简介：结构和磁性ofPr_xFe_(60.5x)上的Pr的效果Pt_(39.5)合金(x=0，0.5，1.0，和1.5)被调查。X光检查衍射数据显示FePt的阶段转变温度从disorderedface-centered-cubic基于合金到订的face-centered-tetragonal有Prconcentration的增加的立方的减少。Pr戏更精制的谷物和它的角色能提高在软磁性的阶段和努力磁性的阶段之间联合的交换。结果显示由Prcan的Fe的代替显著地改进Fe_(60.5)Pt_(39.5)合金的顽磁和coercivity。Theseresults能根据阶段转变和微观结构被解释。当Pr内容的功能被0.5at.%Pr的最佳增加增加，FePt的顽磁比率和coercivity基于合金。

简介：Ni0.3Cu0.07Zn0.63Fe2xLaxO4铁酸盐被稳固的阶段方法和sintered在1,150点准备?t接口。紫外分光光度计(UVS)被采用获得HfO2的乐队差距价值。在3d和Hf4f，核心级的系列和原子价系列被采用获得HfO2/InP的原子价乐队偏移量。试验性的结果出现(5.88??T

简介：ZnSnanostructureswithdifferentdimensionsandstructure-relatedpropertieswerereviewedinthispaper.Thecrystallizationofnanostructuresfrom0D,1Dto3D,aswellastheheterogonouscounterparts,wassummarizedintheaspectofzincblende,wurtzitestructure,andtheircombinations.Furthermore,thestructure-relatedenergybandsandthecorrespondingphotoelectricpropertiesofZnSnanostructureswerealsofocused,inwhichwemadeabriefsummaryoftheco-relationsbetweenphotoluminescenceandcrystallography,especiallythedefectrelatedluminescencepropertiesofZnSnanocrystal.

简介：ThecompositionandstructureofcyclicsulfoxidederivativePd(Ⅱ)complexwereinvestigated.Thecoordinatednumberwasstudiedwithslopemethod.Thecoordinationnumberis2inloweracidity,butitis3inhigheracidity.Fourmethods,UV(ultraviolet)spectra,FrIR(Fouriertransforminfrared)spectra,1H-NMR(nuclearmagneticresonance)spectra,and13C-NMRspectra,wereusedtodeterminethecoordinatedatomincomplex.PdiscoordinatedwithOandSatominS=Ogroupinloweraciditymedia.Theconversionofcoordinationbondappearswithanincreasingtime.PdiscoordinatedwithSatominS=Ogroupinhigheraciditymedia,andinter-ligand-transferreactionoccurs.

简介：[埃及土人_(1.5nm)/ZrO_(2xnm)]_(10)多层的电影被磁控管劈啪作响在玻璃底层上扔然后为30min在600℃在真空退火了。他们的结构和磁性作为ZrO_2内容的功能被调查。结果证明谷物尺寸和coercivity首先随ZrO_2内容的增加增加然后减少。Themaximumcoercivity和谷物尺寸在ZrO_2的37vol.%被获得。在这部电影的ZrO_2的内容在埃及土人谷物的分离并且在intergrainexchange相互作用的减小起一个重要作用。根据尖依赖coercivity的研究，埃及土人的磁化颠倒拍摄与，这被发现(111)质地与领域墙运动或旋转模式的S-W类型不同。

简介：ThepurposeofthisstudywastoinvestigatetheeffectsofZrinterlayeronthestructureandmechanicalpropertiesofTiAlNfilms,whichweredepositedontheM2high-speedsteelsubstratesbymeansofplasma-enhancedmagnetronsputtering.TheresultshowsthatthecrystalorientationofZr/TiAlNfilmsissimilartothatofsingle-layeredTiAlNfilms,butthedifferenceisthatAlN(111)ofZr/TiAlNfilmsdisappearscompletely.WithrespecttoZrinterlayer,thetexturecoefficientofZr/TiAlNfilmsisapproximately1.Zr/TiAlNfilmsexhibitacompactisometricstructure,whichisdistinctlydifferentfromthecolumnarstructureexistinginthesingle-layeredTiAlNfilmsandTi/TiAlNfilms.ThehardnessandH3/E*2ofZr/TiAlNfilmsare,respectively,enhancedtobe36.6GPaand0.147.Withafewcracksemergingaroundtheindention,theadhesionstrengthofTiAlNfilmsisobviouslyadvancedbyaddingZrmetalinterlayer.

