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14 个结果
  • 简介:Thecombinedquadraticorthogonalregressionmethodofexperimentdesignwasemployedtoexploretheeffectsofprocessparametersofplasmanitridingoftantalumsuchastotalpressure,temperatureandoriginalhydrogenmolarfractiononthehardness,roughnessandstructureofnitridingsurfaces.Theregressionequationsofhardness,roughnessandstructureweregivenaccordingtotheresultsofregressionandstatisticanalysis.Andthediffusionactivationenergyofnitrogenintantalumonplasmanitridingconditionswascalculatedaccordingtotheexperimentaldataofhardnessofplasma-nitridingoftantalumvstimeandtemperature.Thediffusionactivationenergycalculatedbelongsto(155.49+10.51)kJ/mol(783-983K).

  • 标签: 渗氮等离子体 温度 压力 正交回归法 扩散活化能
  • 简介:Titaniumandtitaniumalloyshaveseveraladvantages,butthecostoftitaniumalloysisveryexpensivecomparedwiththetraditionalmetalmaterials.Thisarticleintroducestwonewlow-costtitaniumalloysTi-2.1Cr-1.3Fe(TCFalloy)andTi-3Al-2.1Cr-1.3Fe(TACFalloy).Inthisstudy,weusedCr-Femasteralloyasoneoftherawmaterialstodevelopthetwonewalloys.Weintroducethemicrostructureandtensilepropertiesofthetwonewalloysfromβsolutiontreatedwithdifferentcoolingmethods.Optica...

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  • 简介:Thechloridizingsegregationandmagneticseparationoflow-gradenickellateritesfromYunnanprovinceofChinawasinvestigated.Thenickellateriteswerecharacterizedbymicroscopicinvestigations,usingX-raydiffractometry(XRD)andenergydispersivespectrometry(EDS)techniques.Thepellets,whichwerepreparedwithmagnesiumchlorideandcokeaschlorideagentandreductantrespectively,wereheatedtoahightemperature,andthepelletsaftercoolingwerecrushedformagneticseparation.Aseriesofexperimentswereconductedtoexaminetheeffectofchlorinatingagentdosage,reductantdosage,chloridizingtemperatureandchloridizingtimeonenrichmentgradeofNiandCo.TheresultsindicatethatthefourfactorshavesignificanteffectsontheextractionsofNiandCo.Theoptimumconditionsareasfollows:theamountsofmagnesiumchlorideandcokeare6%and2%,respectively,chloridizingtemperatureis1253K,andchloridizingtimeis90min.Undertheconditions,extractionsofNiandCoreach91.5%and82.3%,respectively.

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  • 简介:Aprocessoftheselectiveleachingofnickelfromlow-sulfurNi-Cumatteatatmosphericpressurewasdescribed.ThismattewasobtainedfromhighgradeNi-Cumattebymagneticseparation,whichmainlycontainedNi-Cualloyandasmallquantityofsulfides.Firstly,theacid-oxygen(CuSO4-H2SO4-O2)leachingofthemattewasconductedatatmosphericpressure.WhenthesolutionpHvaluereached1.0-2.0,theoxygenflowwasceased.Then,theaqueouscopperwasrejectedbycementationreactionwithNiinthealloy.ThemineralogicalcharacteristicsofthematteintheprocesswereanalyzedbyX-raydiffractometry,opticalmicroscopyandscanningelectronmicroscopy.Andtheeffectsofvariationsintemperature,particlesizedistribution,oxygenflowrate,pulpdensity,initialacidconcentrationandinitialconcentrationofcopperionwereinvestigated.

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  • 简介:在这,纸,脱臼的高密度,谷物边界和纳米规模猛抛包括严重冷滚动和短时间的退火处理通过一条thermo机械的途径被介绍给亚稳的Ti-36Nb-5Zr合金(wt%)。martensitic转变被延迟,并且有stabilizers的低内容的阶段在thermo机械的处理以后在房间温度被保留。作为结果,两低模量(57?GPa)并且高力量(950?MPa)被获得。结果显示通过微观结构优化控制martensitic转变开始温度而不是作文设计是可行策略,与制作低模量类型Ti合金的目的。

