学科分类
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8 个结果
  • 简介:Wesynthesized(Pb,Cd)Sr2(Y,Ca)Cu2O7+x,phasesuperconductor.AftersubstitutionofPbwithBi,theBiCd1212phaseshowsnosuperconductivity.AlthoughpreviousEXAFSstudyhasshownthelocalstructureenvironmentoftheCuissimilarinbothcompounds,EXAFSresultsofBiandPbheredemonstratethatσ2ofPb-Oin-planeislargerthanthatofBi-Oinplane,whereasσ^2ofPb-OapicalissmallerthanthatofBi-O,wheraseσ^2ofPb-OapicalissmallerthanthatofBi-Oapical.TheSrshellfeaturesarealsodiffernet,itappearedthatsuperconductivityneedssomedisorder.incarrierreservoirlayer,whichisduetothesubstitutionaldefectcausedbydifferentionicradii.

  • 标签: 超导体相 (Pd Cd)1212 化合物相 (Bi Cd)1212
  • 简介:Liquidgasificationphenomenonwasobservableinliquid-soliddielectricbarrierdischarge(DBD)experiments.Startingfromclassicalthermodynamics,thisstudyaimedatfindingtilereasonofliquidgasificationintheDBDexperiments.Fluidstaticsandelectrohydrodynamicswereadoptedtoanalyzethemechanismofphasetransitionfromliquidtogas.TheSumotoeffectwasalsoemployedtovisuallyexplainthechangeinthepressureoffluidduetotheelectricfield.ItwasconcludedfromboththeoreticalanalysisandexperimentthatthechangeinliquidpressurewasakeyfactorcausingliquidtogasifyinDBDconditions.Furthermore,itwasstressedthattheliquidpressurewasaffectedbymanyparametersincludingliquidpermittivity,voltage,electricintensity,sizeofthedischargespaceanduniformityoftheelectricfielddistribution,etc.AllofthemaffectedDBDliquidgasification.Therelatedresultswouldprovideusefultheoreticalevidenceformulti-phaseDBDapplications.

  • 标签: 介质阻挡放电 相变机制 放电等离子体 液体压力 实验观察 流体压力
  • 简介:Chitosan(CTS)coatingscontainedcalcium(Ca)andphosphorus(P)ontitanium(Ti)surfacearepreparedbythecathodeliquidphaseplasmatechnology(CLPT),inacertainconcentrationelectrolytesolutionwithselectiveadditionsofammoniumdihydrogenphosphateandcalciumnitrate.Itisindicatedthattheparametersforastabledischargearevoltageof400V,frequencyof100Hz,dutycycleof30%basedonalargeamountofexperimentdata.Themorphology,structureandcompositionofthecoatedsamplesarestudiedbySEM,FTIR,XRD,XPS.Theresultsdemonstratethatthecompositecoatingsareuniform,andsomesolidparticlesofinorganicsaltcontainingcalciumandphosphorusdispersedonthecoatings.CAtestsshowthatthesamplestreatedbytheliquidplasmabecamelesshydrophilic.ThevariationofhydrophilicityontheCLPTtreatedtitaniumisattributedtothechangeofthefunctiongroupsonthesamplesurface.Meanwhile,apossibleformationmechanismofthecompositecoatingsisdiscussed.

  • 标签: 磷酸二氢铵 涂层表面 硝酸钙 等离子体技术 液相 阴极