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简介：Inthispaper,X-raydiffractogramanalysisandSEMobservationofAl4C3formedathightemperaturefromcarbon-containingrefractorieswithAlhavebeencarriedout.Aluminumaddedtocarbon-containingrefractoriesreactswithC(s)toformAl4C3(s)graduallyduringheatingfrom600℃to1200℃.ItisconsideredthattheinterlockedstructureofAl4C3platecrystalspromotestheoutstandingincreaseofhotmodulusofruptureofcarbon-containingrefractorieswithAl.TheHMORofcarbon-containingrefractoriesaddedwithAladditivefrom0to5wt％increasesby2.8timesbeingfrom6.5MPato18.2MPa.AfterathermochemicalcalculationforhydrationreactionprocessesofAl4C3andH2O(g),theequilibriumpartialpressurechartofH2O(g)inH2O-Al4C3-Al(OH)3systemvsvarioustemperatureshasbeenattained.TheH2O(g)partialpressureintheairneededfortheAl4C3hydrationreactionisnomorethan10～18atmatthetemperaturebelow120℃.Itisconsideredthattheburnedcarbon-containingrefractorieswithAlisextremelyeasytohydrateandthecrackingofburnedcarbon-containingrefractoriesisgeneratedbecausethatthehydrationexpansionis2.11timesduringtransformingfromAl4C3toAl(OH)3.ThefundamentalmeasureagainsthydrationoftherefractoriesistoinsulatetherefractoriesfromH2O(g)byvariousmeanssuchaspitchimpregnationorothersealingmaterials.

简介：Inthispaper,Yangquanbauxitebasedonmineralseperationareinvestigated.Itisfoundthattheglassphasewillbedecreasedandthehightemperaturemechanicalpropertiedswillbeimproved.

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简介：ThemechanicalpropertiesofpressurelesssinteringFe-Si3N4bondedSiCandSi3N4bondedSiCwithsamemanufactureprocesshavebeencomparedinthispaper.TheoxidizingmechanismofFe-Si3N4bondedSiCceramicmatrixcompositehasbeeninvestigatedespeciallythroughTG-DSC(thermogravimetricanalysis-differentialscanningcalorimeter)experiment.DuringoxidationprocedurethemainreactionistheoxidationofSiCandSi3N4,SiO2whichformprotectingfilmtopreventfurtheroxidizing.AndresidualironinthesamplesbecomeFe2O3andFe3O4,theoxidationkineticsat1100～1300℃ofre-Si3N4bondedSiChasbeenstudiedespecially.Theweightgainperunitareaatinitialstagechangesaccordingtobeelinerule,inthemiddleaccordingtoconic,andinthelastoxidationperiodfollowsparabolarule.

简介：Siliconcarbide(SiC)-alumina(Al_2O_3)-mullite(Al_6Si_2O_(13))compositepowderwassuccessfullysynthesizedat1550℃for5hviacarbothermalreductionreaction,andtheeffectsofvariousmassratiosofactivecarbontoflyash(0.38,0.44and0.58)onthephasecompositionandmicrostructureofproductswereinvestigated,andtheformationprocessofthepowderwasalsoanalyzedindetail.Theproductsmainlyconsistofβ-SiC,α-Al_2O_3,Al_6Si_2O_(13)andFeSi.IncreasingcarboncontentfavorsthedecompositionofAl_6Si_2O_(13)andformationofSiC.Theaverageparticlesizeofβ-SiCandα-Al_2O_3isabout1μmandthatofAl_6Si_2O_(13)is5-10μm.TheformationprocessofSiC-Al_2O_3-Al_6Si_2O_(13)powderincludesthedecompositionofmulliteinflyashandformationofSiC.

简介：Themicrostructureandslagerosionfractaldimensionofreactioninterfaceofβ-Sialon-Al2O3brickusedin300MtironladleofBaosteelhavebeenstudiedbySEMandXRD.Theresultsindicatedthatβ-Sialon-Al2O3brickexhibitedexcellentslagresistance.Themainwearmechanismofβ-Sialon-Al2O3brickismainlyfromthespallingcausedbythermalmechanicalstressandattackedbyslagsecondly.

简介：Al2O3-MgOcastableshavebeenwidelyusedforworkingliningsofsteelladleduetotheirsuperiorhotstrengthandcorrosionresistance.Inthiswork,effectsofmicrosilica,ultrafinealuminaandMgOfinesadditionsontherheologicalbehaviorofthecastableswereinvestigatedbymeansofIBBrheometerV1.0tomeasuretorque(shearstress)undervaryingshearrates.Theresultsshowthatrheologicalpropertiesofcastablesatvaryingshearratesaresignificantlyimprovedwithincreaseofmicrosilicaadditions(from1mass%to5mass%)andcorrespondingdecreaseinwateraddition;thereisonlylittlechangeinrheologicalbehaviorwithvariationofultrafinealuminaandMgOfinesadditions.Optimumultrafinealuminaandmicrosilicaadditionsarerecommendedforcastableswithgoodrheologicalbehavior.

