学科分类
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271 个结果
  • 简介:Mg2Ni氢存储合金的电气化学的性质上的镍涂层的效果在这份报纸被介绍。X光检查衍射(XRD)和扫描电子显微镜(SEM)技术被采用检验赤裸、Ni涂的Mg2Ni合金的水晶结构和表面形态学。合金的电气化学的性质被周期的voltammetry(CV)和电气化学的阻抗光谱学(EIS)描绘。结果显示出那Ni涂层不仅减少费用转移抵抗,而且减少为Mg2Ni合金的H原子散开抵抗。Ni涂层有效地改进了分泌物能力,这也被发现,但是减少同样综合的Ni涂的Mg2Ni合金的骑车的表演。分泌物电流在同样综合的Ni涂的Mg2Ni合金的骑车的表演上有大影响。

  • 标签: 氢贮存合金 化学覆盖层 循环伏安法 电气化学
  • 简介:Carbon-coatedlithiummanganesesilicate(Li2MnSiO4/C)nanoparticlesweresynthesizedbypolyolprocess.X-raydiffraction(XRD)patternsoftheobtainedmaterialsexhibitagoodfitwiththatoftheLi2MnSiO4phase.Fieldemissionscanningelectronmicroscopy(FESEM)imagesoftheobtainedsamplesshowthattheparticlesizeisonlytensofnanometers.Thehighresolutiontransmissionelectronmicroscopy(HRTEM)analysisshowsthattheLi2MnSiO4nanoparticlesaresurroundedbyaverythinfilmofamorphouscarbon.Thecompositepreparedthroughpolyolprocessshowsgoodperformanceascathodematerialsinlithiumcellsatroomtemperature.ThechargecapacityoftheLi2MnSiO4/Csamplesis219mAh/g(about1.3Li+perunitformulaextracted),andthedischargecapacityis132mAh/g(about0.8Li+perunitformulainserted)inthefirstcycleinthevoltagerangeof1.5-4.8V.Agoodcapacitycyclingmaintenanceof81.8%after10cycleswasobtained.

  • 标签: 电化学性能 纳米粒子 多元醇法 合成过程 场发射扫描电子显微镜 高分辨透射电子显微镜
  • 简介:Theeffectsoftwopost-weldheattreatmentprocessesonthemicrostructureandfatiguepropertiesoftheelectronbeamweldedjointsof30CrMnSiNi2Asteelwerestudied.Electronbeamlocalpost-weldheattreatment(EBLPWHT),inavacuumchamber,immediatelyafterweldingandatraditionalfurnacewholepost-weldheattreatment(FWPWHT)wereaccepted.Theexperimentalresultsshowthat,afterEBLPWHT,themainmicrostructureofweldischangedfromcoarseacicularmartensiteintolathmartensite,andbasemetalischangedfromferriteandperliteintoupperbainiteandresidualaustenite,howeverthemicrostructuresofdifferentzonesofjointsinFWPWHTconditionsaretemperedsorbite.Thefatiguecrackgrowthrateda/dNofweldsandbasemetalarenotobviouslychangedamongEBLPWHT,FWPWHTtestandas-welded(AW)test,asthemechanicalpropertiesofmaterialshaveacertainbutnotlargeeffectontheda/dNofweldedjoints.TheresistancetonearthresholdfatiguecrackgrowthdataofweldedjointscanbelargelyimprovedbyEBLPWHTanditisrelatedtomicrostructureandcrackclosureeffect.