  • 标签: 优化控制 低模量 类型 设计 合金 制造
  • 简介:通过在环氧体系中添加不同含量含磷酚醛,研究了不同添加量对胶水及层压板性能的影响。结果表明:含磷酚醛的添加量对胶水凝胶化时间及板材的耐热性、耐湿热性、抗剥离强度、阻燃性有明显影响。当含磷酚醛含量为10%,板材综合性能最优,得到无卤阻燃UL-V0级,lowloss的耐湿热性、耐热性好的覆铜板。

  • 标签: 含磷酚醛 无卤阻燃 LOW LOSS
  • 简介:Theeffectsoflow-CoAB5typehydrogenstoragealloyspreparedbyquenchingandannealingontheperformancesofMH-Nibatterieswereinvestigated,andthecharacteristicsofthelow-CoAB5typehydrogenstoragealloyswerecomparedwiththoseofthehigh-CoAB5typehydrogenstoragealloyaswell.Theresultsshowedthatthefasterthecoolingofthelow-Cohydrogenstoragealloyis,thebetterhomogeneityofthechemicalcompositionforthealloyandthelongercyclelifeofthebatteryare,buttheelectrochemicaldischargecapacityandhigh-ratedischargeabilityarereduced.Thehigh-ratedischargeabilityandchargeretentionofMH-Nibatteriesfortheconventionalas-castannealedlow-Cohydrogenstoragealloyweresuperiortothosefortherapidlyquenchedlow-Cohydrogenstoragealloyandthehigh-Cohydrogenstoragealloy,butalittleinferiorinthecyclelife.

  • 标签: 热处理 MH-NI电池 能量储存 低-Co-AB5氢储存合金 制备 淬火
  • 简介:Reducingthemanufacturingcostofsolarcellsisnecessarytotheirindustrialproduction.Electrodepositingisaneffective,non-vacuummethodwhichisverysuitableforcuttingthemanufacturingcostofthinfilmsaswellasdevelopingitslarge-scaleindustrialproduction.Inthisstudy,about1-μm-thickCu(In,Ga)Se_2(CIGS)precursorswereelectrodepositedonMo/glasssubstratesinaqueoussolutionutilizingathree-electrodepotentiostaticsystem.Triethanolaminewasusedascomplexingagent,andallparametersofelectrodepositionwerepreciselycontrolled.Afterthat,theelectrodepositedprecursorswereselenizedinaSeatmospherewithdifferentheatingramprates(60and600℃·min~(-1)).High-qualityCIGSfilmswereobtained,andtheircharacteristicswereinvestigatedbyX-rayfluorescence,scanningelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,Ramanspectraandnear-infrared-visible(NIR-Vis)spectra.Theresultsrevealthattherearemanydifferencesbetweenthepropertiesofthefilmsunderdifferentheatingrates.Finally,CIGSsolarcellswerefabricatedusingafastandaslowheatingrate.Themaximumefficienciesachievedforthefilmsselenizedat60and600℃-min~(-1)are3.15%and0.71%,respectively.

  • 标签: 薄膜太阳能电池 Cu 性能 制备 低成本 X射线荧光分析
  • 简介:Au/-Al2O3催化剂被免职降水方法为低集中白酒溪流(甲醇,乙醇,iso-propanol和n-propanol)的催化燃烧作好准备。催化剂被X光检查光电子描绘光谱学(XPS),X光检查diffractometry(XRD)和精力散X光检查微分析(版本)技术。XPS结果证明仅仅催化剂的表面上有Au0。XRD模式证明Au高度大概在-Al2O3上被驱散。为有2.0g/m3的集中的甲醇,乙醇,iso-propanol和n-propanol的完全的变换的温度是60,155,170和137?,分别地但是他们完全在60,220,260和217点被使矿物化进CO2和H2O吗?分别地在优化催化剂上。催化剂的活动在130h是稳定的。为催化甲醇消除的动力学跟随了伪--首先订表示为r=0.6528c0+0.084的反应2。明显的激活精力的价值是在反应温度的范围的54.7kJ/mol。

