学科分类
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21 个结果
  • 简介:Co-basedcatalystswerepreparedbyusingdielectric-barrierdischarge(DBD)plasmaasanalternativemethodtoconventionalthermalcalcination.ThecharacterizationresultsofN2-physisorption,temperatureprogrammedreduction(TPR),transmissionelectronmicroscope(TEM),andX-raydiffraction(XRD)indicatedthatthecatalystspreparedbyDBDplasmahadahigherspecificsurfacearea,lowerreductiontemperature,smallerparticlesizeandhighercobaltdispersionascomparedtocalcinedcatalysts.TheDBDplasmamethodcanpreventthesinteringandaggregationofactiveparticlesonthesupportduetothedecreasedtreatmenttime(0.5h)atlowertemperaturecomparedtothelongerthermalcalcinationathighertemperature(at500℃for5h).Asaresult,thecatalyticperformanceoftheFischer-TropschsynthesisonDBDplasmatreatedCo/SiO2catalystshowedanenhancedactivity,C5+selectivityandcatalyticstabilityascomparedtotheconventionalthermalcalcinedCo/SiO2catalyst.

  • 标签: 放电等离子体 合成催化剂 介质阻挡放电 钴基催化剂 催化性能 FISCHER-TROPSCH合成