简介:有效的氨兆兆赫(THz)洞激光试验性地被报导。不同于象洞couplers和独立网孔couplers那样的过去的设计计划,在我们的系统,输入和输出couplers被扔镍制作ZnSe和高抵抗力的硅底层上的电容的金属性的网孔。因此couplers能不仅作为一个F-P振荡器被构造而且能是封上更容易执行排列的调整与的窗户被使用。为了提高THz激光,输出精力和光子变换效率,象泵紧张那样的主导的因素和煤气的压力试验性地被调查。最后,有在1.09kPa操作的90m波长(3.33THz)的氨激光的1.35mJ兆兆赫放射与9R(16)由402mJ茶CO2激光抽了线被产生,并且6.5%的光子变换效率被完成。
简介:Theexperimentalandnumericalinvestigationsoftheflowwithreactionoftwogases:hydrogenchlorideHClandammoniaNH3wereperformed.ThearticlecontainsdescriptionofthevisualisationmethodoftheformationandflowofparticlesofammoniachlorideNH4Cl.Analysesofmeanconcentrationandvarianceofconcentrationfluctuationsofdispersedphasewereperformedfordifferentoutputsofgases.Numericalcalculationswereperformedforanalysedphenomenon.Bothnumericalandvisualisationresutswerematchedandcompared.
简介:Electrolysisofammoniainalkalineelectrolytesolutionwasappliedfortheproductionofhydrogen.BothPt-loadedNifoamandPt-IrloadedNifoamelectrodeswerepreparedbyelectrodepositionandservedasanodeandcathodeinammoniaelectrolyticcell,respectively.TheelectrochemicalbehaviorsofammoniainKOHsolutionwereindividuallyinvestigatedviacyclicvoltammetryonthreeelectrodes,i.e.bareNifoamelectrode,Pt-loadedNifoamelectrodeandPt-IrloadedNifoamelectrode.ThemorphologyandcompositionofthepreparedNifoamelectrodewereanalyzedbyscanningelectronmicroscopy(SEM)andX-raydiffraction(XRD).Effectsoftheconcentrationofelectrolytesolutionandtemperatureofelectrolyticcellontheelectrolysisreactionwereexaminedinordertoenhancetheefficiencyofammoniaelectrolysis.Thecompetitionofammoniaelectrolysisandwaterelectrolysisinthesamealkalinesolutionwasfirstlyproposedtoexplainthechangesofcellvoltagewiththeelectrolysisproceeding.Atvaryingcurrentdensities,differentcellvoltagescouldbeobtainedfromgalvanostaticcurves.Thelowcellvoltageof0.58V,whichislessthanthepracticalelectrolysisvoltageofwater(1.6V),canbeobtainedatacurrentdensityof2.5mA/cm2.Basedonsomeexperimentalparameters,suchastheappliedcurrent,theresultingcellvoltageandoutputofhydrogengas,thepowerconsumptionpergramofH2producedcanbeestimated.
简介:WiththerisingofIGCCandthesecondgenerationPFBC-CC,andwiththedevelopmentoftech-nologyofstagedcombustiontoloweremissionofNOx,thedesulfurizationefficiencyunderreducingatmosphereisraised.Inthispaper,withtheapplicationofthefly-ashrecycleandtwo-stagecombustiontechnologiesinafluidizedbedcombustor,thedesulfurizationtestunderreducingatmosphereisdescribed.Meanwhile,ammoniainjectiontestwasalsoconducted.Resultsshowthatdesulfurizationunderreducingatmospherehashigherefficiency,andamooniainjectiondenitrificationeffectisveryperfect.
简介:Aseriesofhighsurfaceareagraphiticcarbonmaterials(HSGCs)werepreparedbyball-millingmethod.EffectofthegraphiticdegreeofHSGCsonthecatalyticperformanceofBa-Ru-K/HSGC-x(xistheball-millingtimeinhour)catalystswasstudiedusingammoniasynthesisasaprobereaction.ThegraphiticdegreeandporestructureofHSGC-xsupportscouldbesuccessfullytunedviathevariationofball-millingtime.RunanoparticlesofdifferentBa-Ru-K/HSGC-xcatalystsarehomogeneouslydistributedonthesupportswiththeparticlesizesrangingfrom1.6to2.0nm.ThegraphiticdegreeofthesupportiscloselyrelatedtoitsfacileelectrontransfercapabilityandsoplaysanimportantroleinimprovingtheintrinsiccatalyticperformanceofBa-Ru-K/HSGC-xcatalyst.更多还原
简介:Core-shellstructurednanosphereswithmesoporoussilicashellandNicore(denotedasNi@meso-SiO2)arepreparedthroughathree-stepprocess.MonodispersedNiprecursorsarefirstprepared,andthencoatedwithmesoporousSiO2.FinalNi@meso-SiO2spheresareobtainedaftercalcination.TheproductsarecharacterizedbyX-raypowderdiffraction,transmissionelectronmicroscopyandN2adsorption-desorptionmethods.Thesesphereshaveahighsurfaceareaandarewelldispersedinwater,showingahighcatalyticactivitywithaTOFvalueof18.5,andoutstandingstabilityinhydrolyticdehydrogenationofammoniaboraneatroomtemperature.
简介:Toimprovetheinitialcoulombicefficiencyandbulkdensityoforderedmesoporouscarbons,activeFe2O3nanoparticleswereintroducedintotubularmesoporechannelsofCMK-5carbon,whichpossesseshighspecificsurfacearea(>1700m2g-1)andlargeporevolume(>1.8cm3g-1).FineFe2O3nanoparticleswithsizesintherangeof57nmwerehighlyandhomogenouslyencapsulatedintoCMK-5matrixthroughammonia-treatmentandsubsequentpyrolysismethod.TheFe2O3loadingwascarefullytailoredanddesignedtowarrantahighFe2O3contentandadequatebufferspaceforimprovingtheelectrochemicalperformance.Inparticular,suchFe2O3andmesoporouscarboncompositewith47wt%loadingexhibitsaconsiderablystablecycleperformance(683mAhg-1after100cycles,99%capacityretentionagainstthatofthesecondcycle)aswellasgoodratecapability.Thefabricationstrategycaneffectivelysolvethedrawbackofsinglematerial,andachieveahigh-performancelithiumelectrodematerial.