简介：稳固的氧化物燃料房间(SOFC)为海洋的力量系统作为一种有效、干净的其他的选择被识别了。这份报纸在在海洋的操作情形之上基于的SOFC力量系统和它的表演的动态建模上强调。一个SOFC力量系统模型就热力学、电气化学的反应机制而言被提供了。锂离子电池，力量调节单位，栈结构和控制器的子部件集成于模型。系统的动态反应根据它的子部件和控制器的惯性被识别。以稳定的状态和运输时期的整个系统模拟的确认被介绍，有关thermo惯性，控制策略和航海的环境的效果。模拟结果显示出合理精确性与实验室测试作比较。模型能被用来预言一个SOFC力量系统的性能并且当部件参数的部分被调整时，识别系统反应。

简介：为稳固的氧化物的NiO/SDCcomposites和Ni/SDC金属陶瓷造成房间(SOFC)阳极应用程序从氧化镍(NiO)被准备，samaria做了由粉末冶金学的粉末处理的二氧化铈(SDC)。NiO/SDCcomposites和Ni/SDC金属陶瓷的物理、机械的性质，以及微观结构被调查。NiO/SDCcomposites和NiO内容的sintering温度在决定NiO/SDCcomposites的微观结构和性质起一个重要作用，这被显示出，接着，它影响Ni/SDC金属陶瓷的微观结构，电的传导性，和机械性质。Thepresent学习表明了那篇作文并且(进程参数必须适当地被选择优化微观结构，为稳固的氧化物的NiO/SDC材料的性质造成房间应用程序。

简介：Thispaperpresentsanapplicationofiterativelearningcontrol(ILC)techniquetothevoltagecontrolofsolidoxidefuelcell(SOFC)stack.Tomeetthedemandsofthecontrolsystemdesign,anautoregressivemodelwithexogenousinput(ARX)isestablished.Firstly,byregulatingthevariationofthehydrogenflowrateproportionaltothatofthecurrent,thefuelutilizationoftheSOFCiskeptwithinitsadmissiblerange.Then,basedontheARXmodel,threekindsofILCcontrollers,i.e.P-,PI-andPD-typearedesignedtokeepthevoltageatadesiredlevel.SimulationresultsdemonstratethepotentialoftheARXmodelappliedtothecontroloftheSOFC,andprovetheexcellenceoftheILCcontrollersforthevoltagecontroloftheSOFC.

简介：现代先进能源系统普遍具有复杂性和多尺度特性,其模拟研究存在的最大问题是计算代价过高.为了提高计算效率,将非结构化自适应建表法(insituadaptivetabulation,isat)与动力学蒙特卡洛法(kineticsmontecarlo,kmc)相结合,在误差允许的范围内,通过采用近似插值计算代替部分耗时的微观模拟过程,达到减少计算时间的目的.以固体氧化物燃料电池(solidoxidefuelcell,sofc)为例,对其在不同参数条件下氢氧反应过程进行仿真研究.仿真结果表明,在满足精度要求的前提下,所建立起的混合方法相比于单独使用kmc能够有效的缩短计算时间,提高计算效率.

简介：Inco-ionicconductingsolidoxidefuelcell(SOFC),bothoxygenion(O2)andproton(H+)cantransportthroughtheelectrolyte,generatingsteaminboththean-odeandcathode.ThusthemasstransportphenomenonintheelectrodesisquitedifferentfromthatinconventionalSOFCwithoxygenionconductingelectrolyte(O-SOFC)orwithprotonconductingelectrolyte(H-SOFC).Thegenerationofsteaminbothelectrodesalsoaffectstheconcentrationover-potentiallossandfurthertheSOFCperformance.However,nodetailedmodelingstudyonSOFCswithco-ionicelectrolytehasbeenreportedyet.Inthispaper,anewmathematicalmodelforSOFCbasedonco-ionicelectrolytewasdevelopedtopredictitsactualperformanceconsideringthreemajorkindsofoverpotentials.Ohm'slawandtheButler-Volmerformulawereusedtomodeltheionconductionandelectrochemicalreactions,respectively.Thedustygasmodel(DGM)wasemployedtosimulatethemasstransportprocessesintheporouselectrodes.Parametricsimulationswereperformedtoinvestigatetheeffectsofprotontransfernumber(tH)andcurrentdensity(jtotal)onthecellperformance.Itisinterestingtofindthattheco-ionicconductingSOFCcouldperformbetterthanO-SOFCandH-SOFCbychoosinganappropriateprotontransfernumber.Inaddition,theco-ionicSOFCshowssmallerdifferencebetweentheanodeandcathodeconcentrationoverpotentialsthanO-SOFCandH-SOFCatcertaintHvalues.TheresultscouldhelpmaterialselectionforenhancingSOFCperformance.

