简介：CyclicvoltammetryandchronoamperometrywereusedtoinvestigatetheclectrochemicalbehaviorofFe(Ⅱ)andEr(Ⅲ)inaLiClO4-DMSO(dimethylsufoxide)systematPtandCuelectrodes.ExperimentalresultsindicatethatthereductionsofFe(Ⅱ)toFe(0)andEr(Ⅲ)toEr(0)wereirreversibleatPtandCuelectrodes.ThediffusioncoefficientandtheclectrontransfercoeffieientofFe(Ⅱ)ina0.01mol/LFeCl2-0.1mol/LLiClO4-DMSOsystemat303Kwere1.70×10^-10m^2/sand0.08respectively,thediffusioncoeffieientandtheelectrontransfercoefficientofEr(Ⅲ)ina0.01mol/LErCl3-0.1mol/LLiClO4-DMSOsystemat303Kwere1.47×10^-10m^2/sand0.108respectivealy.Thehomogeneous,strongadhesiveEr-FealloyfilmscontainingErof31.39%-42.12%inmassfractionwithmetalliclustrewerepreparedbypotentiostaticelectrolysisonaCuelectrodeinaErCl3-FeCl2-LiClO4-DMSOsystemat-1.75—-2.05V(vs.SCE).

简介：［1］BASFUSP4479906［2］BASFBP1443541［3］BASFDE3618265［4］WangL.,WuZ.,ChinaLeather,26(8),11,(1997)［5］YuanL.,DinY.,ChineseChemistryBulletin,(2),19(1988)［6］KurokiH.,ChemistryofDyeingTheory(ChineseTranslation),TextileIndustryPress,Beijing,89(1982)［7］WangS.,LiP.,WuZ.DyestuffIndustry(Chinese),34(4),1,(1997)［8］Tian,Y.,Wu,Z.,Wang,G.,Zhang,S.J.ChineseChem.Eng.,46,156(1995)［9］Tian,Y.,Wang,G.,Wu,Z.,J.ChineseChem.Eng.,47,75(1996)［10］Lycka,A.,DyesandPigment,32,11(1996)［11］Griffith,J.,ColourandConstitutionofOrganicMolecules,AcademicPress,London,191(1976)

简介：Dibromobiphenylreactedwithcynomethylanioninammoniaunderirradiationtoformnucleophilicbis-substitutedproductinhighyieldwithoutsubstantialmonosubstitutedproduct.Quantumyieldsfortheformationsofbis-andmonosubstitutedproductswerefoundtobe85.6and2.3×10-6respectively,whilethecorrespondingpseudo-first-orderrateswere6.9×10-3and5.2×10-10mol.L-1.S-1.Blockupthepossibleelectrontransferof4-brome-4’-cyanomethylbiphenylylradicalanionto4-cyanometbyl-biphenylylradicalandbromineion.

简介：Ahomologousseriesof4’-methylphenyl4"-[(4-alkoxy-2,3,5,6-tetrafluorophenyl)ethynyl]-benzoateshavebeensynthesized.Polarizingmicroscopictexturalobservationshowsthatsuchcompoundsexhibitenantiotropicnematicphase.

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简介：Weexperimentallydemonstratea4×4nonblockingsiliconthermo-optic(TO)switchfabricconsistingofthreestagesoftunablegeneralizedMach–Zehnderinterferometers.All24routingstatesfornonblockingswitchingarecharacterized.Thedevice’sfootprintis4.6mm×1.0mm.Measurementsshowthattheworstcrosstalkofallswitchingstatesis-7.2dB.Theon-chipinsertionlossisintherangeof3.7–13.1dB.TheaverageTOswitchingpowerconsumptionis104.8mW.

简介：Thesynthesisofopen-fiameworkmetalphosphateshasbeenasubjectofintenseresearchowingtotheirinterestingstructuralchemistryandpotentialapplicationsasionexchangers,catalystsandadsorbents.Alargenumberofthesematerialsaresynthesizedinthepresenceoforganicaminesasstructure-directingagents.Recently,manyresearchactivitieshavefocusedonthesynthesisofinorganic-organichybridframeworks.Ascomparedwithinorganicligands,theadvantageofusingorganicmultidentateligandsistheefficacyofrationaldesignofcrystallinesolidsthroughtheircoordinatingpropensitiesandgeometries.

