简介:应用密度泛函理论中的ω-B97XD/6-311+G(d,p)方法,对甲湛分子团簇[CH2O]n(n=1~4)的空间结构进行了优化,得到了这些团簇的基态结构,并对其红外光谱,核磁共振谱的性质进行了研究.结果表明,当甲醛分子构成稳定的多分子团簇时,团簇中的每个分子仍然为平面结构,分子间将形成氢键,并且团簇中的各个分子共面.与单分子甲醛相比,多分子团簇的红外光谱,会出现许多与分子间氢键振动有关的新的吸收峰.当甲醛分子形成团簇时,13C核和17O核的核磁共振谱线会发生劈裂现象,这与电荷分布的对称性的破缺有关;而1H的核磁共振谱中将会出现新的条纹,这是由分子间的氢键的形成引起的.本文的研究可为甲醛团簇的识别、检测及性质研究提供理论依据.
简介:Theaddedmasscoefficientandthewaterlevelindexformulasforthesame-phaseandanti-phasevibrationofrectangularliquidtanks'bulkheadswerederivedbasedondrymodetheory.Threefluid-structureinteractionnumericalmethodsincludingFluidFEMandFluidBEMwereusedinthiscase.ThecomparisonofnumericalandtheoreticalresultsbythepresentmethodshowsthatANSYS/FluidS0ismorecredible,theNASTRAN/VirtualMassMethodismoresuitableforengineeringcalculationsandresultsofthesame-phasevibrationbythepresentmethodismoreaccurate.
简介:S-surfacecontrolhasproventobeaneffectivemeansformotioncontrolofunderwaterautonomousvehicles(AUV).Howevertherearestillproblemsmaintainingsteadyprecisionofcourseduetotheconstantneedtoadjustparameters,especiallywheretherearedisturbingcurrents.Thusanintelligentintegralwasintroducedtoimproveprecision.AnexpertS-surfacecontrolwasdevelopedtotunetheparameterson-line,basedontheexpertsystem,itprovidesS-surfacecontrolaccordingtopracticalexperienceandcontrolknowledge.Topreventcontroloutputover-compensation,afuzzyneuralnetworkwasincludedtoadjusttheproductionrulestotheknowledgebase.ExperimentswereconductedonanAUVsimulationplatform,andtheresultsshowthattheexpertS-surfacecontrollerperformsbetterthananS-surfacecontrollerinenvironmentswithcurrents,producinggoodsteadyprecisionofcourseinarobustway.
简介:Arraycalibrationisimportantinengineeringpractice.Inthispaper,fastcalibrationmethodsforaULA'sgainandphaseerrorsbothinfarandnearfieldsareproposed.Inthefarfield,usingasinglesoundsourcewithoutexactorientation,thismethodhorizontallyrotatesthearrayexactlyonce,performseigenvaluedecompositionforthecovariancematrixofreceiveddata,thencomputesthegainandphaseerroraccordingtotheformulas.Inthenearfield,usingthesamesinglesoundsource,itisnecessarytorotatethearrayhorizontallyatmostthreetimes,buildequationsaccordingtogeometricrelations,thensolvethem.Usingtheformulaproposedinthispaper,sphericalwavesaremodifiedintoplanewaves.Theneigenvaluesdecompositionisperformed.Thesetwocalibrationmethodswereshowntobevalidbysimulationandarefast,accurateandeasytouse.Finally,ananalysisoffactorsinfluencingestimationprecisionisgiven.
简介:Oceanographicsurvey,orothersimilarapplicationsshouldbetheapplicationsofmultipleAUVs.Inthispaper,theskill&simulationbasedhybridcontrolarchitecture(S2BHCA)asthecontroller'sdesignreferencewasproposed.Itisamulti-robotcooperationorientedintelligentcontrolarchitecturebasedonhybridideas.TheS2BHCAattemptstoincorporatethevirtuesofthereactivecontrollerandofthedeliberativecontrollerbyintroducingtheconceptofthe"skill".Theadditionalonlinetasksimulationabilityforcooperationissupported,too.Asanapplication,amultipleAUVcontrolsystemwasdevelopedwiththree"skills"fortheMCMmissionincludingtwodifferentcooperativetasks.Thesimulationandtheseatrialsshowthatsimpletaskexpression,fastreactionandbettercooperationsupportcanbeachievedbyrealizingtheAUVcontrollerbasedontheS2BHCA.
简介:
简介:面对biofilms,不锈钢(SS)展览腐蚀潜力的增加,叫的崇高。在现在的学习,腐蚀潜力(E<潜水艇class=“a-plus-plus”>双SSUNSS32760的corr)行为同时被记录与在里面在Arraial的区域做Cabo的在二的situ水兵biofilm形成,东南的巴西。在Forno港口(一个人为地扰乱的区域)的biofilm被更高相对的许多细菌在白天2点描绘,在白天10上由硅藻(特别Naviculasp)列在后面并且白天18上的dinoflagellates,而没有清楚的趋势在CaboFrio岛(一个没受到干扰的区域)被记录。E的崇高<潜水艇class=“a-plus-plus”>corr价值是地点依赖者。在互补实验室试金,biofilms被移开并且E<潜水艇class=“a-plus-plus”>corr价值处于无菌的条件登记了为随后10天并且在situ结果支持了。理解biofilms和SS相互作用象帮助在这知识填重要差距一样为材料科学和工程决定有重要含意。