简介：ThispaperreportstheuseofAufilmstoimprovetheperformanceofthestackedsolidoxidefuelcell(SOFC)basedonthecharacterizationoftheinterfaceandtheadhesionbetweentheelectrodesoftheSOFCsandtheAgpaste.Thespecimensweremanufacturedtoperformtheexperimentasfollows.ASiO2waferwitha300mmnotchwasattachedtotheelectrodesofaSOFCbyaAgpasteandAufilm,whichweredepositedontheelectrodesbysputteringfor1minor5mindepositiontimeandannealedat300Cfor1h.Thefour-pointbendingtestwasperformed,whichresultedintheformationofanextendedcrackatthetiponthewafernotch,andthecrackpropagationwasobservedusingastereomicroscopeequippedwithacharge-coupleddevice(CCD).Consequently,theinterfacialadhesionenergyandtheeffectoftheAufilmbetweentheeachelectrodeandtheAgpastecanbeevaluated.Onthecathode,theinterfacialadhesionenergywithoutAufilmwas2.59J/m2(uppervalue)andtheadhesionenergyincreasedto11.59J/m2(uppervalue)and15.89J/m2(lowervalue)withtheAufilm.Ontheanode,theinterfacialadhesionenergywithoutAufilmwas1.74J/m2(uppervalue),whichincreasedto11.07J/m2(uppervalue)and14.74J/m2(lowervalue)withtheAufilm.Inaddition,theinterfaceareaswereanalyzedbyscanningelectronmicroscopy(SEM)andenergydispersivespectroscopy(EDS)toestimatetheinterfacedelamination.

简介：Inthispaper,anapplicationofanonlinearpredictivecontrollerbasedonaselfrecurrentwaveletnetwork(SRWN)modelforadirectinternalreformingsolidoxidefuelcell(DIR-SOFC)ispresented.Asoperatingtemperatureandfuelutilizationaretwoimportantparameters,theSOFCisidentifiedusinganSRWNwithinletfuelflowrate,inletairflowrateandcurrentasinputs,andtemperatureandfuelutilizationasoutputs.ToimprovetheoperatingperformanceoftheDIR-SOFCandguaranteeproperoperatingconditions,thenonlinearpredictivecontrolisimplementedusingtheoff-linetrainedandon-linemodifiedSRWNmodel,tomanipulatetheinletflowratestokeepthetemperatureandthefuelutilizationatdesiredlevels.SimulationresultsshowsatisfactorypredictiveaccuracyoftheSRWNmodel,anddemonstratetheexcellenceoftheSRWN-basedpredictivecontrollerfortheDIR-SOFC.

简介：采用自蔓延高温合成技术（SHS）制备固体氧化物燃料电池（SOFC）阴极材料La1-xSrxMnO3（LSM）;研究成形压力、稀释剂添加量等参数对反应过程及合成产物性能的影响;采用XRD、ICP研究SHS法合成LSM的物相和晶型结构.结果表明：自蔓延高温合成产物为钙钛矿结构菱方晶系La1-xSrxMnO3,Sr含量的变化引起合成产物特征峰的位置和半峰宽变化;随着Sr含量的增加,合成的LSM粉末粒度变细,晶格常数a和c减小.

简介：在这个工作，一个管状的陶器支持的稳固的氧化物燃料房间(SOFC)被包含阶段倒置，刷子涂层和泉华co的低费用和简单过程成功地制作。包括sintering行为，管状的支持的微观结构以及单个房间的电气化学的性质的性质被调查。结果证明有指状的毛孔和macrovoids的多孔的管状的支持在阶段倒置过程以后被获得。管状的支持被证明在在1400点的sintering以后气体可渗透吗？？

简介：日本碍子开发出了使用氢气燃料时发电效率（LHV）达到全球最高的63％的固体氧化物型燃料电池（SOFC）。输出功率为700W，工作温度为800℃。在单元的支撑体——燃料极整个面上形成了5μm的电解质（氧化锆）薄膜，降低了电阻值，并在单元两面形成空气极确保了发电面积，从而实现了较高的输出功率。

简介：Strongrestrictionsonemissionsfrommarinepowerplants(particularlySOx,NOx)willprobablybeadoptedinthenearfuture.Inthispaper,acombinedsolidoxidefuelcell(SOFC)andsteamturbinefuelledbynaturalgasisproposedasanattractiveoptiontolimittheenvironmentalimpactofthemarinesector.TheanalyzedvariantofthecombinedcycleincludesaSOFCoperatedwithnaturalgasfuelandasteamturbinewithasingle-pressurewasteheatboiler.ThecalculationswereperformedfortwotypesoftubularandplanarSOFCs,eachwithanoutputpowerof18MW.Thispaperincludesadetailedenergyanalysisofthecombinedsystem.Massandenergybalancesareperformednotonlyforthewholeplantbutalsoforeachcomponentinordertoevaluatethethermalefficiencyofthecombinedcycle.Inaddition,theeffectsofusingnaturalgasasafuelonthefuelcellvoltageandperformanceareinvestigated.Ithasbeenfoundthatahighoverallefficiencyapproaching60%maybeachievedwithanoptimumconfigurationusingtheSOFCsystem.Thehybridsystemwouldalsoreduceemissions,fuelconsumption,andimprovethetotalsystemefficiency.

简介：对钙钛矿型复合氧化物（ABO3）的结构特征和性质进行详细分析，研究表明，以合适的阳离子取代A、B位离子而形成含有氧空穴的钙钛矿结构是钙钛矿型复合氧化物演变为各种功能材料的基础。通过适当的掺杂，钙钛矿型复合氧化物可同时具有良好的导电性、催化活性、热稳定性和化学稳定性，因此在SOFC中有广泛的应用。分别以LSM、LSCF等典型钙钛矿型复合氧化物为例，阐述了钙钛矿型复合氧化物在SOFC阴极中的应用。