简介：我们综合有单个多孔的壳和Ag@Au/Ag@Au的空结构的Ag@Aunanoparticles由使用流电的代替反应加倍壳并且调查他们的线性、非线性的光性质。我们的结果证明空多孔的nanoparticles的表面电浆子回声波长能被控制HAuCl4的体积容易在可见、近的红外线的区域在一个宽范围调节。双shelledAg@Au/Ag@Aunanoparticles的非线性的光折射被电浆子回声显著地提高。我们的调查结果可以在生物传感器和非线性的光nanodevices发现应用。

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简介：Ｉｎｔｅｒｍｅｄｉａｔｅ　Ｍａｓｓ　Ｆｒａｇｍｅｎｔ　Ｅｍｉｓｓｉｏｎ　ｉｎ　Ａｒ＋Ａｇ　ＣｏｌｌｉｓｉｏｎｓＩｎｔｅｒｍｅｄｉａｔｅＭａｓｓＦｒａｇｍｅｎｔＥｍｉｓｓｉｏｎｉｎＡｒ＋ＡｇＣｏｌｌｉｓｉｏｎｓ￥ＷｕＥｎｊｉｕ；ＺｈｅｎｇＪｉｗｅｎ；Ｗ...

简介：我们用散布理论的第一个原则在FM|NM|YIGmultilayers调查了热旋转转移效果。在房间温度，旋转Seebeck转矩TSSE~1:0J/(K？？

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简介：TheannealingbehaviorofAgnanoparticlesinsilicawithandwithoutdefectswasinvestigatedinthisstudy.SilicasampleswithandwithoutArionpre-irradiationwereimplantedwithAgionsandthenannealedattemperaturefrom300to850℃.UV-VISspectroscopyandTEMwereusedtocharacterizetheopticalabsorbancepropertyandsizedistributionofAgnanoparticles,respectively.OpticalabsorbanceresultsshowthattheabsorbanceintensityofSPR(SurfacePlasmonResonance,SPR)peakfromAgnanoparticlesinthesamplewithpre-irradiationisstrongerthaninthesamplewithoutpre-irradiation,whichindicatesthatthedefectsproducedbypre-irradiationpromptthenucleationofAgnanoparticles.Duringannealing,theSPRpeakshiftstoshortwavelengthdirection,asshowninFig.1.

简介：ThispaperinvestigatesthesolidificationbehaviouroftheAg—Cueutecticalloymeltundercooledupto100K.ItisrevealedthatlamellareutecticsgrowinadendriticformintheAg-Cueutecticmeltwithundercoolingequaltoorgreaterthan76K.Asundercoolingincreases,theremeltedfractionoftheprimaryeutecticsduringrecalescencerises.Thesevereremeltingandthesubsequentripeningoftheprimaryeutecticdendritesleadtotheformationofanomalouseutectics.

简介：Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties（including:microstructureandcomposition）andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.

简介：COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.

简介：Ｍｅａｓｕｒｅｍｅｎｔ　ｏｆ　Ｌｉｎｅａｒ　Ｍｏｍｅｎｔｕｍ　Ｔｒａｎｓｆｅｒ　ｉｎ　Ａｒ＋Ｂｉ　ａｎｄ　Ａｒ＋Ａｇ　Ｓｙｓｔｅｍｓ　ａｔ　２５ＭｅＶ／ｕＭｅａｓｕｒｅｍｅｎｔｏｆＬｉｎｅａｒＭｏｍｅｎｔｕｍＴｒａｎｓｆｅｒｉｎＡｒ＋ＢｉａｎｄＡｒ＋...

简介：ＩｓｏｔｏｐｅｓＴｅｍｐｅｒａｔｕｒｅｉｎ４０Ａｒ＋１５８Ｔｂａｎｄ１０８ＡｇＲｅａｃｔｉｏｎｓａｔ３０ＭｅＶ／ｕ￥ＤａｉＧｕａｎｇｘｉ；ＦｕＹａｎｂｉａｏ；ＨｅＺｈｉｙｏｎｇ；ＤｕａｎＬｉｍｉｎ；ＬｉＺｕｙｕａｎｄＺｈａｎｇＢａｏｇ?..

