学科分类
/ 25
500 个结果
  • 简介:Autler-Townes(在)在飞米第二光电子光谱ofthree水平Li-2分子切开理论上用时间依赖者被调查量波浪包方法。与合适的飞米秒激光脉搏,切开的AT的三座山峰能在thephotoelection光谱被观察。切开的AT源自强烈超短波的激光pluses引起的快速的Rabi摆动。分子的电离动力学上的激光参数的效果也被讨论。

  • 标签: 裂变 光电子光谱 分子结构 超短波脉冲
  • 简介:介绍了高功率一次Li-FeS2电池的结构和技术性能;论述了温度和贮存时间对电池放电性能的影响;报导了AA型Li-FeS2和碱性锌锰电池定电阻、定功率放电试验结果,以及在数码相机上实际使用的对比结果;分析了Li-FeS2电池的可充性和安全性.

  • 标签: 锂电池 锂一二硫化铁 高功率 放电测试
  • 简介:采用XRD、XPS、IR、ICP-AES、循环伏安、恒电流充放电等方法对LiCoO2掺杂Na高温固相化学反应合成的Li1-xNaxCoO2材料的结构及电化学性能进行了系统研究。结果表明,当掺杂Na的量x〉0.05后,Li/Li1-xNaxCoO2电池的充、放电容量较Li/LiCoO2的明显下降。随x从0.0增至0.3时,Li/Li1-xNaxCoO2电池以0.5mA/cm^2充电容量由146.3mAh/g下降至130.0mAh/g,放电容量则由110.6mAh/g下降至80.0mAh/g,但工作电压平台均为3.6V。XRD结果显示,随x的增大,Li1-xNaxCoO2的六方晶胞参数a没有统计学上的差异,而晶胞参数c则逐渐减小。但当x〉0.25后,其中有NaCoO2产生。相同x的Li1-xNaxCoO2充电后的六方晶胞参数c比未充电的有所增大,而晶胞参数a则略微缩小。但是当x〉0.25后,出现3个NaCoO2的特征衍射峰。然而,以0.5mA/cm^2充电至4.4V后,Li1-xNaxCoO2的六方晶胞参数c均增大,a略减小。XPS结果表明,随x增大,Li1s的电子结合能有增大趋势,但O1s和Na1s及Co2p3/2和Co2p1/2电子结合能变化很小。与LiCoO2相比,Li1-xNaxCoO2的循环伏安并没有新的氧化还原峰产生。

  • 标签: 锂离子电池 锂电池 LICOO2 Li1-xNaxCoO2
  • 简介:虽然不具有实际应用的价值,Li2MeO3阴极电化学脱嵌锂行为研究对于理解其它正极材料电化学脱嵌锂仍然十分重要,未见相关综述。其中Li2MnO3是层状富锂锰基正极材料的主要相组成成份,对其研究结果对于富锂锰基正极材料的电化学性能改进具有重要指导意义。本文简要综述了该系列材料的国内外研究现状。

  • 标签: 锂离子电池 正极材料 电化学容量
  • 简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.

  • 标签: boron ABNORMALITY LI2O-AL2O3-SIO2 system glass ceramics
  • 简介:Carbon-coatedlithiummanganesesilicate(Li2MnSiO4/C)nanoparticlesweresynthesizedbypolyolprocess.X-raydiffraction(XRD)patternsoftheobtainedmaterialsexhibitagoodfitwiththatoftheLi2MnSiO4phase.Fieldemissionscanningelectronmicroscopy(FESEM)imagesoftheobtainedsamplesshowthattheparticlesizeisonlytensofnanometers.Thehighresolutiontransmissionelectronmicroscopy(HRTEM)analysisshowsthattheLi2MnSiO4nanoparticlesaresurroundedbyaverythinfilmofamorphouscarbon.Thecompositepreparedthroughpolyolprocessshowsgoodperformanceascathodematerialsinlithiumcellsatroomtemperature.ThechargecapacityoftheLi2MnSiO4/Csamplesis219mAh/g(about1.3Li+perunitformulaextracted),andthedischargecapacityis132mAh/g(about0.8Li+perunitformulainserted)inthefirstcycleinthevoltagerangeof1.5-4.8V.Agoodcapacitycyclingmaintenanceof81.8%after10cycleswasobtained.

