简介:Normally,itisdifficulttodirectlymeasurethebandgapsofperovskitebasedonmethylammonium(MA)orformamidinium(FA)athightemperaturesduetomaterialdecomposition.Wepreventthedecompositionbykeepingthesynthesizedperovskitefilms(MAPbI3andMAPbI3)inorganiciodidevapors,thenmeasurethein-situresistanceofthefilmsatvariedtemperatures,andfurtherevaluatethebandgapsofthesetwomaterials.Theevaluatedbandgapsareconsistentwiththeresultsfromultraviolet-visible(UV-vis)absorptionspectrum.ThebandgapofMAPbI3decreaseswithtemperatureabove95℃,whereasthatofFAPbI3firstincreaseswithtemperaturefrom95℃to107℃andthendecreaseswithtemperatureabove107℃.