectivenessofthenonlineartransform.

  • 标签: Poisson系统 对称结构 非线性传播 刚性体 POISSON结构
  • 简介:Thereisawellestablishedmultifractaltheoryforself-similarmeasuresgeneratedbynon-overlappingcontractivesimilutudes.Ourreporthereconcernsthosewithoverlaps.Inparticularwerestrictourattentiontotheimportantclassesofself-similarmeasuresthathavematrixrepresentations.ThedimensionspectraandtheLq-spectraareanalyzedthroughtheproductofmatrices.Thereareabnormalbehaviorsonthemultifrac-talstructureandtheywillbediscussedindetail.

  • 标签: 矩阵 不规则结构 乘积 自我相似测量法 叠函数 空间范围
  • 简介:Tetradecyldimethylbenzylammoniumsalt(TDMBA)cationswereintercalatedintosodiummontmorillonite(Na-MMT)byanionexchangereaction.TheresultingTDMBA-MMTwascharacterizedbyFourier-transforminfraredspectroscopy(FTIR),thermogravimetricanalysis(TGA),andX-raydiffraction(XRD).Moreover,theantibacterialactivityandwater-resistanceofTDMBA-MMTwereinvestigated.TheresultsshowthatTDMBAcationsareintercalatedintotheNa-MMT.TheonsettemperatureofdecompositionofTDMBAcationsinTDMBA-MMTisraisedabout60℃higherthanthatoftetradecyldimethylbenzylammoniumchloride(TDMBACl),andthed_((001))spacingenlargedfrom1.23nmto2.10nm.0.1mg/mLTDMBA-MMTisfullyenoughtokillalltheStaphylococciaureus(S.aureus)andmorethan99.99%oftheEscherichiacoli(E.coli)inasamplesolutionwithin6.0htouch,andtheTDMBA-MMTalsoshowslongactingproperties.

  • 标签: 抗菌活性 金黄色葡萄球菌 石结构 傅立叶变换红外光谱 离子交换反应 钠蒙脱土
  • 简介:

  • 标签:
  • 简介:平行的Liesegang模式猛抛当包含的答案一同沉淀时,乐队们被获得在一个1D胶化矩阵的离子interdiffuse。形成的节俭地可溶的盐,显示磁盘的美丽的层化猛抛对1D试管轴垂直。Liesegang结构从他们的分数维的性质的观点被分析。几何Liesegang模式与象时间,乐队间距和乐队宽度法律那样的著名实验法律在一致被构造。扩散的起始的集中上的乐队间距的依赖(外部)并且不动(内部)电解质(一0并且B0,分别地)被拿跟随Matalon-Packter法律。数学分数维的尺寸和盒子计数尺寸是计算的。分数维的尺寸被发现与增加A增加0并且减少的B0。我们也与雏晶的随机的分发分析马赛克模式,在他们的分数维的性质上比古典Liesegang胶化方法,和报告在不同条件下面成长。最后,乐队在多重谱线被组织的复杂Liesegang模式被学习,并且分数维的性质与复合增加,这被显示出。

  • 标签: 沉淀 分形结构 Liesegang环 艺术 分形性质 凝胶基质
  • 简介:Intheunderwater-shockenvironment,cavitationoccursnearthestructuralsurface.Thedynamicresponseoffluid-structureinteractionsisinfluencedseriouslybythecavitationeffects.Itisalsothedifficultyinthefieldofunderwaterexplosion.Withthetraditionalboundaryelementmethodandthefiniteelementmethod(FEM),itisdifficulttosolvethenonlinearproblemwithcavitationeffectssubjectedtotheunderwaterexplosion.Tosolvethisproblem,undertheconsiderationofthecavitationeffectsandfluidcompressibility,withfluidvisciditybeingneglected,a3Dnumericalmodeloftransientnonlinearfluid-structureinteractionsubjectedtotheunderwaterexplosionisbuilt.Thefluidspectralelementmethod(SEM)andtheFEMareadoptedtosolvethismodel.AftercomparisonwiththeFEM,itisshownthattheSEMismoreprecisethantheFEM,andtheSEMresultsareingoodcoincidencewithbenchmarkresultsandexperimentresults.Basedonthis,combinedwithABAQUS,thetransientfluid-structureinteractionmechanismofthe3Dsubmergedsphericalshellandshipstiffenedplatessubjectedtotheunderwaterexplosionisdiscussed,andthecavitationregionanditsinfluenceonthestructuraldynamicresponsesarepresented.Thepaperaimsatprovidingreferencesforrelevantresearchontransientfluid-structureinteractionofshipstructuressubjectedtotheunderwaterexplosion.

  • 标签: 结构相互作用 三维数值模型 水下爆炸 拟流体 气蚀 有限元法
  • 简介:Theeffectofdifferentkindsofcomonomerswithorwithoutflexiblechainonproper-tiesofcopolyesters,suchastransitiontemperature,crystallizationvelocity,crystallinityandsizeofcrystallites,isstudied.Theexperimentalresultsindicatetheobviousdiffer-enceinpropertiesbetweencomonomerswithiso-andortho-structureofphenylringandcomonomerswithflexiblechain.Theinfluenceofchemicalstructureofcomonomersonpropertiesofcopolyestersisdiscussed.

  • 标签: COPOLYESTERS POLYETHYLENETEREPHTHALATE COMONOMER CHEMICAL STRUCTURE