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  • 简介:Itiswellknownthatsurfaceroughnesshasaveryimportanteffectonsuperhydrophobicity.TheWenzelandCassie-Baxtermodels,whichcorrespondtothehomogeneousandheterogeneouswettingrespectively,arecurrentlyprimaryinstructionsfordesigningsuperhydrophobicsurfaces.However,theparticulardropshapethatadropexhibitsmightdependonhowitisformed.Awaterdropcanoccupymultipleequilibriumstates,whichrelatetodifferentlocalminimalenergy.Insomecases,bothequilibriumstatescanevenco-existonasamesubstrate.Thustheapparentcontactanglesmayvaryandhavedifferentvalues.WediscusshowtheWenzelandCassie-Baxterequationsdeterminethehomogeneousandheterogeneouswettingtheoretically.Contactangleanalysisonhierarchicalsurfacestructureandcontactanglehysteresishasbeenputspecificattention.Inparticular,westudytheenergybarrieroftransitionfromCassie-BaxterstatetoWenzelstate,basedonexistingachievementbypreviousresearchers,todeterminethepossibilityofthetransitionandhowitcanbeinterpreted.Ithasbeendemonstratedthatsurfaceroughnessandgeometrywillinfluencetheenergyrequiredforadroptogetintoequilibrium,nomatteritishomogeneousorheterogeneouswetting.

  • 标签: SUPERHYDROPHOBIC surface contact ANGLE WETTING TRANSITION
  • 简介:Whencharacterizingflowsinminiaturizedchannels,thedeterminationofthedynamiccontactangleisimportant.Bymeasuringthedynamiccontactangle,theflowpropertiesoftheflowingliquidandtheeffectofmaterialpropertiesontheflowcanbecharacterized.Amachinevisionbasedsystemtomeasurethecontactangleoffrontorrearmenisciofamovingliquidplugisdescribedinthisarticle.Inthisresearch,transparentflowchannelsfabricatedonthermoplasticpolymerandsealedwithanadhesivetapeareused.Thetransparencyofthechannelsenablesimagebasedmonitoringandmeasurementofflowvariables,includingthedynamiccontactangle.Itisshownthatthedynamicanglecanbemeasuredfromaliquidflowinachannelusingtheimagebasedmeasurementsystem.AnimageprocessingalgorithmhasbeendevelopedinaMATLAB?environment.Im-agesaretakenusingaCCDcameraandthechannelsareilluminatedusingacustommaderinglight.Twofittingmethods,acircleandtwoparabolas,areexperimentedandtheresultsarecomparedinthemeasurementofthedynamiccontactangles.

  • 标签: 数字图像处理 机器视觉 微观射流技术 图像测量 微通道