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简介：WepresentthetemperaturedependentelectricaltransportmeasurementsofAg/Si（111）-（√3×√3）R30°bytheinsitumicro-four-pointprobemethodintegratedwithscanningtunnelingmicroscopy.Thesurfacestructurecharacterizationsshowhexagonalpatternsatroomtemperature,whichsupportstheinequivalenttriangle（IET）model.Ametal-insulatortransitionoccursat-115K.Thelowtemperaturetransportmeasurementsclearlyrevealthestronglocalizationcharacteristicsoftheinsulatingphase.

简介：TernarymetalchalcogenidesemiconductorAg8SnS6,whichisanefficientphotocatalystundervisiblelightradiation,isstudiedbyplane-wavepseudopotentialdensityfunctionaltheory.Aftergeometryoptimization,theelectronicandopticalpropertiesarestudied.Ascissoroperatorvalueof0.81eVisintroducedtoovercometheunderestimationofthecalculationbandgaps.Thecontributionofdifferentbandsisanalyzedbyvirtueoftotalandpartialdensityofstates.Furthermore,inordertounderstandtheopticalpropertiesofAg8SnS6,thedielectricfunction,absorptioncoefficient,andrefractiveindexarealsoperformedintheenergyrangefrom0to11eV.TheabsorptionspectrumindicatesthatAg8SnS6hasagoodabsorbencyinvisiblelightarea.Surfaceenergiesandworkfunctionsof(411),(413),(211),and(112)orientationshavebeencalculated.TheseresultsrevealthereasonforanoutstandingphotocatalyticactivityofAg8SnS6.

简介：CrystallineTiO2（P25）andisolatedtitanatespeciesinaZSM-5structure（TS-1）weremodifiedwithAuandAg,respectively,andtestedinthegas-phasephotocatalyticCO2reductionunderhighpurityconditions.Thenoblemetalmodificationwasperformedbyphotodeposition.LightabsorbancepropertiesofthecatalystsareexaminedwithUV–Visspectroscopybeforeandaftertheactivitytest.Inthegas-phasephotocatalyticCO2reduction,itwasobservedthatthecatalystswithAgnanostructuresaremoreactivethanthosewithAunanostructures.Itisthusfoundthattheenergeticdifferencebetweenthebandgapenergyofthesemiconductorandthepositionoftheplasmonisinfluencingthephotocatalyticactivity.Potentially,plasmonexcitationduetovisiblelightabsorptionresultsinplasmonresonanceenergy,whichaffectstheexcitationofthesemiconductorpositively.Therefore,anoverlapbetweenbandgapenergyofthesemiconductorandmetalplasmonisneeded.

简介：Afacilestep-by-stepapproachisdevelopedforsynthesizingthehigh-efficiencyandmagneticrecyclableFe_3O_4@SiO_2@Ag@Nitrepang-likenanocomposites.ThismethodinvolvescoatingFe_2O_3nanorodswithauniformsilicalayer,reductionin10%H_2/AratmospheretotransformtheFe_2O_3intomagneticFe_3O_4,andfinallydepositingAg@Nicore-shellnanoparticlesontheL-lysinemodifiedsurfaceofFe_3O_4@SiO_2nanorods.Thefabricatednanocompositesarefurthercharacterizedbyx-raydiffraction,transmissionelectronmicroscopy,scanningelectronmicroscope,Fouriertransforminfraredspectroscopy,andinductivelycoupledplasmamassspectroscopy.TheFe_3O_4@SiO_2@Ag@Nitrepang-likenanocompositesexhibitremarkablyhighercatalyticefficiencythanmonometallicFe_3O_4@SiO_2@AgnanocompositestowardthedegradationofRhodamineB(RhB)atroomtemperature,andmaintainsuperiorcatalyticactivityevenaftersixcycles.Inaddition,thesesamplescouldbeeasilyseparatedfromthecatalyticsystembyanexternalmagnetandreused,whichshowsgreatpotentialapplicationsintreatingwastewater.