The relationship between apparent equilibrium temperature and closure temperature with application to oxygen isotope geospeedometry

(整期优先)网络出版时间:2014-02-12
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Oxygenisotopefractionationbetweencoexistingmineralsinslowlycooledrocksconveysinformationabouttheircoolinghistory.Byusingthefastgrainboundary(FGB)modeltosimulateclosed-systemdiffusiveexchangeofoxygenisotopesbetweencoexistingminerals,Ishowthattheapparentequilibriumtemperatures(Tae)bythemineralpairwiththelargestisotopicfractionation(PLIF)alwaysliesbetweentheclosuretemperatures(Tc)ofthosetwominerals.Therefore,whentherateofoxygendiffusionandhenceTcforthePLIFchancetobecomparable(suchasinthecaseofquartzandmagnetite),TaewillserveasagoodapproximationofTcregardlessofvariationinmineralproportions.ThespecialtyofthePLIFinconstrainingTaewithintheirTcrangecanbegeneralizedtootherstableisotopesystemsandelementpartitioning.ByapproximatingTcwithTaeandinvertingDodson'sequation,thecoolingrateofplutonicormetamorphicrockscanbeinferred.