  • 标签: 微观结构 疲劳裂缝 电子束焊接 合金钢 局部加热处理
  • 简介:CuO-CoO-MnO/SiO2nanocompositeaerogels被经由大音阶的第五音胶化过程和乙醇supercritical弄干技术作为先锋把tetraethylorthosilicate(TEOS)用作Cu,公司和Mn醋酸盐的Si来源,和水的答案准备。gelatination机制被原子磁性的回声(NMR)和X光检查光电子光谱学(XPS)调查。CuO-CoO-MnO/SiO2nanocompositeaerogels的微观结构和作文被扫描电子显微镜学(FE-SEM)的地排放描绘,传播电子显微镜学(TEM),电子散光谱学(版本)和XPS。特定的表面区域,毛孔尺寸和nanocompositeaerogels的毛孔尺寸分发被Brunauer-Emmett-Teller(赌注)方法决定。产品被煤气的层析(GC)分析。结果证明CuO-CoO-MnO/SiO2nanocompositeaerogels是多孔的,与10150nm,216nm的毛孔尺寸分布,7.68nm的一种平均毛孔尺寸,和664.4695.8m2/g的一个特定的表面区域的粒子尺寸分布。在nanocompositeaerogels的转变金属的臼齿的部分是0.71%-13.77%。这种结构是有利的不仅增加装载催化剂,而且作为cocatalysts充分利用转变金属氧化物的效果;CuO-CoO-MnO/SiO2nanocompositeaerogels能在diphenyl碳酸盐的更安全、环境友好的合成和催化作用的另外的地被用作一个新奇催化剂搬运人。

  • 标签: 纳米复合材料 复合气凝胶 催化剂载体 X射线光电子能谱 制备 过渡金属氧化物
  • 简介:TheCurietemperatureof(Nd1-xPrx)2Fe14CoyBcompounds(x=0,0.2,…,1.0andy=O,2,4,6,14)hasbeendeterminedwithACinitialsusceptibilitymeasurement.ItwasfoundthatthevariationsofCurietempera-turewithxisnotlinearfory=0and14,whereasitislinearforothervaluesofy.Thelatticeconstantsof(Nd1-xPrx)2Fet14BweredeterminedbyusingX-raydiffraction.Thelatticeexpansionwasmostlyalongthecaxis,whereasthatalongthea-axisremainedpracticallyzeroforthewholeseries.ItissuggestedthatPratomsmayshowsitepreferenceinR2M14Bcompounds(M=FeorCo).DuetothesubstitutionofCoforFe.thetendencyofsitepreferenceofPrbecomeslesspronounced,whichmaybeattributedtothedecreaseofdiffer-enceofcrystalelectricfield(CEF)actingonthetworareearthsiteswiththeintroductionofCoorFe.Incon-trasttothatofthePratoms,thesitepreferenceofCoiu(Nd(1-x)Prx)2Fe(14-y)CoyBcompoundsdoesnotdependonthecompositionoftherareearthsublattice(R=NdorPr).

  • 标签: CURIE temperature Site PREFERENCE Rare earth-transition
  • 简介:AnewsimulationmodelofCO2short-circuitingtransferweldingmaybeemployedtodevelopanewpatternofweldingmachineandtopredictweldingprocessparameterstoobtaintheoptimumweldingtechnologyproperties.Inthispaper,anewsimulatingmodelisdevelopedaccordingtotheAWP(adaptingweldingphysicsprocess)waveformcontrolmethod.Goodagreementisshownbetweenthepredictedandexperimentallydeterminedresults.ThemodelwillmakeanimportantpromotioninthedevelopmentofCO2arcweldingtechnique.

  • 标签: 二氧化碳电弧焊 仿真 焊接参数 预测 短路传递
  • 简介:Anewhardfacingprocess,reactivebrazecoatingprocess(RBCC)wasstudied,and(TiC+Cr3C2)/FecompositecoatingswerepreparedbyRBCCusingcarbon,Cr3C2,iron,ferrochromiumandtitaniumpowderastherawmaterialsinvacuumbrazefurnace.TheresultsshowthatTiCisin-situsynthesizedinthecoatings.ThemethodsofintroducingCr3C2havegreateffectsonthedistributionofTiC.AddingCr3C2directlytotherawmaterialsforcoatings,fineTiCparticlesaggregateintodiscoidsparalleltothecoatingsurface,whereas,in-situsynthesizingCr3C2incoatings,theaggregationsofTiCarelumpish.Duringbrazecoating,Cr3C2particlesdirectlyaddeddissolveandprecipitatetobecomeneedle-shaped.Thecoatingshaveanevenandsmoothsurfaceandarecombinedwiththeirmildsteelsubstratesbyametallurgicalbonding.