简介：LiCoO2thinfilms,whichcanbeusedasacathodematerialinmicrobatteries,weredepositedusingradiofrequency(r.f.)magnetronsputteringsystemfromaLiCoO2targetandinanO2+Aratmosphere.ThefilmswerecharacterizedbyvariousmethodssuchasXRD,SEMandAFM.TheLiCoO2filmswereannealedinairat300,500,700and800℃respectively.Theeffectoftheannealingtemperatureonthestructure,thesurfacemorphologyandtheelectrochemicalpropertiesofthefilmswereinvestigated.TheLiCoO2thinfilmdepositedatroomtemperatureisamorphousandhassmallergrainsize.Withincreasingofannealingtemperature,thecrystallinityofthefilmsispromoted.Whentheannealingtemperatureincreasesto700℃,thefilmshaveaperfectcrystallineLiCoO2phase.TheLiCoO2thinfilmwithoutannealinghasnodischargeplateauandsmalldischargecapacity(about27μAh·cm-2μm).Thedischargecapacityincreaseswiththeincreasingofannealingtemperatureandreaches47μAh·cm-2μmforthefilmannealedwith700℃,whichalsoshowsthetypicaldischargeplateauof3.9V.ThecycleperformanceofLiCoO2thinfilmsofasgrownandannealedatdifferenttemperatureswerestudied.Inthecaseofthefilmwithoutthermaltreatment,thecapacityfadingismuchfasterthanthatofthefilmannealedatdifferenttemperature,showingabout40%capacitylossonlyafter25cycles.However,inthecaseofthefilmannealedat700℃,thecapacityreachestosteadystategraduallyandmaintainedconstantlywithcycling.After25timescycling,thedischargecapacityofthefilmannealedat700℃decreasestoabout36.9μAh·cm-2·μm,only0.8%capacitylosspercycle.

简介：Sm_(0.9)Pr_(0.1)Fe_xandSm_(1-x)Nd_xFe_(1.9)的结构，磁化，和磁伸缩变瘦电影用X光检查衍射，颤动的样品磁强计，和光伸臂方法被调查了。Sm_(0.9)Pr_(0.1)Fe_xthin电影的结构由一张Sm-Pr-Fe无定形相组成，这被发现什么时候x≤2.69并且Sm_(1-x)Nd_xFe_(1.9)的薄电影由一张Sm-Nd-Fe无定形相组成。有Fe内容的增加的在里面飞机磁化ofSm_(0.9)Pr_(0.1)Fe_x薄电影增加，和茶碱飞机coercivity的低价值发生在1.62≤x≤的范围2.28。当时，有增加Fe的磁伸缩价值ofSm_(0.9)Pr_(0.1)Fe_x薄电影增加满足x≤1.94并且减少什么时候x>1.94。Sm_(1-x)Nd_xFe_(1.9)的在里面飞机磁伸缩在低磁场下面的薄电影被Nd的替换为Sm改进了什么时候x=0.2。

简介：Theexchangecouplingattheferromagnetic/antiferromagnetic(FM/AFM)interfaceisinfluencedbyboththemagneticstructureandthecrystallinemicro-structure.Co/FeMn/Cothinfilmswith0.4nmPtspacerlayerinsertedintotheCo/FeMnandFeMn/Cointerfacerespectivelyweredepositedbymeansofmagnetronsputtering.ThetwointerfacesuponandbeneaththeFeMnlayershowdistinctbehaviorsbeforeandafterthePtspacerinserted.ThereisaremarkableshrinkoftheinterfacialuncompensatedspinswithintheFeMnbottominterfacialmonolayers,whereasarelaxationofthepinningstrengthoftheFeMninterfacialspinsalongtheout-of-planedirectionoccursatthetopinterface.XRDanalysisindicatesthePtlayerupontheFeMnlayerformsanfcc(002)texture,implyingthemagneticdiscrepancybetweenthetopandbottomFeMninterfaceshascrystallinestructuralorigins.

简介：阶段和磁电机在合金R(Co_(1-x)Sn_x)的热量的效果有x=的_20，0.025，0.050，0.075，和0.100被X光检查衍射分析和磁化测量调查。在RCo_2的Sn的替换是有限的。为RCo_2的合金的立方的MgCu_2-typestructure被X光检查粉末衍射证实，留下的合金主要由RCo_2阶段组成了，与一些RCo_3和R_5Sn_3杂质阶段一起。Theimpurity阶段随Sn内容的增加增加。合金的T_c不对为Dy(Co_(1-x)Sn_x)的Sn替换很敏感_2和Tb(Co_(1-x)Sn_x)_2inGd(Co_(1-x)Sn_x)_2，居里温度显著地增加。最大的磁性的熵在合金Dy(Co_(1-x)Sn_x)改变_2(x=0，0.025，0.050，0.075)是5.78，5.43，3.88，并且2.98J·kg~(-1)·K~(-1),分别地，并且那些在Tb(Co_(1-x)Sn_x)_2(x=0，0.025)是3.44，and2.29J·kg~(-1)·K~(-1)分别地0-2.0T在应用的地里变化。

简介：AnewtypeofcomplexsolidsuperacidcatalystWO3-ZrO2-SO42-withanacidstrengthH0≤-16.04waspreparedbykneadingZr（OH）4oramorphousZrO2withtungsticacid（H2WO4）（W/Zr=0.15）,followedbyexposingthiscomplexhydroxidesto0.5tool/LH2SO4,calcininginairat700～800℃for3h.ThiscatalystpossessesbothstrongBronstedacidityandstrongLewisacidityexperimentallyshowedbyIRobservationofpyridineabsorbedonit.XPSandAEStechniqueswereemployedtoexaminethevalencestatesoftungsten,zirconium,sulfurandtheirinteractions.Thestructureofsulfurspecieswasstudiedbyinfraredspectroscopyandastructuremodelofactivesitewasproposedupontheseresults.

