Distribution and geochemical significance of trace elements in shale rocks and their residual kerogens

(整期优先)网络出版时间:2018-06-16
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Thereisadearthofinformationaboutthedistributionoftraceelementsinkerogenfromshalerocksdespiteseveralreportsontraceelementcompositioninmanyshalesamples.Inthisstudy,traceelementsinshalerocksandtheirresidualkerogensweredeterminedbyinductivelycoupledplasma–massspectrometry.Theresultsfromthisstudyshowredox-sensitiveelementsrelativelyconcentratedinthekerogensascomparedtotheshales.Thismaybeprimarilyduetotheadsorptionandcomplexationabilityofkerogen,whichenablesenrichmentinNi,Co,Cu,andZn.Fortherareearthelements(REEs),distinctdistributioncharacteristicswereobservedforshalesdominatedbyterrigenousmineralsandtheirkerogencounterparts.However,shaleswithlessinputofterrigenousmineralsshowedsimilarREEdistributionpatternstotheirresidualkerogen.ItisspeculatedthatthedistributionpatternsoftheREEsinshalesandkerogensmaybesourcerelated.