  • 标签: 反应铜焊 电镀处理 复合层 微结构 碳化钛
  • 简介:本文主要研究了温度对X65管线钢腐蚀产物膜结构的影响规律。试验结果表明,腐蚀温度提高以后,管线钢表面CO2腐蚀产物膜的晶体形态没有发生明显变化,但是腐蚀产物膜的厚度则变小;同时腐蚀产物膜的硬度和弹性膜量都降低,这主要是因为Ca元素在FeCO3晶体中的含量增加,弱化了FeCO3的晶体结构。

  • 标签: CO2腐蚀 腐蚀产物膜 X65钢
  • 简介:PassivationofInsolubleAnodefromTi-baseAlloysinPreparationofElectrolyticMnO_YuZhengandYangShengshu(俞征)(杨生恕)DepartmentofChemis...

  • 标签: Ti-base alloy iusolublc ANODE EMD PASSIVATION
  • 简介:CO2气体保护焊具有效率高、成本低、应用范围广等优点,且随着CO2焊接设备、焊接材料和焊接工艺的研究发展,使CO2气体保护焊在矿用汽车工业中获得广泛应用。

  • 标签: CO2气体保护焊 矿用汽车 应用
  • 简介:Laserblankweldingisbecomingmoreandmoreimportantintheautomotiveindustryandthequalityoftheweldiscriticalforasuccessfulapplication.Afullyautomatedsolutionisrequiredtoinspectthequalityoftheblanks.ThispaperpresentsavisioninspectionsystemwithaCMOScamerawhichusesART2networktoinspectthedefectson-linetoobtainthegeometryandthequalityoftheweldseam.TheneuralnetworkART2hasthecapabilityofself-learningfromtheenvironment.Itcandistinguishthedefectsthathavebeenlearnedbeforeandgivenewoutputsfornewdefects.SoART2networkissuitableforweldqualityinspectioninlaserblankwelding.Additionally,aCO_2laserisusedfortheblankbutt-welding.

  • 标签: 激光拼焊扳 ART2 神经网络 在线质量检验
  • 简介:在Ce1-xDyx-ySryO2-δ体系中,研究了Dy和Se对总离子电导率的影响。在该体系中,使用麦芽糖和果胶作为有机前驱体,通过改性溶胶-凝胶工艺,在x=0.15,y=0.015,0.03和0.045的条件下,制备不同组分的导电体。采用X射线衍射谱的Rietveld拟合验证了导电体具有空间群Fm3m的立方结构。从SEM像可以看到具有明显晶界、相对均匀的晶粒。在150-500℃的温度范围和40Hz-1MHz的频率范围内,采用四探针交流阻抗法测量导电体的总离子电导率。与单掺杂的二氧化铈样品相比,Ce0.85Dy0.12Sr0.03O2-δ具有更高的电导率。

  • 标签: 电解液 Se-Dy掺杂 阻抗谱 电导率
  • 简介:HotcompressionbehaviorofTiC–Al2O3/AlcompositeswasstudiedusingtheGleeble-1500systematatemperaturerangeof300–550°Candatstrainraterangeof0.01–10.00s-1.TheassociatedstructuralchangeswerestudiedbyTEMobservations.Theresultsshowthatstressleveldecreaseswithdeformationtemperatureincreasingandstrainratedecreasing,whichcanberepresentedbyaZener–Hollomonparameterinanexponent-typeequationwithhotdeformationactivationenergyQof172.56kJ·mol-1.Dynamicrecoveryoccurseasilywhenstrainratesarelessthan10.00s-1.Dynamicrecrystallizationcanoccuratstrainrateof10.00s-1.

