简介:TheeffectsofLaonsomehydrolyticenzymeactivitiesinredsoilwerestudiedinincubationandpetcultureexperiments.Intheincubationexperiment,Laslightlystimulatestheactivitiesofureaseandacidicphosphataseinsoilandstronglystimulatessucraseactivityinsoil.Inthepetcultureexperiment,Lastimulatestheactivitiesofurease,acidicphosphataseandsucrasetodifferentdegrees.Thestimulativeeffectsofrareearthelements(REE)onhydrolyticenzymeactivitiesinsoilmayresultinincreasingyieldofeivps.
简介:Rareearthcompoundsasmodifiersusedwidelyinmodernfrictionmaterialscanenhancetheinterfacialbindingofconstituentsofmaterialsandimprovethecomprehensivepropertiesofmaterialsevidently.However,therearestillfewreportsonapplicationofrareearthinautomotivefrictionmaterials.Inordertostudytheeffectmechanismofrareearthsinfrictionmaterials,arareearthcompoundwasselectedasadditiveandtheeffectsofmaterialsdopedwithorwithoutrareearthonfrictionandwearpropertiesofmaterialswerestudied.Themicrostructureandwornsurfacemorphologywereobservedbyscanningelectronmicroscopyandthemacroperformancewasdiscussed.Wornsurfaceelementconstitutionofmaterialswasanalyzedbyenergydispersivespectroscopy.Effectmechanismofrareearthsonfrictionandwearbehaviorsoffrictionmaterialswerediscussed.Theresultsshowthatdopingrareearthsinfrictionmaterialscanstabilizefrictioncoefficient,lowerthewearrateofmaterialsandincreasetheimpactstrengthofmaterials.Theflexibilityandfractureresistanceofmaterialsisgreatlyimproved.Wornsurfaceofmaterialsdopedwithrareearthiscompactandthesurfaceadhesionisgreatlyenhanced.
简介:Theslowtensiletests,dynamichydrogenchargingtensiletestsandhydrogenevolutiontestsafterhydrogenchargingwereusedtostudytheeffectsofrareearthmetal(REM)onhydrogenbehaviourinasteel16Mn(St.52).TheratiosofRE/Swerechosenas0,0.7,2.2and7.7,respectively.ItwasshownthatthesteelwithRE/S=2.2givealowerhydrogenembrittlementsusceptibilitythanothers.ThesteelswithoutREMcanadsorbmuchmoreamountofhydrogenthanthatwithREMunderthesamehydrogenchargingconditions.Andtheamountofadsorbedhydrogenfortheforinercanbeevolvedeasierthanthatforthelatteratroomtemperature,50℃and80℃,respectively.Theexperimentalresultswereexplainedbythetraptheoryofhydrogen,theshort-circuitdiffusionpathsintheinterfacesbetweentheelongatedMnSinclusionsandthematrix,andstrongabilityofREMtoadsorbhydrogen.
简介:Ceriasphereswithdifferentsizesandsulfurizedproductswithcorrespondingmorphologywerepreparedbyhydrothermalandgas-solidreactionmethodat600–800°CunderCS2atmosphereforashorttime,respectively.Dimensionaleffectinpreparationofγ-Ce2S3wasfirstlyinvestigatedbymeansoftechniquessuchasscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),thermalgravimetricanalysis(TGA)andspectrophotometer.Theresultsshowedthatwhenceriananoparticleswithsmallsizewereusedasprecursors,theγ-Ce2S3couldbepreparedatthelowertemperatureandthebadlysinteredproductswereobtained;whenceriananoparticleswithlargesizewereemployedasprecursors,pureγ-Ce2S3wasdifficultlyobtainedevenifthetemperaturewasupto800°Candtheproductstendedtokeeptheiroriginalsize.Theheat-resistancepropertyoftheγ-Ce2S3withlargesizewasbetterthanthesmallerone,andthepureγ-Ce2S3preparedfromprecursorwithsmallsizehadagoodpigmentaryperformance.
简介:CeO2nanoparticles(nano-CeO2p)wereaddedintolasercladdedNiCoCrAlYcoatingsonNi-basedsuperalloysubstratetoimprovethemicrostructureandproperties.Scanningelectronmicroscope(SEM),X-raydiffractometer(XRD),micro-hardnesstester,andheattreatmentfurnacewereemployedtoinvestigatetheirmorphologies,phases,micro-hardnessandthermalshockresistance,comparedwiththecoatingwithoutnanoparticlesadded.Theresultsshowedthatthemicrostructureandpropertiesofthecoatingswiththeaddition...
