学科分类
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10 个结果
  • 简介:Small-angleX-rayscattering(SAXS)usingsynchrotronradiationasX-raysourcehasbeenemployedtocharactcizcthemicroscopicstructrureoforgano-modifiedmesoporousmolecularsieves(organo-MSU-X)preparedbyaone-pottemplate-directedsynthesis.ItisshownthattheSAXSprofileishardlyconstantwithPorod’slawshowinganegativeslope,i.e.,negativedeviation.Thissuggeststhatthereisdiffuseinterfaciallayerlocatedbetweentheporesandthematrix.Thissuggeststhattheorganicgroupsremaincovalentlylinkedtothematrix,asindicatedby^29SiCPMASNMRandFT-IR.Theaveragethicknessoftheinterfaciallayerwasfoundtobeabout1nmforeachofthethreesampleswithdifferentkindsandthesameamounts(20?oforganicgroups.Thiskindofmaterialhasalsobeenprovedtopossessbothsurfaceandmassfractalstructureoftheamophousporoussilicamaterials.2001ElsevierScienceB.V.Allrightsreserved.

  • 标签: 中孔材料 SAXS 小角X射线散射分析 界面层 结构特征 有机中孔分子筛
  • 简介:Inthiswork,negativedielectricnematicliquidcrystalSLC12V620-400,chiraldopantS811,andlaserdyeDCMareusedtopreparedye-dopedchiralnematicliquidcrystallasersample.Inordertoinvestigatetemperature-tunablelasinginnegativedielectricchiralnematicliquidcrystal,wemeasurethetransmissionandlasingspectrumofthissample.Thephotonicbandgap(PBG)isobservedtoredshiftwithitswidthreducingfrom71.2nmto40.2nm,anditsshort-wavelengthbandedgemoves55.3nmwhilethelong-wavelengthbandedgeonlymoves24.9nm.Thewavelengthofoutputlaserisfoundtoredshiftfrom614.4nmat20°Cto662.8nmat67°C,whichisverydifferentfromthepreviousexperimentalphenomena.Therefractiveindices,parallelandperpendiculartothedirectorinchiralnematicliquidcrystalhavedifferentdependenciesontemperature.Theexperimentshowsthatthepitchofthischiralnematicliquidcrystalincreaseswiththeincreaseoftemperature.ThedecreaseinthePBGwidth,differentshiftsofbandedges,andtheredshiftoflaserwavelengtharetheresultsofrefractiveindiceschangeandpitchthermalelongation.

  • 标签: 可调谐激光 负介电常数 向列液晶 手性 温度 激光染料
  • 简介:NanoporousanataseTiO2(np-TiO2)electrodeshavebeendevelopedviatheanodizationoftitaniumfoilsinfluoridecontainingelectrolytes,anditsapplicationinrechargeablelithium-ionbatteries(LIBs)wasinvestigated.Fourdifferenttypesofnp-TiO2electrodeswithdifferentporediametersof14.7±8.2nm,12.8±6.8nm,11.0±5.5,and26.7±13.6nmwerefabricatedforevaluatingtheeffectofnanoporouscharacteristicsontheLIBperformance.Thedischargecapacityofthefourbatterytypes1,2,3,and4were132.7mAhg-1,316.7mAhg-1,154.3mAhg-1,and228.4mAhg-1,respectively.Inaddition,theseelectrodes1,2,3,and4exhibitedreversiblecapacityof106.9mAhg-1after295th,180.9mAhg-1after220th,126.1mAhg-1after150th,and206.7mAhg-1after85thcycleatarateof1C,respectively.Itwasnotedthatthecycliclifeofthebatterieshadaninverserelationship,andthecapacityhadaproportionalrelationshiptotheporediameter.Theenhancedelectrochemicalperformanceofthenanoporouselectrodescanbeattributedtotheimprovedconductivityandtheenhancedkineticsoflithiuminsertion/extractionatelectrode/electrolyteinterfacesbecauseofthelargespecificsurfaceareaofnp-TiO2electrodes.

  • 标签: 纳米二氧化钛 锂离子电池 电化学性能 多孔电极 负极 放电容量
  • 简介:Chiral导致异例的否定磁致电阻(NMR)广泛地在拓扑的半金属为Weyl费米子的存在被用作批评运输证据。在这微型评论,我们在非中心对称的NbP和NbAs讨论NMR现象的一般观察。我们证明NMR能从Weyl费米子或外来的效果的内在的chiral异例产生,例如霍尔信号的重迭;地依赖者在体积的不同类的当前的流动,即,当前的jetting;并且共存的小搬运人的弱本地化(WL)。控制WL的NMR重重地依赖于样品质量并且被一条显著转线路描绘从对在提高的温度的否定先生生长积极,源于在阶段连贯时间和体积的纺纱轨道的散布常数之间的比赛小衣袋。因此,没有赞美技术的支持,在NMR之间的关联和chiral异例需要被细看。因为上升旋转退化,Weyl费米子的旋转取向与动量平行或反平行,它是作为helicity知道的一个唯一的物理性质。helicity的保存为Weyl费米子的运输提供强壮的保护,它能被磁性的杂质有效地仅仅散布。与磁性、无磁性的杂质的化学的做因此是比为检测Weyl费米子的存在的NMR方法更有说服力的。

  • 标签: NBP 半金属 NBA 负磁阻效应 异常 手性
  • 简介:Magneticlocalizedsurfaceplasmonmodesaresupportedonmetallicspiralstructures.Couplingmechanismsforthesemetamaterialresonators,whicharethejointactionofmagneticandelectriccoupling,arestudied.Basedonthestrongcoupling,spoofmagneticplasmonmodespropagatinginthebackwarddirectionareproposedalongachainofsubwavelengthresonators.Thetheoreticalanalysis,numericalsimulations,andexperimentsareingoodagreement.Theproposednovelrouteforachievingnegative-indexwaveguidinghaspotentialapplicationsinintegrateddevicesandcircuits.

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  • 简介:Thetargetofthelargenegativeionsourcebasedonneutralbeaminjection(N-NBI)istoproduceneutralbeamcurrentof22Aandbeampowerof10MWat500keVwithdurationtimeof10s.Sinceitwassuccessfullyoperatedin1996,the5.3MWneutralbeampowerat380keVwithdurationtimeof3shasbeenachieved.Inrecentyearsimprovingandenhancingthebeampoweraregoingon.Severalreasonssuchasplasmanon-uniformity,higherbeamdensityattheupperregioninthebeamprofile,

  • 标签: 能量限制 能量分配 负离子 中性电子束 等离子体
  • 简介:Here,wereportthesynthesisofhardcarbonmaterials(RH)madefromnaturalricehuskthroughasinglepyrolysisprocessandtheirapplicationasananodeinsodium-ionbatteries.ThestudiesshowthattheelectrochemicalpropertiesofRHsareaffectedbythetreatmenttemperatures,whichdeterminethematerialsmorphology,inparticular,theirdegreeofgraphitizationandextentofcontinuouschannels(nanovoids).Thelatterareaccessibletosodiumionsandsignificantlycontributetochargestoragecapacityoftheproducedanodes.TheRHsobtainedat1600°Cdeliverthehighestreversiblecapacityof276mAhg-1mainlyduetoinsertionofsodiumionsintothenanovoids.Thisworkdeepensthebasicunderstandingoftheinfluenceofthecarbonizationtemperatureonthesodiumstoragemechanism.

  • 标签: Nanovoids in RICE husk SUSTAINABLE energy