简介:Forinitiativeapplicationofnon-oxidesinrefractories,itisessentialtostudythermodynamicpropertiesofnon-oxides.Thestabilityandstableorderofnon-oxidesunderoxidizedatmosphereareanalyzedfirstlyandthenanewprocess,"conversereactionsintering",isproposed.Theresultsofstudyonoxidationmechanismofsiliconandaluminumnitridesindicatethatthegaseoussuboxidescanbeproducedobservablywhentheoxygenpartialpressureislowerthan"conversionoxygenpartialpressure".Thesuboxidescanbedepositednearthesurfaceofcompositetobecomeacompactlayer.Thiscausesthematerialpossessingaperformanceof"self-impedientoxidation".MetalSiandAlarethebetteradditivesforincreasingthedensityandwidthofcompactlayerandincreasingtheabilityofanti-oxidationandanti-corrosion.ThestudyonSi3N4-Al2O3,Si3N4-MgO,Si3N4-SiCsystemsisalsoenumeratedasexamplesinthepaper.TheexperimentalresultsshowthattheconversereactionsinteringisabletomakehighperformancecompositesandmetalSiandAlnotonlycanpromotethesinteringbutalsoincreasethedensityandwidthofcompactlayer.
简介:Thepaperdescribesthereactionbetweencar-bon-containingrefractories,magnesia-chromere-fractoriesandmatte,converterslag.Theresultsshowthatcarbon-containingrefractorieshavegoodresistancetomatteandconverterslaginnitrogenat-mosphere,Thepracticalresultsareunsuitableforconverter,highperformacemagnesiachromere-fractoriesarepromisingmaterials.Newlydevel-opedhighqualitydirectbondingmagnesiachrome,rebondedco-clinkermagnesiachrome,semi-rebondedmagnesiachrome,fusedcastmagnesiachromeusedinsmeltingfurancesareintroducedbriefly.
简介:TheternarycompoundbariumaluminosilicateBaAl2Si2O8,knownascelsian,anon-wettingadditivethatincreasesthecorrosionresistanceofrefractorymaterialsagainstmoltenaluminum,wasincorporatedintothematrixofahigh-aluminalowcementcastableafteritssynthesisusingbariteandalowcostsourceofaluminaandsilica.Thispaperpresentstheinfluenceofthisphaseonthewettingangleformedbetweenliquidaluminumalloyandsolidrefractorycastablesurface.
简介:Thenon-burnedcorundumspineluppernozzle,maldeofelectro-fusedcorunndumpowder,highpureelectro-fusedspinelwiththermosettingresinasbinder,addedwithcompoundant-oxdationadditives,hassuperiorHMOR,excellentcorrosionresistanceandsimpleproductionprocess,Theuppernozzlewasusedin90MTladleandtheservicelifewasimprovedby50%to60%