简介:Itiswellknownthatsurfaceroughnesshasaveryimportanteffectonsuperhydrophobicity.TheWenzelandCassie-Baxtermodels,whichcorrespondtothehomogeneousandheterogeneouswettingrespectively,arecurrentlyprimaryinstructionsfordesigningsuperhydrophobicsurfaces.However,theparticulardropshapethatadropexhibitsmightdependonhowitisformed.Awaterdropcanoccupymultipleequilibriumstates,whichrelatetodifferentlocalminimalenergy.Insomecases,bothequilibriumstatescanevenco-existonasamesubstrate.Thustheapparentcontactanglesmayvaryandhavedifferentvalues.WediscusshowtheWenzelandCassie-Baxterequationsdeterminethehomogeneousandheterogeneouswettingtheoretically.Contactangleanalysisonhierarchicalsurfacestructureandcontactanglehysteresishasbeenputspecificattention.Inparticular,westudytheenergybarrieroftransitionfromCassie-BaxterstatetoWenzelstate,basedonexistingachievementbypreviousresearchers,todeterminethepossibilityofthetransitionandhowitcanbeinterpreted.Ithasbeendemonstratedthatsurfaceroughnessandgeometrywillinfluencetheenergyrequiredforadroptogetintoequilibrium,nomatteritishomogeneousorheterogeneouswetting.
简介:Biologicaltinystructureshavebeenobservedonmanykindsofsurfacessuchaslotusleavesandinsectwings,whichenhancethehydrophobicityofthenaturalsurfacesandplayaroleofself-cleaning.Wepresentedthefabricationtechnologyofasuperhydrophobicsurfaceusinghighenergyionbeam.Artificialinsectwingsthatmimicthemorphologyandthesuperhydrophobocityofcicada’swingsweresuccessfullyfabricatedusingargonandoxygenionbeamtreatmentonapolytetrafluoroethylene(PTFE)film.Thewingstructuresweresupportedbycarbon/epoxyfibersasartificialflexibleveinsthatwerebondedthroughanautoclaveprocess.Themorphologyofthefabricatedsurfacebearsastrongresemblancetothewingsurfaceofacicada,withcontactanglesgreaterthan160°,whichcouldbesustainedformorethantwomonths.
简介:Thisstudyaimsatthemechanismofdragreductioninturbulentboundarylayer(TBL)withsuperhydrophobicsurface.Comparingthetime-resolvedparticleimagevelocimetry(TRPIV)measurementresultswiththatofhydrophilicsurface,thedragreductionrateoverasuperhydrophobicsurfaceisapproximately10%.Toinvestigatethecharacteristicsofcoherentstructureinadrag-reducedTBLwithsuperhydrophobicsurface,amodifiedmulti-scalespatiallocally-averagedstructurefunctionisproposedfordetectingcoherentstructure.Theconditionalsamplingandspatialphase-lockaveragemethodsareemployedtoobtainthetopologyofphysicalquantitieslikethevelocityfluctuation,spanwisevorticity,andReynoldsstressduringejectandsweepprocess.Theresultsindicatethatthesuppressionofcoherentstructureburstinthenear-wallregionisthekeymechanisminreducingtheskinfrictiondragforTBLoversuperhydrophobicsurface.
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简介:微弧的氧化(毛)/zinc硬脂酸盐(ZnSA)合成涂层经由毛与superhydrophobicZnSA的电极淀积处理并且随后的封上被制作。表面形态学,化学作文和涂层的腐蚀抵抗用扫描电子显微镜学的地排放被调查,Fourier变换红外线,X光检查衍射并且电气化学并且氢进化大小。结果显示毛涂层被下列superhydrophobicZnSA涂层高效地封上。MAO/ZnSA合成涂层显著地由于它的superhydrophobic功能提高了Mg合金Mg-4Li-1Ca的腐蚀抵抗。另外,腐蚀机制为合成涂层被建议并且讨论。