简介:采用XRD、XPS、IR、ICP-AES、循环伏安、恒电流充放电等方法对LiCoO2掺杂Na高温固相化学反应合成的Li1-xNaxCoO2材料的结构及电化学性能进行了系统研究。结果表明,当掺杂Na的量x〉0.05后,Li/Li1-xNaxCoO2电池的充、放电容量较Li/LiCoO2的明显下降。随x从0.0增至0.3时,Li/Li1-xNaxCoO2电池以0.5mA/cm^2充电容量由146.3mAh/g下降至130.0mAh/g,放电容量则由110.6mAh/g下降至80.0mAh/g,但工作电压平台均为3.6V。XRD结果显示,随x的增大,Li1-xNaxCoO2的六方晶胞参数a没有统计学上的差异,而晶胞参数c则逐渐减小。但当x〉0.25后,其中有NaCoO2产生。相同x的Li1-xNaxCoO2充电后的六方晶胞参数c比未充电的有所增大,而晶胞参数a则略微缩小。但是当x〉0.25后,出现3个NaCoO2的特征衍射峰。然而,以0.5mA/cm^2充电至4.4V后,Li1-xNaxCoO2的六方晶胞参数c均增大,a略减小。XPS结果表明,随x增大,Li1s的电子结合能有增大趋势,但O1s和Na1s及Co2p3/2和Co2p1/2电子结合能变化很小。与LiCoO2相比,Li1-xNaxCoO2的循环伏安并没有新的氧化还原峰产生。
简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.
简介:Carbon-coatedlithiummanganesesilicate(Li2MnSiO4/C)nanoparticlesweresynthesizedbypolyolprocess.X-raydiffraction(XRD)patternsoftheobtainedmaterialsexhibitagoodfitwiththatoftheLi2MnSiO4phase.Fieldemissionscanningelectronmicroscopy(FESEM)imagesoftheobtainedsamplesshowthattheparticlesizeisonlytensofnanometers.Thehighresolutiontransmissionelectronmicroscopy(HRTEM)analysisshowsthattheLi2MnSiO4nanoparticlesaresurroundedbyaverythinfilmofamorphouscarbon.Thecompositepreparedthroughpolyolprocessshowsgoodperformanceascathodematerialsinlithiumcellsatroomtemperature.ThechargecapacityoftheLi2MnSiO4/Csamplesis219mAh/g(about1.3Li+perunitformulaextracted),andthedischargecapacityis132mAh/g(about0.8Li+perunitformulainserted)inthefirstcycleinthevoltagerangeof1.5-4.8V.Agoodcapacitycyclingmaintenanceof81.8%after10cycleswasobtained.
简介:Li0.33MnO2cathodematerialwassynthesizedbysolidstatereaction.Thematerialshowedasmallcoherentdomainsizeabout10nmdeterminedbyX-raydiffractionandtransmissionelectronmicroscopy.Theelectrochemicalpropertiesofthematerialwerestudiedindifferentpotentialwindowsof3.5―2.0Vand4.3―2.0V.Anirreversibletransformationtospinelphasewasobservedintheinitialseveralcycles,whichwasmoreprominentoncyclingat4.3―2.0V.ElectrochemicalimpedancespectroscopyshowedthattheLi+diffusioncoefficientofthematerialwasabout2×10–9cm2/s.Li0.33MnO2showedareversibledischargecapacityof140and200mA·h/ginthepotentialwindowsof3.5―2.0Vand4.3―2.0V,respectively.Butthecapacityretentionat4.3―2.0Vwaspoorduetothethickerspinellayerformedonthematerialsurface.
简介:AnInterviewwithLiYiningOnJanuary17,1994,ourreporterinterviewedMrLiYining,well-knownprofessorofeconomics,memberoftheStandingCo...
简介:ThecapacitytocaptureCO2wasdeterminedinseveralstoichiometriccompositionsintheLi2O–Bi2O3system.Thecompounds(Li7BiO6,Li5BiO5,Li3BiO4andLiBiO2phases)weresynthesizedviasolid-statereactionandcharacterizedbyX-raydiffraction,scanningelectronmicroscopyandN2adsorptiontechniques.Thesampleswereheat-treatedattemperaturesfrom40to750°CundertheCO2atmospheretoevaluatethecarbonateformation,whichisindicativeofthecapacityofCO2capture.Moreover,Li7BiO6showsanexcellentCO2capturecapacityof7.1mmol/g,whichisconsiderablyhigherthanthoseofotherpreviouslyreportedceramics.Li7BiO6isabletoreactwithCO2from240°Ctoapproximately660°CshowingahighkineticreactionevenatCO2partialpressurevaluesaslowas0.05.
简介:Li4Ti5O12(LTO)/carbonnanotubes(CNTs)compositematerialissynthesizedbasedonasolid-statemethodbysand-milling,spray-dryingandcalciningat8508CunderN2flow.TheLTO/CNTssampleswith1wt%and3wt%weightratioofCNTsadditionandthepristineLTOsampleareprepared.TherateperformanceandthethermalstabilityofthesesamplesareinvestigatedbasedonLiMn2O4(LMO)/LTOfull-cell.TheresultsshowthattheweightratioofCNTsadditionhasdistincteffectonLTOperformances.ThecompositematerialsofLTOcompositedCNTshavebetterperformanceathigh-rateduetotheintercalationenhancementbyconductivenetworkofCNTs.Atsecond,theoverchargingtemperatureresponseofthecell’ssurfacewith1wt%CNTsadditionisthelowest.Theparticlesizedistributionismeasuredandthemostuniformparticlesareobtainedwith1wt%CNTsaddition.ThistrendcouldexplainthatthemediumquantityofCNTsisoptimaltoimprovetheheatandmasstransferandpreventtheproblemsofcrystallitegrowinginterferenceandaggregationduringthecalcinationprocess.