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  • 简介:Organicgermaniumcompoundshavebeenextensivelyappliedinmedicineastonics,Inthispaper,thelocalstructuresoftwoorganicgermaniumcompounds,carboxyethylgermaniumsesquioxideandpolymericgermaniumglutamate,weredeterminedbyEXAFS.Thestructureparametersincludingcoordinationnumbersandbondlengthswerereported,andpossiblestructurepatternswerediscussed.

  • 标签: 锗原子结构 锗有机化合物 EXAFS
  • 简介:Thenanoparticlesγ-Fe2O3coatedwithsurfactants.DBS,STandCTAB.repsectively.weresynthesizedbymicroemulsionmethod.Thecoatedferricoxides.whichshowenhancednonlinearopticalpropertiescomparedwiththeirbulkcounterpart.wereprobedbyEXAFSinsolutionforms.Thex=-rayabsorptionspectraforFeKedgeweremeasuredatroomtemperaturebyhelpofsynchrotronradiationlightsource.Extendedx-rayabsorptionfinestructureanalysisshowsthatthecoatinglayersoforganicmoleculesinteractwithsurfaceatomsofnanopartices,theFe-Obondlengthwasextended.

  • 标签: 氧化铁 纳米粒子 涂层 有机活化剂 EXAFS
  • 简介:Removalofsinglecomponentandbinarymixturesofbenzeneandm-xyleneusingamulti-pin-meshreactorwasstudiedtofindthedecompositioncharacteristics,carbonbalanceandCO_2selectivity.Thedecompositionrateofbenzeneinmixturewasapproximately16%lowerthanthatofsinglecomponentbenzene.However,thedecompositionrateofm-xyleneinmixturewasslightlyhigherthanthatofsinglecomponentm-xylene.Carbonbalanceofthemixturedecompositionprocessachievedalowerlevelthanthatofsinglecomponentbenzene/m-xylene.IncreaseinthespecificinputenergywashelpfultoimproveCO_2selectivityinthesinglecomponentdecompositionprocess,whilethespecificinputenergyhadanegligibleeffectonCO_2selectivityinthemixturedecompositionprocess.Bychangingtheoxygencontentinbackgroundgas,wefoundthatdifferenttypesofradicalsshoweddifferentreactionactivitiestowardbenzeneandm-xylene.Benzenewasmorelikelytoreactwithnitrogen-containingradicals,whilem-xylenewasmorelikelytoreactwithoxygen-containingradicals.

  • 标签: 二元混合物 挥发性有机化合物 脉冲高电压 VOCS 电晕放电 间二甲苯