摘要
Theinfluencingfactorsforliquidphasecatalyticoxidationofminegastomethanol(informofCH3COOCH3)arestudiedusingtheself-establishedexperimentalapparatus.TheresultsshowthatCH3COOCH3(targetproduct)isobtainedbyusingCH3COOHasreactionsolvent,andtheyieldoftargetproductincreaseswiththeincreasingofreactiontemperature,gaspressureandreactiontime.Intheminegas-Pd(OAc)2-CH3COOHsystem,theyieldofCH3COOCH3increaseswiththeincreasingofadditionofPd(OAc)2whichisredoxcatalystforminegasconversion.TheyieldofCH3COOCH3willbegreatlyimprovedbycompositeadditionaloxidantwhichisobtainedbyequimolarmixofp-benzoquinonewithNO2.
出版日期
2014年02月12日(中国期刊网平台首次上网日期,不代表论文的发表时间)