学科分类
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3 个结果
  • 简介:Theinvestigationofelectrochromiceffectofcorona-polednonlinearopticalpolymerfilmsisaneffectivemethodfortheestimationofpolinglevelandtheselectionofpolingconditions.ThepolingelectricfieldEpandorientationalorderparameterΦ,whicharetheimportantparameterstopredictd33ofpoledfilms,canbecalculatedbyasimpleoperationfromthenumberofredshiftofchargetransferabsorptionband.Thecalculatedresultsareingoodagreementwiththeexperimentaldata.

  • 标签: Nonlinear optical POLYMER POLING Corona-poled film
  • 简介:Inthispaper,sixkindsofactivatedcarbonssuchasAg^+-activatedcarbon,Cu^2+activatedcarbon,Fe^3+-activatedcarbon,activatedcarbon,Ba^2+-activatedcarbonandCa^2+activatedcarbonwereprepared.Themodelforestimatingactivatedenergyofdesorptionwasestablished.Temperature-programmeddesorption(TPD)experimentswereconductedtomeasuretheTPDcurvesofn-hexanolandthenestimatetheactivationenergyfordesorptionofn-hexanolontheactivatedcarbons.Resultsshowedthattheactivationenergyforthedesorptionofn-hexanolontheAg^+-activatedcarbon,theCu^2+-activatedcarbonandtheFe^3+-activatedcarbonwerehigherthanthoseofn-hexanolontheactivatedcarbon,theCa^2+-activatedcarbonandtheBa^2+-activatedcarbon.

  • 标签: 有机化合物 解吸 n-乙烷
  • 简介:4newmodel,phaseequilibrium-kineticsmodel(PEKM),forestimationofdiffusioncoefficientwasproposedinthispaper.KineticexperimentsofphenoldesorptiononNKAIIresininthepresenceandtheabsenceofultrasoundwereseparatelyconducted,anddiffusioncoefficientsofphenolwithinanadsorbentparticlewereestimatedbymeansofproposedPEKMandclassicsimplifiedmodel.ResultsshowthattheuseofultrasoundnotonlychangesthephaseequilibriumstateofNKAllresin/phenol/watersystemwhichhadbeenequilibriumatnormalcondition,butalsoenhancesdiffusionofphenolwithintheresin.ThediffusioncoefficientofphenolintheresininthefieldofultrasoundincreasesinanorderofmagnitudeincomparisonwiththediffusioncoefficientdeterminedundernoultrasoundExperimentalresultsalsoindicatedthatthediffusioncoefficientsestimatedbyPEKMweremoreaccuratethanthatestimatedbytheclassicsimplifiedmodel.

  • 标签: 扩散系数估计模式 苯酚解吸附作用 聚合树脂 超声