简介:拥有做位置的不同Ce的Pd和PdPt催化剂的物理化学的性质被TEM,XRD,N2吸附解吸附作用,XPS和英尺红外的技术调查。为甲醇总数氧化的催化表演被检验学习增加位置的Ce的效果。CeO2艾尔2O3Ce直接被介绍进支持的TiO2(猫)催化剂比CeO2/Al22选择>O3Ce被受精在装载的TiO2(Ce/AT)样品方法。描述结果表明做位置的Ce不引起基本水晶的阶段的明显的另一和支持的mesoporous结构。然而,做位置的Ce影响支持的毛孔形状然后影响毛孔直径。猫催化剂拥有更丰富的吸附的氧和更多Ti3+能在催化剂表面上把更气体的氧转变成活跃的氧种类,它对反应有益。在猫的AlOTi桥便于艾尔和Ti种类的合作,它进一步加快反应率。
简介:在这份报纸,有石墨(C)或碳nanotubes(CNT)的增加的SmCo6.9Hf0.1当演员组合金和带子被融化的弧和融化旋转分别地准备。补充说结构和磁性SmCo6.9Hf0.1上的碳借助于X光检查衍射(XRD)被调查的效果,扫描电子显微镜学(SEM),传播电子显微镜学(TEM),磁性的力量显微镜学(MFM)和颤动的样品磁强计(VSM)。尽管他们的水晶结构作为一样的Sm被描绘,微观结构和SmCo6.9Hf0.1带子的磁性的结构由于C或CNT的介绍显然被改变,这被发现尽管他们的水晶结构作为一样的Sm被描绘(公司,Hf)7单个阶段,不管碳被增加。作为结果,包含碳的带子的磁性在某个度被提高。这被认为与精制equiaxed谷物,小领域尺寸和C或CNTs富有的区域的卡住的效果有关。SmCo6.9Hf0.1(CNT)的磁性0.05条带子到达了Hc=12.5kOe,Mr=57.0emu/g和Mr/M2T=0.788。
简介:Praseodymium(Pr)wasimpregnatedtoCeO2-ZrO2solidsolutionbyanimpregnationmethod.Theas-obtainedPrmodifiedCeO2-ZrO2wasimpregnatedwith1wt.%Pdtopreparethecatalysts.ThestructureandreducibilityofthefreshandhydrothermallyagedcatalystswerecharacterizedbyX-raydiffraction(XRD),Raman,X-rayphotoelectronspectroscopy(XPS),COchemisorptionandH2temperature-programmedreduction(H2-TPR).Theoxygenstoragecapacity(OSC)wasevaluatedwithCOservingasprobegas.EffectsofimpregnatedPronthestructureandoxygenstoragecapacityofcatalystswereinvestigated.TheresultsshowedthattheagedPr-impregnatedsampleshadmuchhigherOSCandbetterreducibilitythantheunmodifiedones.TheschemeofstructuralevolutionsofthecatalystswithandwithoutPrwasalsoestablished.PartialoftheimpregnatedPrdiffusedintothebulkofCeO2-ZrO2duringageing,whichinhibitedthesintering,andincreasedtheamountofoxygenvacanciesinCeO2-ZrO2support.Furthermore,thoseimpregnatedPrspecieswhichcoveredonthesurfaceofthesupportobstructedthestrongmetal-supportinteractionbetweenPdandCesoastoreducetheencapsulationofPdaswellasthebackspill-overoftheoxygenduringthecatalyticprocess.
简介:(Cu60Zr30Ti10)98Y2bulkmetallicglass(Φ4mm×70mm)wasobtainedsuccessfullybycoppermouldcoolingandspraying-casting,andsomesampleswereisothermallyannealedattemperaturesof473and623K,whichwaslowerthantheglasstransitiontemperature(Tg)for1h.Microstructureandpropertiesofas-castandannealedsampleswerestudied.Crystallizationphases(Cu10Zr7andCuZr)wereobservedinannealedsamples,andthespeciesandfractionofthesephasesincreasedwithincreasingannealingtemperature.Mic...