简介：Thesynthesisandphasebehaviorofaseriesof4’-alkyloxy-4-hydroxybiphenylswerediscribed.Theeffectsofreactionconditionsontheyieldsofproductswereinvestigated.Thecharacterizationsofthermotropicliquidcrystallineproductsforthetypeandthermalpropertiesarediscussedthroughtheuseofdifferentialscanningcalorimetry,polarizingmicroscopy.

简介：Reactionsofthe6-hydroxy-thiopyrano[3,4-c]pyridine-5-carbonitrilederivative1withα-halo-carbonylcompoundsgavetheortho-substitutedintermediates2a-cwhichwereconvertedintofuro[2,3-b]thiopyrano[4,3-d]pyridines3a-cbyfusionofafuranmoietyunderbasicconditions.Furthercyclizationof3a-cledtoafusionofapyrimidinering,yieldingthetetracyclicproducts6,7and8.Inaddition,condensationof6withvariousaromaticaldehydesaffordedthecorrespondingimines9a,b.Mannichreactionof7gaveproducts10a,b.

简介：Thestructureofpolyimidefrom1,4-bis(3’,4’-dicarboxyphenoxy)benzeneand4,4’-oxydianilinefilmspecimensbeforeandafterhotstretchinghasbeeninvestigatedbyWAXD,DSCandFTIR.AsevidencedbyboththeWAXDandDSCresults,itcouldbebelievedthatstraininducedcrystallizationdidtakeplaceafterhotstretching.Meanwhile,shiftingpositionandsplittingofsomebandpeaksexistedontheFTIRspectrogramswereexplainedintermsoftheclosepackingofchainsandthechangesofinter-molecularcharge-transferinteractionbetweenimidegroupsandaromaticgroupsuponcrystallization.

简介：3,5,6,8-Tetrahydro-4H-thiopyrano[4′,3′:4,5]thieno[2,3-d]pyrimidin-4-ones(7)weresynthesizedviathebasecatalyticreactionsofaminesorphenolswithcarbodiimides(5),whichwereobtainedfromtheaza-Wittigreactionsofiminophosphoranes(4)witharomaticisocyanates.

简介：Ｏｎ　△Ｉ＝４　Ｂｉｆｕｒｃａｔｉｏｎ　ＰｈｅｎｏｍｅｎａＯｎ△Ｉ＝４ＢｉｆｕｒｃａｔｉｏｎＰｈｅｎｏｍｅｎａ￥ＺｈａｎｇＪｉｎｇｙｅ；ＹａｎｇＳｕｎａｎｄＭｉｋｅＧｕｉｄｒｙＴｈｅｅｘｐｅｒｉｍｅｎｔｓ－ｂｙｔｈｅｎｅｗ７－－ｒａｙｄｅｔｅｃｔｏｒ...

简介：我们介绍自发的对称碎在Pati之间的acouplingbetween的顺序—Salam和电镀物品弱对称苏(4)_(PS)直接X苏(4)_(EW)可伸缩以便在宏大统一精力在联合常数之中建立一种算术地一致的关系。与减已知的夸克和雷普顿的雷普顿量数字那里的酒吧的价值，由传递includingright的中微子，我们能在直到电磁的U(1)_(他们)的层次放大的不同精力发现混合角度关系。

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简介：Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit

简介：Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.

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简介：让x：Mn是有非零主管弯曲的脐的免费hypersurface。然后，x与Laguerre公制的g被联系，Laguerre张肌\mathbbL\mathbb{L}，Laguerre形式C，和一个Laguerre秒基础形成\mathbbB\mathbb{B}它是在Laguerre下面的x的invariants转变组。如果它的Laguerre形式消失，hypersurfacex被称为Laguerreisoparametric并且\mathbbB\mathbb的特征值{B}是不变的。在这份报纸，我们在4分类所有Laguerreisoparametrichypersurfaces。

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简介：ThedevelopmentoftheGEANT4applicationforALICEsimulationwithinthealiRootframeworkisdescribed.TheG3toG4approachadoptedbyALICEcollaborationisexplained.Theoverviewofthedesign,presentimplementationandfunctionalityispresentedandtheremainingproblemsarediscussed.