  • 标签: 光催化 催化性能 Γ-AL2O3 活性催化剂 X射线光电子能谱 X射线显微分析
  • 简介:Aluminum,themainimpurityinthelixiviumofweatheredcrustelutiondepositedrareearthore,notonlyresultsinanincreasingconsumptionofprecipitantintherareearthprecipitationprocess,butalsolowersthepurityoffinalrareearthproduct.Aluminumintheweatheredcrustelution-depositedrareearthorelixiviumshouldberemoved.Neutralizinghydrolysismethodwasemployedtoremovealuminumfromthelixivium.HexamethylenetetraminewasfoundtobetheoptimumpHregulatorfortheremovalofaluminuminthelowconcentration.WhenusedtoadjustthepHvalueofthelixiviumto5.0,aluminuminthelixiviumcanbeeffectivelyremovedintheformofaluminumhydroxideprecipitationwithremovalrateof97.60%.Itshowsthathexamethylenetetraminehasagoodeffectontheremovingofaluminumionsfromthelowconcentrationlixivium.Moreover,hexamethylenetetramineinremovingaluminumfromlixiviumhaslittleadverseeffectontheREprecipitationprocess.

  • 标签: 风化壳淋积型稀土矿 中和水解法 浸出液 低浓度 除铝 pH值调节剂
  • 简介:SincethelowandmediumgradeoxideoresintheMainandEasternMiningAreasattheBayanOboMinehaveahighgradeofNb2O5andlargeorereservesandarerichinmanyelements,theyareofgreatervaluetouseindevelopmentandrecoverythanotherkindsofniobiummineralsresources.Thedisseminationcharacteristicsandprocessingpropertiesoffourtypesofniobiummineralsaresummarisedandmethodsandresultsofniobiummineralprocessingarealsodescribed.

  • 标签: Oxide ORE NIOBIUM DISSEMINATION CHARACTERISTICS
  • 简介:SiliconEpitaxialWaferforXBandDoubleRead-typeDDRIMPATTDiodesbyAtmosphere/LowPressureGrowthTechniqtWangXiangwuandLuChunyi王向武,陆春...

  • 标签: Si EPITAXY Multilayer X BAND DDR
  • 简介:Low-CoLa1.8Ti0.2MgNi8.9Co0.1alloyswerepreparedbymagneticlevitationmeltingfollowedbyannealingtreatment.TheeffectofannealingonthehydrogenstoragepropertiesofthealloyswasinvestigatedsystematicallybyX-raydiffraction(XRD),pressure-compositionisotherm(PCI),andelectrochemicalmeasurements.TheresultsshowthatallsamplescontainLaNi5andLaMg2Ni9phases.LaCo5phaseappearsat1,000℃.Theenthalpychangeofallhydridesiscloseto-30.6kJ·mol-1H2ofLaNi5compound.Annealingnotonlyincreaseshydrogencapacityandimprovescyclingstabilitybutalsodecreasesplateaupressureat800and900℃.Afterannealing,thecontractionofcellvolumeandtheincreaseofhydridestabilitycausethehighratedischargeabilitytoreduceslightly.Theoptimumalloyisfoundtobeoneannealedat900℃,withitshydrogencapacityreachingupto1.53wt%,anddischargecapacityremaining225.1mAh·g-1after140charge–dischargecycles.

  • 标签: 储氢性能 钴合金 退火态 高倍率放电性能 LANI5 循环稳定性
  • 简介:ThestructureandelectrochemicalpropertiesofanewlowcobalthydrogenstorageelectrodealloysLa1-xLixNi3.2Co0.3Al0.3(0≤x≤0.2)wereinvestigatedwithadifferentadditionsofLiinreplacementofLa.WiththeincreaseofLicontentsthemaximumdischargecapacityincreasesfrom240mAh·g-1(x=0)to328.4mAh·g-1(x=0.1)andthecyclestabilityisimprovedcorrespondingly.ThecapacitydecaycanremaiN28.6%(x=0.2)after230charge/dischargecycles.Thehighratedischarge(HRD)abilityofthealloys(x≤0.1)isimprovedandthebestHRDis34.1%(x=0.1)underthedischargecurrentdensity1200mA·g-1.ItisfoundthatthepreparedalloysarebasicallycomposedofLaNi5asmatrixphaseandLaNi3assecondphase(x≤0.1).ButtheabundanceofLaNi3phasedramaticallydecreaseswithincreasingx.Whenx=0.2,anewphaseAl(NiCo)3isformed.

  • 标签: HYDROGEN storage alloy microstructure high rate