Calcium Hydroxytitanate in Bayer Digestion Process

(整期优先)网络出版时间:1989-01-11
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CalciumhydroxytitanateformedinBayerdigestionprocessofchinesediasporicbauxitewasstudied.InterplanarspacingsofcalciumhydroxytitanatecrystalweredeterminedbyXRDanalysis.Onlyoneendothermicpeakoccursat550~560℃ontheDTAcurveofthiscompound.IRspectrometrystudyhasrevealedthathydroxyldoesexistincalciumhydroxytitanateinsteadofcrystalwater.ObservationunderSEMhasindicatedthatitscrystalgrainsareintheshapeofregularhexagonalplateswith2~8μminedgelengthandlessthan1μminthickness.TheinfluencesofvariousdigestionconditionsontheformationandtransformationofcalciumhydroxytitanateandotherCa-Ti-containingcompounds,suchaslimeaddition;contentanddistributionstateofTiO2inbauxite;digestiontemperatureandretentiontime,werefurtherstudied.