  • 标签: TiC–Al2O3/Al COMPOSITES HOT DEFORMATION Flow stres
  • 简介:NanocrystallineMg2Ni-typealloyswithnominalcompositionsofMg20Ni10–xCux(x=0,1,2,3,4,massfraction,%)weresynthesizedbyrapidquenchingtechnique.Themicrostructuresoftheas-castandquenchedalloyswerecharacterizedbyXRD,SEMandHRTEM.Theelectrochemicalhydrogenstorageperformancesweretestedbyanautomaticgalvanostaticsystem.ThehydridinganddehydridingkineticsofthealloysweremeasuredusinganautomaticallycontrolledSievertsapparatus.Theresultsshowthatalltheas-quenchedalloysholdthetypicalnanocrystallinestructureandtherapidquenchingdoesnotchangethemajorphaseMg2Ni.Therapidquenchingsignificantlyimprovestheelectrochemicalhydrogenstoragecapacityofthealloys,whereasitslightlyimpairsthecyclingstabilityofthealloys.Additionally,thehydrogenabsorptionanddesorptioncapacitiesofthealloyssignificantlyincreasewithrisingquenchingrate.

  • 标签: 合金成分 快淬技术 储氢特性 高分辨透射电子显微镜 纳米晶 MG2NI
  • 简介:这份报纸在极其细小的颗粒的WC-12%Co合金的磁性、机械的性质上处理codopedVC/Cr3C2和sintering温度的效果。结果证明在最佳的比例的做的VC/Cr3C2的synergistic行动提高坚硬和合金的横向的破裂力量(TRS),与更多的同类的微观结构。当合金是在1430点的sintered?C并且与0.5%Cr3C2/0.2%VC,TRS到达3786MPa,坚硬是91.7HRA和比0.6m小的谷物尺寸。谷物生长上的数字分析在sintering过程期间证明在WC谷物边界并且Cr3C2溶解在公司上猛抛的两VC分阶段执行减少固体/液体的界面的精力,溶解和降水的过程极大地被延迟,WC谷物变粗被禁止。

  • 标签: 晶体生成因素 超好晶体 硬质合金 微结构
  • 简介:采用动电位和电化学阻抗谱技术研究了纯Ti(2级)和Ti-Pd合金(7级)的耐腐蚀性能。实验温度为36.6℃,实验溶液包括模拟的健康人体条件的pH7.4的PBS溶液和添加了H2O2(0.015mol/L)的pH5.2的炎症状态的PBS溶液。Ti-Pd合金(7级Ti),在含H2O2的PBS溶液中,其耐腐蚀性能比纯Ti的好(较低的腐蚀电流密度),表明其是一种很好的骨科植入材料。

  • 标签: TI Ti-Pd合金 生物材料 腐蚀 炎症 电化学阻抗谱
  • 简介:2件1Cr17Ni2钢制氮气气瓶使用前经水检、气检和疲劳等试验发现气瓶瓶体存在漏点。通过宏微观形貌观察、能谱分析、金相检查和硬度测试等手段,结合气瓶的加工及热处理工艺,确定了气瓶裂纹的性质和原因。结果表明:2个气瓶裂纹的性质均为应力腐蚀开裂,建议调整气瓶焊接的退火温度,降低其应力腐蚀敏感性,并建议对焊接过程进行全方位控制,防止焊接电极接触瓶体等不规范操作行为。

  • 标签: 1CR17NI2钢 裂纹 应力腐蚀 焊接
  • 简介:AZr-1.15wt%Cr-0.10wt%Fealloywasbeta-quenchedfrom1050℃toproduceasupersaturatedα′-phase,andthenheatedforvaryingtimesattemperaturesfrom650℃to760℃toprecipitateZr(CrFe)2.Athermoelectricpower(TEP)techniqueandtransmissionelectronmicroscopy(TEM)wereusedtomonitorthisprecipitationprocess.UsingtheJohnson-Mehl-Avramiequation,theTEPresultsandalineregressionmethod,theactivationenergyfordiffusionandthediffusioncoefficientofchromium(andFe)inα-Zrhavebeencalculatedover650℃~760℃.Thetemperaturedependenceofthediffusioncoefficient,DCr/α(cm2/s)isdescribedat650℃~760℃bytherelationshipformula.ThecoarseningoftheZr(CrFe)2particlesshowsat1/2dependenceofmeanparticlesizeonagingtime,t.Suchatimedependenceistypicalofcoarseningwhereatomtransferacrosstheinterfaceisrate-controlling.

  • 标签: Zirconium-base ALLOY Heat treatment PRECIPITATION KINETICS