简介：电子结构和在不同压力(260，320，400和600GPa)的新奇Na-hP4高压力阶段的光性质被密度调查有为交换和关联精力的概括坡度近似(GGA)的功能的理论(DFT)。沿着在Brillouin地区，状态(DOS)的密度和状态(PDOS)的部分密度的更高的对称斧子的乐队结构被介绍。乐队差距增加，精力乐队膨胀到某程度，压力增加。绝缘的功能，反射率，精力损失功能，光吸收系数，光传导性，折射索引和扑灭系数为在不同压力讨论Na-hP4高压力阶段的光性质被计算。

简介：在直径的200公里的AZ31合金营舍被扔的常规直接寒冷(DC)的三个不同过程生产，低频率的电磁的扔(LFEC)并且扔的低频率的电磁的颤动(LFEVC)分别地。微观结构，macrosegregation和AZ31合金营舍的机械性质上的LFEC和LFEVC的效果被调查。在扔的常规DC，AZ31合金营舍展出了粗糙的谷物(大约370m)和艾尔和Zn的严重分离。面对独唱，低频率的轮流出现磁场或一块低频率的电磁的颤动地在200公里AZ31营舍扔的DC期间适用，在AZ31合金营舍的谷物有效地被精制(大约210m)并且在营舍的艾尔和Zn的macrosegregation极大地被减少。而且，张力的力量，破裂延伸和当演员组AZ31合金营舍的坚硬被LFEC和LFEVC的过程相对由扔的常规DC的过程扔了那改进。

简介：ThestructureandelectrochemicalcharacteristicsofLa0.7Mg0.3Ni2.875Co0.525Mn0.1-boroncompositewasstudiedsystematically.TheAB3typehydrogenstoragealloysLa0.7Mg0.3Ni2.875Co0.525Mn0.1weresuccessfullysynthesizedbymeansofinter-mediaalloyLa2Mg17.Thealloyswerecompositedwithboronatdifferentweightrate.FromtheXRDanalyses,eachalloyofthisseriesismainlycomposedof(La,Mg)Ni3phaseandtheLaNi5phase,andthephaseabundanceofeachphasevarieswiththeboronweightrate,moreover,aftercomposition,thecandcellvolumesof(La,Mg)Ni3phaseincrease,andtheLaNi5phasekeepthesame,whichindicatethattheboronmayenter(La,Mg)Ni3phase.Theelectrochemicalstudiesshowthatthemaximumdischargecapacityofthecompositesdecreases,butthecyclinglifeimproved.Andthehighratedischargeabilityandexchangeimpendencespectroscopy(EIS)oftheAB3alloysanditscompositewerealsostudied.

简介：Mechanicalalloying(MA)andsubsequentsolidsinteringprocesswasusedtopreparetheNd-containingmagnetostrictiveTb0.4Nd0.6(Fe0.8Co0.2)1.90alloy.Thestructure,thermalstabilityandphasetransformationwereinvestigatedasfunctionsofcomposition,millingprocessandannealingtemperature.Anamorphousphasewasformedbyhigh-energyballmillingfor5hwiththeball-to-powderweightratioof20:1,whichcrystallizedintoMgCu2-typeandPuNi3-typecrystallinestructurewithdifferentannealingte...

简介：Themicrostructuresofas-castandas-solutionMg–12Gd–2Er–1Zn–0.6Zralloyswereinvestigatedbyopticalmicroscopy（OM）,scanningelectronmicroscopy（SEM）,transmissionelectronmicroscopy（TEM）,highresolutiontransmissionelectronmicroscopy（HRTEM）X-raydiffraction（XRD）andselected-areaelectrondiffraction（SAED）inthepresentinvestigation.TheresultsshowthattheprimaryeutecticphaseMg5（Gd,Er,Zn）andsomeflocculentfeaturesarefoundintheas-castalloy;theSAEDpatternindicatesthattheseflocculentfeaturesarethedenseareasofstackingfaults.The14H-LPSOstructureprecipitatesinthetemperaturerangeof673–793K,andthevolumefractionof14H-LPSOstructureincreaseswiththeextensionofheatingtime;however,thereisnoprecipitationof14H-LPSOstructurewhenthetemperaturereachesupto803K.Inaddition,theMg5（Gd,Er,Zn）phasedissolvesgraduallyalongwiththeprecipitationof14H-LPSOstructure.

简介：ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.