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简介：TheinfluencesoffourkindsofadditivesaddedintothematrixofMgO-Al2O3unbunedproductswereinvestigated,TheresultsshowthatsampleswithproperMgO/Al2O3rationandproperadditionofCr2O3(2%-4%)havegoodthermalshockresistanceandslagcorrosionresistanceaswell,XRDandSEMdeterminationresultsindicatethatakindofcompoundspinel(Mg,Al,Cr)O4wasformedandthemicrostuctureofthesamplesaredenser.

简介：TiN-Al2O3compositepowderswithdifferentTiNcontents(0,10vol%,20vol%,30vol%and40vol%)werepreparedwithmicrometerTiNandα-Al2O3powder(theirpuritieswere99%)asstartingmaterialsbywetballmillingfor5h.TiN-Al2O3compositewerethenpreparedbypressingtheabovecompositepowders,dryingat200℃for12handfiringat1800℃for3hinnitrogenatmosphereinhot-pressingfurnace.TheinfluencesofTiNcontentonmechanicalpropertiesandelectricalconductivityofTiN-Al2O3compositeswerestudied.TheresultsshowedthatthemechanicalpropertiesofthecompositeincreasedwithTiNcontentincreasing,whiletheresistivityofcompositesdecreased.Acompositewith40%TiNhad498MPabendingstrength,4.285MPa·m1/2fracturetoughness,1.34×10-3Ω·cmresistivity.TheSEManalysisshowedthatthefineTiNcrystalsdistributedamongthecrystalboundaryofAl2O3matrix.Theybondedtogetherforminganet-likestructurewhichplayedaroleofrestrainingAl2O3grainsfromgrowingup,tougheningandstrengthening,sothemechanicalpropertiesofTiN-Al2O3compositewereenhanced.

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简介：TheinfluenceofthreedifferentAl2O3powderonself-flowingaluminacastablewasstudied.MaximumcompactionofsamplewascomputedbyAndresenEquation.TheresultshowedthattheAl2O3powder,whichhasmuchsmallerparticlesize,couldimprovethemicrostructureandthemechanicalpropertiesofcastableunderroomtemperatureandhightemperature.Withthesamepowdersize,theroomtemperaturestrengthofthecastableaddedwithAl2O3powderproPertiesofwhichwerealteredbyaddingmineralizingagent,washigherthanthatofthecastableaddedwithcommonAl2O3powder,buttheflowabilityofthesethreedifferentcastablewasalmostthesame.

简介：Thestabilizationofγ-aluminiumoxyni-tridespinel(γ-AlON)hasbeeninvestigatedbyadditionofMgO,MgAl2O4,etc.,inreactionprocess.Theresultsindicatedthattherearewidersolidsolutionareasnear,Al2O3-richsideinAlN-Al2O3-MgOternarysystems,ThecontentofstabilizedAlONphaseinsamplesisrelatedtoheatingtemperatures,additives,etc.ThelatticeparametersoftheirAlONphasescouldbewelldescribedbytheequation:a0=0.7900+0.0375[MgO]+0.015[AlN](nm)

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简介：Researchonnewtypesofcastables,pre-castassemblypartsandthermalinsulationmaterialswithgoodresistancetowear,thermalshockanderosion,andlowthermalconductivity,wasdonetosolveproblemsofhighsystemenergyconsumption,crackingandspallingofpartialliningandmismatchoffurnacetopmaterialandhangingmaterialandsoon,causedbyunreasonabledesignofChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacelining.Severaldifficultproblemssuchasthematchingofdifferentmaterials,preservationofexpansionjointsamongdifferentzonesandreasonablemechanicaldistributionofliningweresolved.'Integratedfurnace'conceptwasestablishedincludingrefractoriesR&D,liningstructuredesign,constructionoptimization,furnacewarmingtechnology,initialoperationandliningmaintenancetechnology.Thekeytechnologiesofhigh-efficiencyandenergy-savingforfurnacesweredeveloped.TheseachievementshavebeenappliedtoChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacestoreduceenergyconsumptionby1000MJpertonalumina,enhancethecapacityandreducetheexhaustgasemission.

简介：Inordertoimprovetheservicelifeofcorundumliningforinductionfurnace,corundumdryrammingmixwaspreparedusingbrowncorundum,fusedmagnesia,andα-Al2O3micropowderasmainstartingmaterials,andtheinfluenceofα-Al2O3micropowderadditions(0,1%,2%,and3%,inmass)onpropertiesofcorundumdryrammingmixwasinvestigated.Theresultsshowthatafterheattreatingat1600℃,withtheincreaseofα-Al2O3addition,thepermanentchangeindimensionsonheatingofthespecimensdecreasesfirstlyandthenincreases,bulkdensityincreases,apparentporositydecreases,andthecrushingstrengthdeclinesfirstlyandthenenhances;whentheadditionofα-Al2O3is2mass%,thepermanentchangeindimensionsonheatingofthespecimensisrelativelysmallandthecrushingstrengthdecreasesto22.8MPa.TheXRDandSEMresultsshowthatafterfiringat1600℃for3hsmallgranularmagnesiumaluminatespinelformsandiswelldistributed,whichenhancesthedensity.