简介:Thebovinehydroxyapatite(BHA)wasappliedtopreparebiologicaltissueengineeringscaffoldsbythemethodofextrusionfreeforming.Toachievethisgoal,BHAwereaddedtosodiumalginate(SA)solutiontoformaslurrysysteminappropriateproportion.Theresultingmixtureswerefabricatedtobeakindofcontrollableandporousscaffoldsfollowedwithcross-linkingin5%calciumchloride(CaCl2)solutionfor24h.Afterthat,thescaffoldsweresinteredinairat1000,1100,1200and1300℃for5h.Scanningelectronmicroscopy(SEM)andX-raydiffraction(XRD)studieswereperformedonthescaffoldstoanalyzeitsmicrostructureandconstituent.Toexploretheeffectofsinteringtemperatureonscaffolds,thecompressivestrength,volumeshrinkageandwaterabsorptivityofBHA-SAcompositescaffoldsaftersinteringwereinvestigated.TheresearchtestsindicatedthefeasibilityofapplyingBHApowderto3Dprinting.Besides,thescaffoldssinteredinarespectivelylowertemperaturepossessmuchmoreporesandperformedhigherwaterabsorptivity,whichmeansbettercellularaffinity.Andscaffoldssinteredbetween1100and1200℃presentshighercompressivestrength.
简介:Amathematicalmodelforthethree-dimensionalsimulationoffreedendriticgrowthandmicrostructureevolutionwasdevelopedbasedonthegrowthmechanismofcrystalgrainsandbasictransferequationssuchasheat,massandmomentumtransferequations.Manyfactorsincludingconstitutionalundercooling,curvatureundercoolingandanisotropy,whichhadvitalinfluencesonthemicrostructureevolution,wereconsideredinthemodel.SimulatedresultsshowedthatfinalmicrostructuralpatternsandfreedendriticgrowthcouldbepredictedreasonablyandcalculatedresultswerecoincidentwithexperimentalThesimulatedresultsoffreedendriticgrowthindicatedthatthestrengthofanisotropyhassignificanteffectsonfreedendriticgrowth,dendriteprofile,microsoluteandtemperaturedistribution.Thedendriticgrainprofileswithfully-grownparallelsecondaryarmtendtobeformedattheintensiveanisotropy,whilenearoctahedralgrainprofileswithsmallprotuberancesofsurfaceatlowstrengthofanisotropy.Thesimulatedresultsoffreedendriticgrowthalsoindicatedthattherearesmallmoltenpoolsleftininterdendriticareas.Thisishelpfultounderstandthefundamentaloftheformationofmicrostructurerelateddefectssuchasmicrosegregationandmicroporosity.
简介:TheRamanspectraof3%(molefraction)Y2O3-ZrO2(3Y)areobtainedatdifferenttemperaturefrom77Kto853K.Theresultsshowthat260cm-1Egand460cm-1Egmodesonthespectrashifttowardlowerwavenumberwiththeincreaseoftemperature;meanwhile,thecontinuityoftheHalfWidthatHalfMaximum(HWHM)andwavenumber(frequency)ofRamanbandsarebrokenandt-phaseonlypartiallytransformstom-phaseat523K.Basedontheexperimentalresults,thispaperdiscussesthet-phaselatticevibrationof3YandpresentstheimagesofvibrationdisplacementofsixRaman-activemodesfort-phaseofZrO2.TheanalysisindicatesthattherearediversitiesexistinginthedisplacementoftheatomicvibrationofRaman-activemodesbecauseoftheirdifferentsymmetriesatvarioustemperature,whichleadstothedifferentchangetendenciesofRamanbands.Furthermore,theabruptchangesofsomeRaman-activemodesindicatingtheatomicdisplacementareassumedtobethecondensationsofphononmodesinthet→mphasetransition.
简介:Ahumanfacewithcomplex3Dstructureismachinedwithamodifiedfix-lengthcompensationmethodinthispaper.ThefastdevelopmentofMEMS(MicroElectromechanicalSystems)hasstronglyenhancedtheapplicationofnewharderworkmaterials.Asalowcost,flexible,goodrepeatablemachiningprocesswithnegligibleprocessforces,micro-EDMmillingiswellsuitedforfreeformmetallicmicrostructures.Amajorprobleminmicro-EDMmillingofcomplex3Dstructureistheelectrodewear.AnewCAMsystembasedontheUGsoftwareplatformisdevelopedinordertogetgoodaccuracyandhigherefficiency.Acorrectioncoefficientisintroducedanddeducedforthemodifiedfix-lengthcompensationmethod.Usingthismethodahumanfacewithcomplex3Dstricterismachinedsuccessfullybymicro-EDMmilling.
简介:Basedonrigid-plasticfiniteelementmethod,askewrollingprocessofsteppedpartissimulated.Consideringnodesavingandeffectiveremeshing,thetetrahedronsolidelementsareusedtodiscreteworkpiece.Theworkpiecematerialadoptsrigid-plasticmodel,wheretheflowstressisfunctionofeffectivestrain,effectivestrainrateandtemperature.Thethermomechanicalcouplingisconsideredinthesimulation.Tomodelthespinningworkpieceundergoingplasticdeformation,anovelsolutionispresentedandappliedinthispaper.Thestressstateintheworkpieceandformingcharacteristicofskewrollingareanalyzed.Theformingload,includingrollertorqueandforcesinthreedirectionsarepredicted.Theaboveanalysesarehelpfultounderstandingofformingmechanismsandimprovingofprocessanddiedesign.
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