  • 标签: 电化学性能 纳米粒子 多元醇法 合成过程 场发射扫描电子显微镜 高分辨透射电子显微镜
  • 简介:Li0.33MnO2cathodematerialwassynthesizedbysolidstatereaction.Thematerialshowedasmallcoherentdomainsizeabout10nmdeterminedbyX-raydiffractionandtransmissionelectronmicroscopy.Theelectrochemicalpropertiesofthematerialwerestudiedindifferentpotentialwindowsof3.5―2.0Vand4.3―2.0V.Anirreversibletransformationtospinelphasewasobservedintheinitialseveralcycles,whichwasmoreprominentoncyclingat4.3―2.0V.ElectrochemicalimpedancespectroscopyshowedthattheLi+diffusioncoefficientofthematerialwasabout2×10–9cm2/s.Li0.33MnO2showedareversibledischargecapacityof140and200mA·h/ginthepotentialwindowsof3.5―2.0Vand4.3―2.0V,respectively.Butthecapacityretentionat4.3―2.0Vwaspoorduetothethickerspinellayerformedonthematerialsurface.

  • 标签: 固相合成反应 电化学性能 Windows 正极材料 视窗 尖晶石相
  • 简介:AnInterviewwithLiYiningOnJanuary17,1994,ourreporterinterviewedMrLiYining,well-knownprofessorofeconomics,memberoftheStandingCo...

  • 标签:
  • 简介:ThecapacitytocaptureCO2wasdeterminedinseveralstoichiometriccompositionsintheLi2O–Bi2O3system.Thecompounds(Li7BiO6,Li5BiO5,Li3BiO4andLiBiO2phases)weresynthesizedviasolid-statereactionandcharacterizedbyX-raydiffraction,scanningelectronmicroscopyandN2adsorptiontechniques.Thesampleswereheat-treatedattemperaturesfrom40to750°CundertheCO2atmospheretoevaluatethecarbonateformation,whichisindicativeofthecapacityofCO2capture.Moreover,Li7BiO6showsanexcellentCO2capturecapacityof7.1mmol/g,whichisconsiderablyhigherthanthoseofotherpreviouslyreportedceramics.Li7BiO6isabletoreactwithCO2from240°Ctoapproximately660°CshowingahighkineticreactionevenatCO2partialpressurevaluesaslowas0.05.

  • 标签:
  • 简介:Li4Ti5O12(LTO)/carbonnanotubes(CNTs)compositematerialissynthesizedbasedonasolid-statemethodbysand-milling,spray-dryingandcalciningat8508CunderN2flow.TheLTO/CNTssampleswith1wt%and3wt%weightratioofCNTsadditionandthepristineLTOsampleareprepared.TherateperformanceandthethermalstabilityofthesesamplesareinvestigatedbasedonLiMn2O4(LMO)/LTOfull-cell.TheresultsshowthattheweightratioofCNTsadditionhasdistincteffectonLTOperformances.ThecompositematerialsofLTOcompositedCNTshavebetterperformanceathigh-rateduetotheintercalationenhancementbyconductivenetworkofCNTs.Atsecond,theoverchargingtemperatureresponseofthecell’ssurfacewith1wt%CNTsadditionisthelowest.Theparticlesizedistributionismeasuredandthemostuniformparticlesareobtainedwith1wt%CNTsaddition.ThistrendcouldexplainthatthemediumquantityofCNTsisoptimaltoimprovetheheatandmasstransferandpreventtheproblemsofcrystallitegrowinginterferenceandaggregationduringthecalcinationprocess.

  • 标签: 下线 服务 迁移
  • 简介:Boers-Li画廊的迅速成长毫无疑问与老板皮力有着直接的关系,皮力有着多重身份:博士、批评家、中国最顶尖的艺术策展人之一、中央美院艺术管理系老师。2005年,策展人皮力与WalingBoers在草场地共同创办了UniversalStudiosbeijing,其后更名为Boers-Li画廊。

  • 标签: 青年 回顾 实验