简介:StatisticalMechanicsModelofLiquidBinaryAiloyFanChengcai,WangJianandLiWenchao(樊成才)(王俭)(UniversityofScienceandTechnologyBeijing...
简介:通过化学沉积法制备Ni-P、Ni-Mo-P单镀层以及与其成分相同的Ni-P/Ni-Mo-P双镀层。采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10%HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系。结果表明:Ni-P单镀层和Ni-P/Ni-Mo-P双镀层表现为残余压应力,分别为241和206MPa;Ni-Mo-P单镀层呈现出257MPa的残余拉应力。残余压应力阻止镀层中孔洞的生长,保护镀层的完整性。Ni-P/Ni-Mo-P双镀层比它们的单镀层具有更好的耐蚀性。此外,镀层的应力状态影响其腐蚀形式。
简介:InordertocontrolthesizeanddistributionofthehighconductiveFe2PinLiFePO4/Fe2Pcomposite,twodifferentcoolingrates(Fast:15℃·min-1,Slow:2℃·min-1)wereemployedaftermechanicalalloying.Thedischargecapacityofthefastcooledwas83mAh·g-1andtheslowcooled121mAh·g-1.TheparticlesizeofthesynthesizedpowderwasexaminedbytransmissionelectronmicroscopyanddistributionofFe2Pwascharacterizedusingscanningelectronmicroscopy(SEM).Inaddition,two-stepheattreatmentwascarriedoutforbetterdistributionofFe2P.X-raydiffraction(XRD)andRietveldrefinementrevealthatLiFePO4/Fe2Pcompositeconsistsof95.77%LiFePO4and4.33%ofFe2P.
简介:为描述铁粉末的压缩过程的一个新模型基于连续统假设和椭圆的收益标准被建议。模仿densification行为,组成的模型在马克被实现计算机节目。为在负担和排水量之间的关系,不同模型被比较,在组成的方程的参数的影响借助于模拟和实验是坚定的。balancer的密度分发被测量并且模仿。参数采用了的结果表演为负担排水量曲线起一个修正作用,并且与另外的模型相比,现在的模型主要由于不同参数A和B在压缩进程的以后的阶段与试验性的数据更好适合。接触表面上的磨擦在细工品的大变丑下面贡献不同类的密度分发。在模拟和试验性的数据之间的比较显示这个模型能被用来精确并且有效地预言粉末协议过程。
简介:ThehotdeformationbehaviorofTC18alloyatstrainratesrangingfrom1910-4to1910-2s-1andtemperaturesrangingfrom25to800°CwasstudiedusingaWDW-300electronicuniversaltestingmachine.Therelationshipsbetweentruestressandtruestrainshowthatflowstressdecreaseswiththeincreaseoftemperatureandincreasesasstrainrateincreases.Theeffectofstrainrateontheflowstressbecomespronouncedathighertemperatures.Atroomtemperature,theriverpatterncharacteristicofbrittlefractureandthedimplepatterntypicalofductilefracturearefoundtoexistindifferentregionsoffracturesurfacesofthesamples.AnimprovedconstitutiverelationshipisproposedtoaccuratelydescribetheflowstressofTC18byconsideringtheeffectofstrain.Andamicroscopicmodelisalsodeducedwhichcanlinkthephysicalmechanismstothemacroscopicexperimentalresults.Agoodagreementisobtainedbetweenthepredictionsofthemicroscopicmodelandtheresultsofthemacroscopicexperiment.
简介:为了精确预测非理想条件下稀土金属溶剂萃取的平衡分配比,研究了溶于ShellsolD70中的P507溶剂对盐酸液中钇(Ⅲ)和铕(Ⅲ)的萃取平衡,建立化学基模型,并通过非线性最小二乘法确定萃取平衡常数。所建模型涉及了在低酸度区的离子交换反应和高酸度区的溶剂化萃取反应;模型还考虑了稀土金属与Cl-的配位反应,并用萃取剂的有效浓度代替[(HR)2],进而分别对水相和有机相(HR)2的非理想性加以修正。对稀土单元体系,在较宽的初始浓度范围内(稀土浓度最高至0.1mol/L,盐酸浓度0.07-3.00mol/L,萃取剂浓度0.25-1.00mol/L),由模型计算的稀土分配比与实验测得的数据吻合良好,验证了模型的有效性。对于稀土二元体系,该模型能以良好的精度对平衡分配比进行工程预测。
简介:Thehotdeformationbehaviourof7075aluminiumalloyreinforcedwith10%ofSiCparticleswasstudiedbyemployingboth'processingmaps'andmicrostructuralobservations.Thecompositewascharacterizedbyemployingopticalmicroscopetoevaluatethemicrostructuraltransformationsandinstabilityphenomena.Thematerialinvestigatedwasdeformedbycompressioninthetemperatureandstrainraterangesof300-500℃and0.001-1.0s-1,respectively.Thedeformationefficiencywascalculatedbystrainratesensitivity(m)valuesobtainedbyhotcompressiontests.Thepowerdissipationefficiencyandinstabilityparameterswereevaluatedandprocessingmapswereconstructedforstrainof0.5.Theoptimumdomainsandinstabilityzonewereobtainedforthecomposites.Theoptimumprocessingconditionsareobtainedinthestrainraterangeof0.1-0.9s-1andtemperaturerangeof390-440℃withtheefficiencyof30%.
简介:55%SiCp/A356(体积部分)以铜锌金焊接在把Zn-Al合金用作filler金属的空中的composites被调查。在以铜锌金焊接的过程期间,超声的颤动为结合被用于样品,进在基础材料的矩阵合金的filler金属的重要溶解发生了。当以铜锌金焊接的温度被增加,在基础材料的部分融化层的厚度增加了。原文如此,在基础材料的部分融化层的粒子在超声的行动下面被变成液体filler,有同类地分布式的加强的一张契约在团结以后被获得。体积部分原文如此,在契约的粒子能被改变以铜锌金焊接的温度改变。最大值原文如此,契约材料的粒子体积部分在500的以铜锌金焊接的温度到达了37%?????????????敷摬摥??
简介:AmorphousNi–PcoatingwasplatedonAZ31magnesiumalloyviatheelectrolessplatingtechnique,andtheplatedalloywassubsequentlyannealed.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),anddifferentialscanningcalorimetry(DSC)wereusedtocharacterizethecoating.Theresultsshowthatthehardnessofthecoatingismuchhigherthanthatofbaremagnesiumalloy,whichfurtherincreasesaftercrystallization.Theelectrochemicalpolarizationandsaltspraytestsshowthatthecoatingexhibitsamuchhighercorrosionresistancethanthatofthebaremagnesiumalloy.Moreover,thecrystallizedcoatingstillexhibitsamuchstrongercorrosionresistancethanthatofthebaremagnesiumalloy,althoughitscorrosionresistanceislowerthanthatoftheas-platedone.